Critical flux-based membrane fouling control of forward osmosis: Behavior, sustainability, and reversibility

Membrane fouling is closely related to the concept of critical flux. Therefore, a fouling control strategy for forward osmosis (FO) membranes that is based on the critical flux is necessary. This study systematically investigated the critical flux behavior of FO membranes (CTA and PA-TFC) in the short-term using a stepping method (draw solution (DS) concentration stepping). In addition, to test the reliability of this method, long-term experiments were conducted to evaluate the influences of operational critical flux on the fouling behavior (sustainable operation and fouling reversibility/irreversibility), thereby determining the critical flux for reversibility. Our results showed that the DS concentration stepping could be applied for critical flux determination in FO. Both membranes exhibited higher critical flux values for alginate fouling compared to other single foulants such as colloidal silica or gypsum. The values were 15.9 LMH for a cellulose triacetate membrane (CTA) and 20.5 LMH for the polyamide thin-film composite (PA-TFC). Whilst these values should be adequate in FO applications they were determined for single foulants. The presence of multispecies of foulants caused a significant decline in the critical flux values. This study found 5.4 LMH for the CTA membrane and 8.3 LMH for the PA-TFC membrane for the combined foulants of alginate + gypsum. This indicates that the critical flux behavior in FO was dependent on the foulant type and membrane type. Importantly, the high restoration of water flux was achieved with the PA-TFC membrane at an operation either close to critical flux (92–98%) or below critical flux (98–100%) (i.e., with negligible irreversible fouling). The critical fluxes for reversibility obtained in this study will aid the efficient operation of practical FO processes

A note on the values of the weighted q-Bernstein polynomials and modified q-Genocchi numbers with weight alpha and beta via the p-adic q-integral on Zp

The rapid development of q-calculus has led to the discovery of new generalizations of Bernstein polynomials and Genocchi polynomials involving q-integers. The present paper deals with weighted q-Bernstein polynomials and q-Genocchi numbers with weight alpha and beta. We apply the method of generating function and p-adic q-integral representation on Zp, which are exploited to derive further classes of Bernstein polynomials and q-Genocchi numbers and polynomials. To be more precise we summarize our results as follows, we obtain some combinatorial relations between q-Genocchi numbers and polynomials with weight alpha and beta. Furthermore, we derive an integral representation of weighted q-Bernstein polynomials of degree n on Zp. Also we deduce a fermionic p-adic q-integral representation of product weighted q-Bernstein polynomials of different degrees n1,n2,...on Zp and show that it can be written with q-Genocchi numbers with weight alpha and beta which yields a deeper insight into the effectiveness of this type of generalizations. Our new generating function possess a number of interesting properties which we state in this paper.Comment: 10 page

On Determining Minimal Spectrally Arbitrary Patterns

In this paper we present a new family of minimal spectrally arbitrary patterns which allow for arbitrary spectrum by using the Nilpotent-Jacobian method. The novel approach here is that we use the Intermediate Value Theorem to avoid finding an explicit nilpotent realization of the new minimal spectrally arbitrary patterns.Comment: 8 page

Expression of Heterologous OsDHAR Gene Improves Glutathione (GSH)-Dependent Antioxidant System and Maintenance of Cellular Redox Status in Synechococcus elongatus PCC 7942.

An excess of reactive oxygen species (ROS) can cause severe oxidative damage to cellular components in photosynthetic cells. Antioxidant systems, such as the glutathione (GSH) pools, regulate redox status in cells to guard against such damage. Dehydroascorbate reductase (DHAR, EC 1.8.5.1) catalyzes the glutathione-dependent reduction of oxidized ascorbate (dehydroascorbate) and contains a redox active site and glutathione binding-site. The DHAR gene is important in biological and abiotic stress responses involving reduction of the oxidative damage caused by ROS. In this study, transgenic Synechococcus elongatus PCC 7942 (TA) was constructed by cloning the Oryza sativa L. japonica DHAR (OsDHAR) gene controlled by an isopropyl β-D-1-thiogalactopyranoside (IPTG)-inducible promoter (Ptrc) into the cyanobacterium to study the functional activities of OsDHAR under oxidative stress caused by hydrogen peroxide exposure. OsDHAR expression increased the growth of S. elongatus PCC 7942 under oxidative stress by reducing the levels of hydroperoxides and malondialdehyde (MDA) and mitigating the loss of chlorophyll. DHAR and glutathione S-transferase activity were higher than in the wild-type S. elongatus PCC 7942 (WT). Additionally, overexpression of OsDHAR in S. elongatus PCC 7942 greatly increased the glutathione (GSH)/glutathione disulfide (GSSG) ratio in the presence or absence of hydrogen peroxide. These results strongly suggest that DHAR attenuates deleterious oxidative effects via the glutathione (GSH)-dependent antioxidant system in cyanobacterial cells. The expression of heterologous OsDHAR in S. elongatus PCC 7942 protected cells from oxidative damage through a GSH-dependent antioxidant system via GSH-dependent reactions at the redox active site and GSH binding site residues during oxidative stress

