A Typha Angustifolia-like MoS2/carbon nanofiber composite for high performance Li-S batteries

A Typha Angustifolia-like MoS2/carbon nanofiber composite as both a chemically trapping agent and redox conversion catalyst for lithium polysulfides has been successfully synthesized via a simple hydrothermal method. Cycling performance and coulombic efficiency have been improved significantly by applying the Typha Angustifolia-like MoS2/carbon nanofiber as the interlayer of a pure sulfur cathode, resulting in a capacity degradation of only 0.09% per cycle and a coulombic efficiency which can reach as high as 99%

Bipartite Graph Pre-training for Unsupervised Extractive Summarization with Graph Convolutional Auto-Encoders

Pre-trained sentence representations are crucial for identifying significant sentences in unsupervised document extractive summarization. However, the traditional two-step paradigm of pre-training and sentence-ranking, creates a gap due to differing optimization objectives. To address this issue, we argue that utilizing pre-trained embeddings derived from a process specifically designed to optimize cohensive and distinctive sentence representations helps rank significant sentences. To do so, we propose a novel graph pre-training auto-encoder to obtain sentence embeddings by explicitly modelling intra-sentential distinctive features and inter-sentential cohesive features through sentence-word bipartite graphs. These pre-trained sentence representations are then utilized in a graph-based ranking algorithm for unsupervised summarization. Our method produces predominant performance for unsupervised summarization frameworks by providing summary-worthy sentence representations. It surpasses heavy BERT- or RoBERTa-based sentence representations in downstream tasks.Comment: Accepted by the 2023 Conference on Empirical Methods in Natural Language Processing (EMNLP 2023

Flameless combustion with liquid fuel: A review focusing on fundamentals and gas turbine application

Flameless combustion has been developed to reduce emissions whilst retaining thermal efficiencies in combustion systems. It is characterized with its distinguished features, such as suppressed pollutant emission, homogeneous temperature distribution, reduced noise and thermal stress for burners and less restriction on fuels (since no flame stability is required). Recent research has shown the potential of flameless combustion in the power generation industry such as gas turbines. In spite of its potential, this technology needs further research and development to improve its versatility in using liquid fuels as a source of energy. In this review, progress toward application of the flameless technique is presented with emphasis on gas turbines. A systematic analysis of the state-of-the-art and the major technical and physical challenges in operating gas turbines with liquid fuels in a flameless combustion mode is presented. Combustion characteristics of flameless combustion are explained along with a thorough review of modelling and simulation of the liquid fuel fed flameless combustion. A special focus is given to the relevant research on applications to the inner turbine burners. The paper is concluded by highlighting recent findings and pointing out several further research directions to improve the flameless combustion application in gas turbines, including in-depth flow and combustion mechanisms, advanced modelling, developed experimental technology and comprehensive design methods aiming at gas turbine flameless combustors

Effects of pore widening vs oxygenation on capacitance of activated carbon in aqueous sodium sulfate electrolyte

The commercial activated carbon has a relatively low specific capacitance in the Na2SO4 electrolyte, which hinder the development of asymmetrical supercapacitors with high voltage. Re-activation and oxidative etching methods were applied to change the pore structure of activated carbon, respectively, to study the capacitive behavior of carbon in the Na2SO4 electrolyte. The pore distributions combining with capacitive properties deduce that 0.85 nm is the threshold diameter of the ion-accessible micropores for hydrated Na+ and SO42−. The specific capacitances of both the carbon materials by re-activation and oxidative etching methods are increased by 40 %, in comparison with the commercial activated carbon. The enhanced capacitive performances of the carbon materials were mainly attributed to the increased ion-accessible specific surface area and pseudocapacitance, respectively. The oxidative etching is a more facile and economical method for practice application. Combining with MnO2 as the positive electrode, the asymmetrical supercapacitor with a high voltage of 1.8 V exhibits a maximum specific cell capacitance of 50 F g–1 and specific energy of 22.5 Wh kg–1

