DETC2005-84822 NONLINEAR DYNAMIC ANALYSIS AND CHAOTIC BEHAVIOR IN ATOMIC FORCE MICROSCOPY

ABSTRACT The atomic force microscope (AFM) system has evolved into a useful tool for direct measurements of intermolecular forces with atomic-resolution characterization that can be employed in a broad spectrum of applications. In this paper, the nonlinear dynamical behavior of the AFM is studied. This is achieved by modeling the microcantilever as a single mode approximation (lumped-parameters model) and considering the interaction between the sample and cantilever in the form of van der Waals potential. The resultant nonlinear system is then analyzed using Melnikov method, which predicts the regions in which only periodic and quasi-periodic motions exist, and also predicts the regions that chaotic motion is possible. Numerical simulations are used to verify the presence of such chaotic invariant sets determined by Melnikov theory. Finally, the amplitude of vibration in which chaos is appeared is investigated and such irregular motion is proven by several methods including Poincare maps, Fourier transform, autocorrelation function and Lyapunov exponents

IDETC2009-86188 SIMULATIONS OF SURFACE DEFECTS CHARACTERIZATION USING FORCE MODULATION ATOMIC FORCE MICROSCOPY

ABSTRACT This paper is devoted to the characterization of the surface defects using a recently developed AFM technique named as frequency and force modulation AFM (FFM-AFM). The simulated system includes a recently developed gold coated AFM probe which interacts with a sample including single-atom vacancy and impurities. In order to examine the behavior of the above system including different transition metals, molecular dynamics (MD) simulation with Sutton-Chen (SC) interatomic potential is used. Along this line, an imaging simulation of the probe and sample is performed, and the effects of the horizontal scan speed, the effective frequency set-point, the cantilever stiffness, the tip-sample rest position and the cantilever quality factor on the resulting images are investigated. Using a proposed optimum controlling scheme for the excitation force amplitude, the cantilever horizontal speed can be maximized

IMECE2006-14275 NONLINEAR DYNAMIC ANALYSIS OF ATOMIC FORCE MICROSCOPY UNDER DETERMINISTIC AND RANDOM EXCITATION

ABSTRACT This paper is devoted to the analysis of nonlinear behavior of amplitude modulation (AM) and frequency modulation (FM) modes of atomic force microscopy. For this, the microcantilever (which forms the basis for the operation of AFM) is modeled as a single mode approximation and the interaction between the sample and cantilever is derived from a van der Waals potential. Using perturbation methods such as Averaging, and Fourier transform nonlinear equations of motion are analytically solved and the advantageous results are extracted from this nonlinear analysis. The results of the proposed techniques for AM-AFM, clearly depict the existence of two stable and one unstable (saddle) solutions for some of exciting parameters under deterministic vibration. The basin of attraction of two stable solutions is different and dependent on the exciting frequency. From this analysis the range of the frequency which will result in a unique periodic response can be obtained and used in practical experiments. Furthermore the analytical responses determined by perturbation techniques can be used to detect the parameter region where the chaotic motion is avoided. On the other hand for FM-AFM, the relation between frequency shift and the system parameters can be extracted and used for investigation of the system nonlinear behavior. The nonlinear behavior of the oscillating tip can easily explain the observed shift of frequency as a function of tip sample distance. Also in this paper we have investigated the AM-AFM system response under a random excitation. Using two different methods we have obtained the statistical properties of the tip motion. The results show that we can use the mean square value of tip motion to image the sample when the excitation signal is random. INTRODUCTION The atomic force microscope (AFM) system has evolved into a useful tool for direct measurements of intermolecular forces with atomic-resolution characterization that can be employed in a broad spectrum of applications such as electronics, semi-conductors, manufacturing, polymers

Unidirectional motion of C60-based nanovehicles using hybrid substrates with temperature gradient