Dynamics of fullerene coalescence

Fullerene coalescence experimentally found in fullerene-embedded single-wall nanotubes under electron-beam irradiation or heat treatment is simulated by minimizing the classical action for many atom systems. The dynamical trajectory for forming a (5,5) C$_{120}$ nanocapsule from two C$_{60}$ fullerene molecules consists of thermal motions around potential basins and ten successive Stone-Wales-type bond rotations after the initial cage-opening process for which energy cost is about 8 eV. Dynamical paths for forming large-diameter nanocapsules with (10,0), (6,6), and (12,0) chiral indexes have more bond rotations than 25 with the transition barriers in a range of 10--12 eV.Comment: 4 pages, 2 figures, 1 supplementary movie at http://dielc.kaist.ac.kr/yonghyun/coal.mpeg. To be published in Physical Review Letter

The quantization of the chiral Schwinger model based on the BFT-BFV formalism II

We apply an improved version of Batalin-Fradkin-Tyutin (BFT) Hamiltonian method to the a=1 chiral Schwinger Model, which is much more nontrivial than the a>1.$one. Furthermore, through the path integral quantization, we newly resolve the problem of the non-trivial$\delta$function as well as that of the unwanted Fourier parameter$\xi$ in the measure. As a result, we explicitly obtain the fully gauge invariant partition function, which includes a new type of Wess-Zumino (WZ) term irrelevant to the gauge symmetry as well as usual WZ action.Comment: 17 pages, To be published in J. Phys.

Resource Allocation for Wireless-Powered Full-Duplex Relaying Systems with Nonlinear Energy Harvesting Efficiency

In wireless power transfer (WPT)-assisted relaying systems, spectral efficiency (SE) of source-relay link plays a dominant role in system SE performance due to the limited transmission power at the WPT-aided relay. In this paper, we propose a novel protocol for a downlink orthogonal frequency division multiple access (OFDMA) system with a WPT-aided relay operating in full-duplex (FD) decode-and-forward (DF) mode, where the time slot durations of the source-relay and relay-users hops are designed to be dynamic, to enhance the utilization of degrees of freedom and hence the system SE. In particular, a multiple-input and signal-output (MISO) source-relay channel is considered to satisfy the stringent sensitivity of the energy harvesting (EH) circuit at the relay, while a single-input and single-output (SISO) relay-user channel is considered to alleviate the power consumption at the relay node. Taking into account the non-linearity of EH efficiency, a near-optimal iteration-based dynamic WPT-aided FD relaying (A-FR) algorithm is developed by jointly optimizing the time slot durations, subcarriers, and transmission power at the source and the relay. Furthermore, self-interference generated at the relay is utilized as a vital energy source rather than being canceled, which increases substantially the total energy harvested at the FD relay. We also reveal some implicit characteristics of the considered WPT-aided FD relaying system through intensive discussions. Simulation results confirm that the proposed A-FR achieves a significant enhancement in terms of SE with different relay's locations and the number of users, compared to the conventional symmetric WPT-aided FD relaying (S-FR) and the time-switching-based WPT-aided FD relaying (TS-FR) benchmarks

Aerosol Modulation of Ultraviolet Radiation Dose over Four Metro Cities in India

This paper discusses the influence of aerosols on UV erythemal dose over four metro cities in India. Tropospheric Emission Monitoring Internet Service (TEMIS), archived UV-index (UV-I), and UV daily erythemal dose obtained from SCIAMACHY satellite were used in this study during June 2004 and May 2005 periods covering four important Indian seasons. UV-Index (UV-I), an important parameter representing UV risk, was found to be in the high to extreme range in Chennai (8.1 to 15.33), moderate to extreme range in Mumbai and Kolkata (5 to 16.5), and low to extreme over Delhi (3 to 15). Average UV erythemal dose showed seasonal variation from 5.9 to 6.3 KJm−2 during summer, 2.9 to 4.4 KJm−2 during postmonsoon, 3 to 4.5 KJm−2 during winter, and 5.1 to 6.19 KJm−2 during premonsoon seasons over the four cities. To estimate the influence of aerosols on reducing UV dose, UV aerosol radiative forcing and forcing efficiency were estimated over the sites. The average aerosol forcing efficiency was found to be from -1.38±0.33 to -3.01±0.28 KJm−2 AOD−1 on different seasons. The study suggests that aerosols can reduce the incoming UV radiation dose by 30–60% during different seasons

Phase Diagram and Crossover Phases of Topologically Ordered Graphene Zigzag Nanoribbons: Role of Localization Effects

We computed the phase diagram of the zigzag graphene nanoribbons as a function of on-site repulsion, doping, and disorder strength. The topologically ordered phase undergoes topological phase transitions into crossover phases, which are new disordered phases with a nonuniversal topological entanglement entropy with significant variance. The topological order is destroyed by competition between localization effects and on-site repulsion. We found that strong on-site repulsion and/or doping weakens the nonlocal correlations between the opposite zigzag edges. In one of the crossover phases, both $\frac{e^-}{2}$ fractional charges and spin-charge separation were absent; however, charge-transfer correlations between the zigzag edges were possible. Another crossover phase contains $\frac{e^-}{2}$ fractional charges, but no charge transfer correlations. In low-doped zigzag ribbons the interplay between electron localization and on-site repulsion contributes to the spatial separation of quasi-degenerate gap-edge states and protects the charge fractionalization against quantum fluctuations. In all these effects, mixed chiral gap-edge states play an important role. The properties of nontopological strongly disordered and strongly repulsive phases are also observed. Each phase of the phase diagram has a different zigzag-edge structure