21 research outputs found
Electric field gradients in MgB synthesized at high pressure: Cd TDPAC study and ab initio calculation
We report the high-pressure synthesis of novel superconductor MgB and
some related compounds. The superconducting transition temperature of our
samples of MgB is equal to 36.6 K. The MgB lattice parameters
determined via X-ray diffraction are in excellent agreement with results of our
ab initio calculations. The time-differential perturbed angular correlation
(TDPAC) experiments demonstrate a small increase in quadrupole frequency of
Cd probe with decreasing temperature from 293 to 4.2 K. The electric
field gradient (EFG) at the B site calculated from first principles is in fair
agreement with EFG obtained from B NMR spectra of MgB reported in the
literature. It is also very close to EFG found in our Cd TDPAC
measurements, which suggests that the Cd probe substitutes for boron in
the MgB lattice.Comment: 10 pages, 3 figure
On the structure and dehydration of hydrous zirconia and hafnia xerogels
Hydrous zirconia and hafnia xerogels of compositions ZrO2 · 2.5H2O and HfO2 · 2.3H2O are dehydrated in two steps upon heating. First, molecular water is mostly removed from the structures to form phases of compositions ZrO2 · H2O and HfO2 · 0.5H2O. Second, polycondensation of OH groups occurs. Both processes are easier for ZrO2 · 2.5H 2O. Apart from these steps, the interaction of water molecules with zirconium-oxygen bridges was found to occur during dehydration of the zirconium compound. The composition of HfO2 · 0.5H2O should actually read as Hf4O7(H2O)(OH)2. © Pleiades Publishing, Ltd., 2010
Structure and dehydration of hydrous tin dioxide xerogel
Hydrous tin dioxide xerogel with the composition SnO2 • 1.75H 2O is built of tin-oxygen-hydroxide fragments. Water molecules (no more than 1 mol) in the grain structure are kept by hydrogen bonds. Xerogel is dehydrated in the range 50-890°C in two stages. Below 123°C, molecular water is removed and the polycondensation of ≡Sn-O(H)-Sn≡ bridge groups occurs. There also takes place the transition of some water molecules from the molecular to hydroxide form as follows: ≡Sn-O-Sn≡ + H 2O → 2≡Sn-O-H. All processes occur within individual grains. Above 123°C, water removal is due to the polycondensation of tin-oxygen groups. As a result, grains are coarsen. After 200°C, their structure is determined as cassiterite coated by tin oxyhydrate. © 2007 Pleiades Publishing, Inc
On the structure and dehydration of hydrous zirconia and hafnia xerogels
Hydrous zirconia and hafnia xerogels of compositions ZrO2 · 2.5H2O and HfO2 · 2.3H2O are dehydrated in two steps upon heating. First, molecular water is mostly removed from the structures to form phases of compositions ZrO2 · H2O and HfO2 · 0.5H2O. Second, polycondensation of OH groups occurs. Both processes are easier for ZrO2 · 2.5H 2O. Apart from these steps, the interaction of water molecules with zirconium-oxygen bridges was found to occur during dehydration of the zirconium compound. The composition of HfO2 · 0.5H2O should actually read as Hf4O7(H2O)(OH)2. © Pleiades Publishing, Ltd., 2010