97 research outputs found

    Untangle charge-order dependent bulk states from surface effects in a topological kagome metal ScV6_6Sn6_6

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    Kagome metals with charge density wave (CDW) order exhibit a broad spectrum of intriguing quantum phenomena. The recent discovery of the novel kagome CDW compound ScV6_6Sn6_6 has spurred significant interest. However, understanding the interplay between CDW and the bulk electronic structure has been obscured by a profusion of surface states and terminations in this quantum material. Here, we employ photoemission spectroscopy and potassium dosing to elucidate the complete bulk band structure of ScV6_6Sn6_6, revealing multiple van Hove singularities near the Fermi level. We surprisingly discover a robust spin-polarized topological Dirac surface resonance state at the M point within the two-fold van Hove singularities. Assisted by the first-principle calculations, the temperature dependence of the kzk_z- resolved ARPES spectrum provides unequivocal evidence for the proposed 3\sqrt{3}×\times3\sqrt{3}×3\times3 charge order over other candidates. Our work not only enhances the understanding of the CDW-dependent bulk and surface states in ScV6_6Sn6_6 but also establishes an essential foundation for potential manipulation of the CDW order in kagome materials.Comment: To appear in PR

    Regulation of BRCA1 stability through the tandem UBX domains of isoleucyl-tRNA synthetase 1

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    Aminoacyl-tRNA synthetases possess unique domains. In this study the structure of the vertebrate IARS1 and EARS1 complex reveals that vertebrate IARS1 protects the DNA repair factor BRCA1 from proteolytic degradation via its UBX-fold domain. Aminoacyl-tRNA synthetases (ARSs) have evolved to acquire various additional domains. These domains allow ARSs to communicate with other cellular proteins in order to promote non-translational functions. Vertebrate cytoplasmic isoleucyl-tRNA synthetases (IARS1s) have an uncharacterized unique domain, UNE-I. Here, we present the crystal structure of the chicken IARS1 UNE-I complexed with glutamyl-tRNA synthetase 1 (EARS1). UNE-I consists of tandem ubiquitin regulatory X (UBX) domains that interact with a distinct hairpin loop on EARS1 and protect its neighboring proteins in the multi-synthetase complex from degradation. Phosphomimetic mutation of the two serine residues in the hairpin loop releases IARS1 from the complex. IARS1 interacts with BRCA1 in the nucleus, regulates its stability by inhibiting ubiquitylation via the UBX domains, and controls DNA repair function

    Design and Development of Cathode Materials for Rechargeable Batteries

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    Over the past two decades, rechargeable Li-ion batteries (LIBs) have been the de facto standard power source for electronic devices [...

    Attosecond counter rotating wave effect in a highly excited atom driven by strong fields

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    Stabilizing oxygen redox chemistry for the realization of high-capacity batteries

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    Maintenance Optimization for Repairable Deteriorating Systems under Imperfect Preventive Maintenance

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    This study deals with the preventive maintenance optimization problem based on a reliability threshold. The conditional reliability threshold is used instead of the system reliability threshold. Then, the difference between the two thresholds is discussed. The hybrid failure rate model is employed to represent the effect of imperfect preventive maintenance activities. Two maintenance strategies are proposed under two types of reliability constraints. These constraints are set to consider the cost-effective maintenance strategy and to evaluate the balancing point between the expected total maintenance cost rate and the system reliability. The objective of the proposed maintenance strategies is to determine the optimal conditional reliability threshold together with the optimal number of preventive maintenance activities that minimize the expected total maintenance cost per unit time. The optimality conditions of the proposed maintenance strategies are also investigated and shown via four propositions. A numerical example is provided to illustrate the proposed preventive maintenance strategies. Some sensitivity analyses are also conducted to investigate how the parameters of the proposed model affect the optimality of preventive maintenance strategies
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