112 research outputs found
Improving the stability and efficiency of anaerobic digestion of food waste using additives: a critical review
Anaerobic digestion is an effective technology to treat food waste, with methane production as renewable bioenergy. However, there are two key problems in the practical application, i.e., poor system stability and low reactor efficiency. In this paper, additives used in anaerobic digestion of food waste were systematically reviewed in view of system stability and reactor efficiency. Enzymes showed excellent property in food waste pre-hydrolysis stage with almost all macromolecular matters being rapidly resolved. Fungi fermentation process to produce hydrolytic enzymes, can be regarded as a promising and low-cost way to realize rate-limiting step elimination. It can be also concluded that adding neutralizers, buffer chemicals and some other materials are effective to maintain the pH level for practical application. Trace metals in food waste are not enough but needed for methanogens activation in long term and high loading rate operation. In addition, direct interspecies electron transfer could be much helpful for intermediate refractory organic acids degradation and methanogenesis promotion with additives of conductive materials, which is also discussed and should be studied further in anaerobic digestion of food waste. Based on literature review, a new concept is proposed for further study, suggesting that after being well liquefied with enzyme pre-hydrolysis, food waste could be co-digested with landfill leachate in a high-rate anaerobic reactor stably, resulting in a high bioenergy recovery efficiency. (C) 2018 Elsevier Ltd. All rights reserved
Imaging of the Atomic Structure of All-Inorganic Halide Perovskites
All-inorganic halide perovskites are promising materials for optoelectronic applications. The surface or interface structure of the perovskites plays a crucial role in determining the optoelectronic conversion efficiency, as well as the material stability. A thorough understanding of surface atomic structures of the inorganic perovskites and their contributions to their optoelectronic properties and stability is lacking. Here we show a scanning tunneling microscopy investigation on the atomic and electronic structure of CsPbBr3 perovskite. Two different surface structures with a stripe and an armchair domain are identified, which originates from a complex interplay between Cs cations and Br anions. Our findings are further supported and correlated with density functional theory calculations and photoemission spectroscopy measurements. The stability evaluation of photovoltaic devices indicates a higher stability for CsPbBr3 in comparison with MAPbBr3, which is closely related to the low volatility of Cs from the perovskite surface
Two ultraviolet radiation datasets that cover China
Ultraviolet (UV) radiation has significant effects on ecosystems, environments, and human health, as well as atmospheric processes and climate change. Two ultraviolet radiation datasets are described in this paper. One contains hourly observations of UV radiation measured at 40 Chinese Ecosystem Research Network stations from 2005 to 2015. CUV3 broadband radiometers were used to observe the UV radiation, with an accuracy of 5%, which meets the World Meteorology Organization's measurement standards. The extremum method was used to control the quality of the measured datasets. The other dataset contains daily cumulative UV radiation estimates that were calculated using an all-sky estimation model combined with a hybrid model. The reconstructed daily UV radiation data span from 1961 to 2014. The mean absolute bias error and root-mean-square error are smaller than 30% at most stations, and most of the mean bias error values are negative, which indicates underestimation of the UV radiation intensity. These datasets can improve our basic knowledge of the spatial and temporal variations in UV radiation. Additionally, these datasets can be used in studies of potential ozone formation and atmospheric oxidation, as well as simulations of ecological processes
Weighted covariance matrix estimation
The paper proposes a cross-validated linear shrinkage estimation for population covariance matrices. Moreover we also propose a novel weighted estimator based on the thresholding and shrinkage methods for high dimensional datasets. It is applicable to a wider scope of different structures of covariance matrices. Some theoretical results about the cross-validated shrinkage method and weighted covariance estimation methods are also developed. The finite-sample performance of the proposed methods is illustrated through extensive simulations and real data analysis.Accepted versio
Preparation and characterization of glazed tiles with high quantity of fly-ashes addition
CERAMICS, ISSN 1004-7840, 2/1993, PP.3-1
Research and production of glazed face-bricks made from fine coal ash
JINGDEZHEN’S CERAMICS, ISSN 1001-9545, 1994(TOTAL NO. 64), PP.1-8
Research and production of glazed face-bricks made from fine coal ash
JINGDEZHEN'S CERAMICS, ISSN 1001-9545, 1994(TOTAL NO. 64), PP.1-
Preparation and characterization of glazed tiles with high quantity of fly-ashes addition
CERAMICS, ISSN 1004-7840, 2/1993, PP.3-10
Molecular simulations of phosphonium-based ionic liquid
Compared with imidazolium-based ionic liquids (ILs), phosphonium-based ILs have been proven to be more stable in thermodynamics and less expensive to manufacture. In this work, a kind of phosphonium-based IL, [PC6C6C6C14][Tf2N], was studied under several conditions using molecular dynamics simulations based on both the all-atom force field (AAFF) and the united-atom force field. Liquid density was calculated to validate the force field. Compared with experimental data, good agreement was obtained for the simulated density based on the AAFF. Heat capacities at constant pressure were calculated at several temperatures, and good linear relationships were observed. Self-diffusion coefficients, viscosities and conductivities were also calculated to study the dynamics properties of this IL. The viscosity of this IL at 293K was also compared with experimental data, and the error was in a reasonable range. In order to depict the microstructures of the IL, centre-of-mass and site-to-site radial distribution functions were employed. In addition, spatial distribution functions were investigated to present the more intuitive features
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