Dislocation subgrain structures and modeling the plastic hardening of metallic single crystals

A single crystal plasticity theory for insertion into finite element simulation is formulated using sequential laminates to model subgrain dislocation structures. It is known that local models do not adequately account for latent hardening, as latent hardening is not only a material property, but a nonlocal property (e.g. grain size and shape). The addition of the nonlocal energy from the formation of subgrain structure dislocation walls and the boundary layer misfits provide both latent and self-hardening of a crystal slip. Latent hardening occurs as the formation of new dislocation walls limits motion of new mobile dislocations, thus hardening future slip systems. Self-hardening is accomplished by an evolution of the subgrain structure length scale. The substructure length scale is computed by minimizing the nonlocal energy. The minimization of the nonlocal energy is a competition between the dislocation wall energy and the boundary layer energies. The nonlocal terms are also directly minimized within the subgrain model as they affect deformation response. The geometrical relationship between the dislocation walls and slip planes affecting the dislocation mean free path is taken into account, giving a first-order approximation to shape effects. A coplanar slip model is developed due to requirements while modeling the subgrain structure. This subgrain structure plasticity model is noteworthy as all material parameters are experimentally determined rather than fit. The model also has an inherit path dependence due to the formation of the subgrain structures. Validation is accomplished by comparison with single crystal tension test results

Absence of magnetic long range order in Y2_{2}CrSbO7_{7}: bond-disorder induced magnetic frustration in a ferromagnetic pyrochlore

The consequences of nonmagnetic-ion dilution for the pyrochlore family Y$_{2}$($M_{1-x}N_{x}$)$_{2}$O$_{7}$ ($M$ = magnetic ion, $N$ = nonmagnetic ion) have been investigated. As a first step, we experimentally examine the magnetic properties of Y$_{2}$CrSbO$_{7}$ ($x$ = 0.5), in which the magnetic sites (Cr$^{3+}$) are percolative. Although the effective Cr-Cr spin exchange is ferromagnetic, as evidenced by a positive Curie-Weiss temperature, $\Theta_\mathrm{{CW}}$ = 20.1(6) K, our high-resolution neutron powder diffraction measurements detect no sign of magnetic long range order down to 2 K. In order to understand our observations, we performed numerical simulations to study the bond-disorder introduced by the ionic size mismatch between $M$ and $N$. Based on these simulations, bond-disorder ($x_{b}$ $\simeq$ 0.23) percolates well ahead of site-disorder ($x_{s}$ $\simeq$ 0.61). This model successfully reproduces the critical region (0.2 < $x$ < 0.25) for the N\'eel to spin glass phase transition in Zn(Cr$_{1-x}$Ga$_{x}$)$_{2}$O$_{4}$, where the Cr/Ga-sublattice forms the same corner-sharing tetrahedral network as the $M/N$-sublattice in Y$_{2}$($M_{1-x}N_{x}$)$_{2}$O$_{7}$, and the rapid drop in magnetically ordered moment in the N\'eel phase [Lee $et$ $al$, Phys. Rev. B 77, 014405 (2008)]. Our study stresses the nonnegligible role of bond-disorder on magnetic frustration, even in ferromagnets

Testing Asteroseismic Radii of Dwarfs and Subgiants with Kepler and Gaia

We test asteroseismic radii of Kepler main-sequence and subgiant stars by deriving their parallaxes which are compared with those of the first Gaia data release. We compute radii based on the asteroseismic scaling relations as well as by fitting observed oscillation frequencies to stellar models for a subset of the sample, and test the impact of using effective temperatures from either spectroscopy or the infrared flux method. An offset of 3%, showing no dependency on any stellar parameters, is found between seismic parallaxes derived from frequency modelling and those from Gaia. For parallaxes based on radii from the scaling relations, a smaller offset is found on average; however, the offset becomes temperature dependent which we interpret as problems with the scaling relations at high stellar temperatures. Using the hotter infrared flux method temperature scale, there is no indication that radii from the scaling relations are inaccurate by more than about 5%. Taking the radii and masses from the modelling of individual frequencies as reference values, we seek to correct the scaling relations for the observed temperature trend. This analysis indicates that the scaling relations systematically overestimate radii and masses at high temperatures, and that they are accurate to within 5% in radius and 13% in mass for main-sequence stars with temperatures below 6400 K. However, further analysis is required to test the validity of the corrections on a star-by-star basis and for more evolved stars.Comment: 12 pages, 9 figures. Accepted for publication in MNRA

