In-situ thermally-reduced graphene oxide/epoxy composites: thermal and mechanical properties

Graphene has excellent mechanical, thermal, optical and electrical properties and this has made it a prime target for use as a filler material in the development of multifunctional polymeric composites. However, several challenges need to be overcome in order to take full advantage of the aforementioned properties of graphene. These include achieving good dispersion and interfacial properties between the graphene filler and the polymeric matrix. In the present work we report the thermal and mechanical properties of reduced graphene oxide/epoxy composites prepared via a facile, scalable and commercially-viable method. Electron micrographs of the composites demonstrate that the reduced graphene oxide (rGO) is well-dispersed throughout the composite. Although no improvements in glass transition temperature, tensile strength, and thermal stability in air of the composites were observed, good improvements in thermal conductivity (about 36%), tensile and storage moduli (more than 13%) were recorded with the addition of 2 wt% of rGO

John S. Bransford to Kinloch Falconer (9 September 1864)

Letter addressing the issue of forgery and leaves of abscences.https://egrove.olemiss.edu/ciwar_corresp/1369/thumbnail.jp

The mechanical properties and toughening mechanisms of an epoxy polymer modified with polysiloxane-based core-shell particles

AbstractAn epoxy resin, cured using an anhydride hardener, has been modified by the addition of pre-formed polysiloxane core-shell rubber (S-CSR) particles with a mean diameter of 0.18 μm. The glass transition temperature, Tg, of the cured unmodified epoxy polymer was 148 °C, and this was unchanged after the addition of the S-CSR particles. The polysiloxane rubber particles had a Tg of about −100 °C. Atomic force microscopy showed that the S-CSR particles were well-dispersed in the epoxy polymer. The addition of the S-CSR particles reduced the Young's modulus and tensile strength of the epoxy polymer, but at 20 °C the fracture energy, GIc, increased from 117 J/m2 for the unmodified epoxy to 947 J/m2 when 20 wt% of the S-CSR particles were incorporated. Fracture tests were also performed at −55 °C, −80 °C, and −109 °C. The results showed that the measured fracture energy of the S-CSR-modified epoxy polymers decreased significantly below room temperature. For example, at −109 °C, a fracture energy of 481 J/m2 was measured using 20 wt% of S-CSR particles. Nevertheless, this value of toughness still represented a major increase compared with the unmodified epoxy polymer, which possessed a value of GIc of 174 J/m2 at this very low test temperature. Thus, a clear fact that emerged was that the addition to the epoxy polymer of the S-CSR particles may indeed lead to significant toughening of the epoxy, even at temperatures as low as about −100 °C. The toughening mechanisms induced by the S-CSR particles were identified as (a) localised plastic shear-band yielding around the particles and (b) cavitation of the particles followed by plastic void growth of the epoxy polymer. These mechanisms were modelled using the Hsieh et al. approach [33,49] and the values of GIc of the S-CSR-modified epoxy polymers at the different test temperatures were calculated. Excellent agreement was found between the predictions and the experimentally measured fracture energies. Further, the experimental and modelling results of the present study indicated that the extent of plastic void growth was suppressed at low temperatures for the S-CSR-modified epoxy polymers, but that the localised shear-band yielding mechanism was relatively insensitive to the test temperature

The mechanical performance of repaired stiffened panels. Part II. Finite element modelling

ABSTRACT In this paper the finite element modelling under compressive static load of I-section stiffened panels is reported. A pristine panel is compared with panels containing simulated damage and repaired panels. Predicted stiffness, stress distributions and strength of the panels are compared with experimental results

The tensile fatigue behavior of a glass-fiber reinforced plastic composite using a hybrid-toughened epoxy matrix

ABSTRACT A thermosetting epoxy-polymer was modified by incorporating 9 wt.% of carboxyl-terminated butadiene-acrylonitrile (CTBN) rubber microparticles and 10 wt.% of silica nanoparticles. The tensile fatigue behaviour at a stress ratio, R = 0.1 for both the neat (i.e. unmodified) epoxy-polymer and the hybridepoxy polymer was first investigated. The fatigue life of the hybrid-epoxy * Corresponding author: Tel. +91-80-2508 6310 ; Fax: +91-80-2508 6301 E-mail address: [email protected] (CM Manjunatha) 2 polymer was about six to ten times higher than that the neat-epoxy polymer. Secondly, the neat and the hybrid-epoxy resins were infused into a quasiisotropic lay-up, E-glass fiber fabric via a 'Resin Infusion under Flexible Tooling' (RIFT) set-up to fabricate glass-fiber reinforced-plastic (GFRP) composite panels. The tensile fatigue tests at a stress ratio, R = 0.1 were performed on both of these GFRP composites during which the matrix cracking and stiffness degradation were routinely monitored. The fatigue life of the GFRP composite increased by about six to ten times due to employing the hybrid-epoxy matrix, compared to the neat-epoxy matrix. Suppressed matrix cracking and a reduced crack propagation rate were observed in the hybrid-epoxy matrix, which resulted from the various toughening micromechanisms induced by the presence of both the rubber microparticles and silica nanoparticles. These factors were considered to contribute towards the enhanced fatigue life which was observed for the GFRP composite employing the hybrid-epoxy matrix

The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite

Abstract An anhydride-cured thermosetting epoxy polymer was modified by incorporating 10 wt.% of welldispersed 20 nm diameter silica nanoparticles. The stress-controlled tensile fatigue behaviour at a stress ratio of R = 0.1 was investigated for bulk specimens of the neat and the silica-modified epoxy. The addition of the silica nanoparticles increased the fatigue life by about three to four times. The neat and the nanoparticle-modified epoxy resins were used to fabricate glass fibre reinforced plastic (GFRP) composite laminates by resin infusion under flexible tooling (RIFT). Tensile fatigue tests were performed on these composites, during which the matrix cracking and stiffness degradation was monitored. The fatigue life of the GFRP composite was increased by about three to four times due to the silica nanoparticles. Suppressed matrix cracking and a reduced crack propagation rate in the nanoparticle-modified matrix were observed to contribute towards the enhanced fatigue life of the composite containing the silica nanoparticles