With the synthesis of nanocar structures the idea of transporting energy and payloads on the surface became closer to reality. To eliminate the concern of diffusive surface motion of nanocars, in this study, we evaluate the motion of C60 and C60-based nanovehicles on graphene and hexagonal boron-nitride (BN) surfaces using molecular dynamics simulations and potential energy analysis. Utilizing the graphene-hBN hybrid substrate, it has been indicated that C60 is more stable on boron-nitride impurity regions in the hybrid substrate and an energy barrier restricts the motion to the boron-nitride impurity. Increasing the temperature causes the molecule to overcome the energy barrier frequently. A nanoroad of boron-nitride with graphene sideways is designed to confine the surface motion of C60 and nanovehicles at 300 K. As expected, the motion of all surface molecules is limited to the boron-nitride nanoroads. Although the motion is restricted to the boron-nitride nanoroad, the diffusive motion is still noticeable in lateral directions. To obtain the unidirectional motion for C60 and nanocars on the surface, a temperature gradient is applied to the surface. The unidirectional transport to the nanoroad regions with a lower temperature occurs in a short period of time due to the lower energies of molecules on the colder parts

Unidirectional motion of C60-based nanovehicles using hybrid substrates with temperature gradient

Abstract With the synthesis of nanocar structures the idea of transporting energy and payloads on the surface became closer to reality. To eliminate the concern of diffusive surface motion of nanocars, in this study, we evaluate the motion of C60 and C60-based nanovehicles on graphene and hexagonal boron-nitride (BN) surfaces using molecular dynamics simulations and potential energy analysis. Utilizing the graphene-hBN hybrid substrate, it has been indicated that C60 is more stable on boron-nitride impurity regions in the hybrid substrate and an energy barrier restricts the motion to the boron-nitride impurity. Increasing the temperature causes the molecule to overcome the energy barrier frequently. A nanoroad of boron-nitride with graphene sideways is designed to confine the surface motion of C60 and nanovehicles at 300 K. As expected, the motion of all surface molecules is limited to the boron-nitride nanoroads. Although the motion is restricted to the boron-nitride nanoroad, the diffusive motion is still noticeable in lateral directions. To obtain the unidirectional motion for C60 and nanocars on the surface, a temperature gradient is applied to the surface. The unidirectional transport to the nanoroad regions with a lower temperature occurs in a short period of time due to the lower energies of molecules on the colder parts

Motion of nanovehicles on pristine and vacancy-defected silicene: implications for controlled surface motion

Understanding the motion of surface-rolling nanomachines has attracted lots of attention in recent studies, due to their ability in carrying molecular payloads and nanomaterials on the surface. Controlling the surface motion of these nanovehicles is beneficial in the fabrication of nano-transportation systems. In the present study, molecular dynamics (MD) simulations alongside the potential energy analysis have been utilized to investigate the motion of C60 and C60-based nanovehicles on the silicene monolayer. Nano-machine simulations are performed using molecular mechanic forcefield. Compared with graphene and hexagonal boron-nitride, the molecules experience a higher energy barrier on the silicene, which leads to a lower diffusion coefficient and higher activation energy of C60 and nanomachines. Overcoming the maximum energy barrier against sliding motion is more probable at higher temperatures where the nanomachines receive higher thermal energy. After evaluating the motion of molecules around local vacancies, we introduce a nanoroad structure that can restrict surface motion. The motion of C60 and nanovehicles over the surface is limited to the width of nanorods up to a certain temperature. To increase the controllability of the motion, a thermal gradient has been applied to the surface and the molecules move toward the lower temperature regions, where they find lower energy levels. Comparing the results of this study with other investigations regarding the surface motion of molecules on boron-nitride and graphene surfaces brings forth the idea of controlling the motion by silicene-based hybrid substrates, which can be further investigated

Size Effect Impact on the Mechanical Behavior of an Electrically Actuated Polysilicon Nanobeam based NEMS Resonator

In this paper, the dynamic response of resonating nano-beams is investigated using a strain gradient elasticity theory. A nonlinear model is obtained based on the Galerkin decomposition method to find the dynamic response of the investigated beam around its statically deflected position. The mid-plane stretching, axial residual stress and nonlinear interaction due to the electrostatic force on the deflected beam are included in the proposed nonlinear beam model. Comparing the beam natural frequency using strain gradient theory with experimental data shows an excellent agreement among both approaches. The normalized natural frequency is shown to be increasing nonlinearly with the decrease of the applied DC voltage as well as beam thickness. The results also reveal that increasing the tension axial stress increases the natural frequency; however its influence decreases when decreasing the beam thickness. To investigate the effect of AC actuation voltage on the beam resonant frequency, a Lindstedt-Poincare based perturbation method is utilized and validated by comparison with experimental data. The results show that increasing the AC actuation voltage makes the beam stiffer by increasing its resonant frequency