Process feasibility study in support of silicon material task 1

Initial results for gas thermal conductivity of silicon tetrafluoride and trichlorosilane are reported in respective temperature ranges of 25 to 400 C and 50 to 400 C. For chemical engineering analyses, the preliminary process design for the original silane process of Union Carbide was completed for Cases A and B, Regular and Minimum Process Storage. Included are raw material usage, utility requirements, major process equipment lists, and production labor requirements. Because of the large differences in surge tankage between major unit operations the fixed capital investment varied from $19,094,000 to$11,138,000 for Cases A and B, respectively. For the silane process the original flowsheet was revised for a more optimum arrangement of major equipment, raw materials and operating conditions. The initial issue of the revised flowsheet (Case C) for the silane process indicated favorable cost benefits over the original scheme

Enceladus: Cassini observations and implications for the search for life

Aims. The recent Cassini discovery of water vapor plumes ejected from the south pole of the Saturnian satellite, Enceladus, presents a unique window of opportunity for the detection of extant life in our solar system. Methods. With its significant geothermal energy source propelling these plumes >80 km from the surface of the moon and the ensuing large temperature gradient with the surrounding environment, it is possible to have the weathering of rocks by liquid water at the rock/liquid interface. For the cases of the putatively detected salt-water oceans beneath the ice crusts of Europa and Callisto, an isolated subsurface ocean without photosynthesis or contact with an oxidizing atmosphere will approach chemical equilibrium and annihilate any ecosystems dependent on redox gradients unless there is a substantial alternative energy source. This thermodynamic tendency imposes severe constraints on any biota that is based on chemical energy. On Enceladus, the weathering of rocks by liquid water and any concomitant radioactive emissions are possible incipient conditions for life. If there is CO, CO2 and NH3 present in the spectra obtained from the plume, then this is possible evidence that amino acids could be formed at the rock/liquid interface of Enceladus. The combination of a hydrological cycle, chemical redox gradient and geochemical cycle give favorable conditions for life. Results. We discuss the search for signatures of these species and organics in the Cassini UVIS spectra of the plume and implications for the possible detection of life

The role of binaries in the enrichment of the early Galactic halo. I. r-process-enhanced metal-poor stars

The detailed chemical composition of most metal-poor halo stars has been found to be highly uniform, but a minority of stars exhibit dramatic enhancements in their abundances of heavy neutron-capture elements and/or of carbon. The key question for Galactic chemical evolution models is whether these peculiarities reflect the composition of the natal clouds, or if they are due to later mass transfer of processed material from a binary companion. If the former case applies, the observed excess of certain elements was implanted within selected clouds in the early ISM from a production site at interstellar distances. Our aim is to determine the frequency and orbital properties of binaries among these chemically peculiar stars. This information provides the basis for deciding whether mass transfer from a binary companion is necessary and sufficient to explain their unusual compositions. This paper discusses our study of a sample of 17 moderately (r-I) and highly (r-II) r-process-element enhanced VMP and EMP stars. High-resolution, low signal-to-noise spectra of the stars were obtained at roughly monthly intervals over 8 years with the FIES spectrograph at the Nordic Optical Telescope. From these spectra, radial velocities with an accuracy of ~100 m/s were determined by cross-correlation against an optimized template. 14 of the programme stars exhibit no significant RV variation over this period, while 3 are binaries with orbits of typical eccentricity for their periods, resulting in a normal binary frequency of ~18+-6% for the sample. Our results confirm our preliminary conclusion from 2011, based on partial data, that the chemical peculiarity of the r-I and r-II stars is not caused by any putative binary companions. Instead, it was imprinted on the natal molecular clouds of these stars by an external, distant source. Models of the ISM in early galaxies should account for such mechanisms.Comment: 14 pages, 3 figures, accepted for publication in Astronomy and Astrophysic