Observation of lyotropic chromonic liquid crystals droplets with the perpendicular boundary condition

Department of PhysicsControlling anchoring conditions of liquid crystals (LCs) is crucial for the study of liquid crystals and development of liquid crystals-based displays and sensors. Although many studies have been made on thermotropic liquid crystals, the anchoring conditions of lyotropic chromonic liquid crystals (LCLCs) are difficult to control even through properties of LCLCs were actively studied. Conventional alignment methods have no effect on LCLCs, even work, anchoring is very weak. Only a few perpendicular alignment layers (a.k.a. homeotropic anchoring) in solid-LCs interfaces were reported through non-covalent interactions of hydrophobic polymer films and solid substrates such as graphene. However, the vertical alignment layers of LCLCs at the liquid interface has never been reported. We report, for the first time, the study of the homeotropic anchoring of liquid and LCLCs interfaces using hydrophobic oils without surfactants. As reported in thermotropic liquid crystals, a radial structure with a point defect has been found, but an unusual feature is the axial structure with ring disclination, which did not apply the external field. It implies that this anchoring strength is very weak anchoring conditions and another supporting evidence is the anchoring transition, which changes to the horizontal orientation from the perpendicular orientation. Also, because of the weak twist modulus of the LCLCs, the structure of the defects seemed to be twisted. This twist structure is consistent with previous reports. To observe the structures of homeotropic chiral nematic, brucine sulfate was used as a chiral dopants. Basically, we reproduced the director configurations of the droplets of the thermotropic chiral nematic LCs both with planar and homeotropic anchoring. Specifically, with the homeotropic anchoring, we noticed an increase in the effective helical pitch in the droplets according to the droplet size, i.e. the untwisting of the helical structure, which originates from the frustration of chiral nematic liquid crystals with the perpendicular boundary condition.ope