Deoxygenation in anisole decomposition over bimetallic catalysts supported on HZSM-5

This work investigated the deoxygenation reaction in anisole decomposition over HZSM-5 (HZ(25)) zeolite supported bimetallic catalysts to produce benzene, toluene and xylene (BTX). Experiments were performed in order to evaluate the synergistic effect between the two active metals with the focus on the effect of temperature, metal type, and metal loading ratio. Experimental results showed that 1%Ni-1%Mo/HZ(25) led to both the highest BTX yield (i.e. 30.0 wt%) and selectivity (i.e. 83.7%). On the contrary, bimetallic catalysts containing Fe were less effective in promoting the BTX production. It was identified that the optimum temperature for BTX production over 1%Ni-1%Mo/HZ(25) catalysts was 500 °C. Characterization of fresh and spent catalysts showed microcrystal particles of bi-metal loadings highly dispersed on the zeolite surface, and some agglomeration of metallic particles were also observed. Large amount of carbonaceous deposit was observed on the spent catalysts mainly in the form of amorphous. Density Functional Theory (DFT) modelling was carried out in order to study the adsorption energy of anisole and phenol molecules onto Ni-Mo, Ni-Fe and Mo-Fe surfaces; and the interactions between phenol molecule and bimetal surfaces were further analysed. All the analysed bimetal surfaces exhibited strong interactions with the adsorbed molecule. Ni-Mo surface declined electrons energy levels mainly around 1.5 eV in the adsorbate molecule and released the highest adsorption energy; while Ni-Fe and Mo-Fe surface led to more electrons exchange with the adsorbate during the adsorption. The modelling results agreed well with experiments by revealing that the strong binding between phenolic compounds (Phs) and the Ni-Mo based catalysts bimetal surface would lead to a higher BTX production in the deoxygenation reaction in the decomposition of anisole

A motivação e a cooperação desportiva no atletismo

A educação física para as crianças e jovens, consiste num período crítico do percurso educacional, dado que pode promover o seu futuro envolvimento desportivo e decisões acerca da sua participação em actividades físicas futuras. Deste modo, o estudo de modelos ou a identificação de determinantes psicológicas, assume-se como uma necessidade para o desenvolvimento de intervenções adequadas para o aumento dos níveis de actividade física. A orientação motivacional e o sentido de cooperação, são factores de primordial importância na coordenação e no sucesso de diversas actividades humanas, e de impacto bem visível no âmbito do desporto. Assim, o presente trabalho destina-se à verificação das possibilidades de correlação entre orientação motivacional e sentido de cooperação em participantes de uma mesma modalidade desportiva, neste caso o atletismo, para o que se utilizou o “Task and Ego Orientation in Sport Questionnaire” (TEOSQ), na versão portuguesa desenvolvido por Duda e colaboradores (1989, 1992, citado por Cruz, 1996), de Fonseca e Brito, (2006) e o Cuestionario de Cooperación Deportiva (CCD), igualmente na versão portuguesa, de Almeida, Garcia-Mas, Lameiras, Olmedílla, Ortega, Martins, (2006). A amostra foi constituída por 52 atletas, onde 51,9% dos sujeitos são do sexo masculino e 48,1% são do sexo feminino, de diversas especialidades.ABSTRACT: Physical education for children and young people is a critical period of the educational process, as this selling may promote individual`s futures involvement in physical activity and sports, and may influence young persons decisions about future sport and activity participation. Therefore, the study of models and identification of psychology variables, underscores the need of developing interventions to increase physical activity. The motivational orientation and the direction of cooperation are factors of primordial importance in the coordination and the success of diverse activities human beings, and well visible impact in the scope of the sport. Thus, the present work destines it verification of the possibilities of correlation between the motivational orientation an direction of cooperation in participants of one same porting modality, in this in case that the track and field so that it was used “Task and Ego Orientation in Sport Questionnaire” (TEOSQ), in the Portuguese version developed by Duda and Collaborators (1989, 1992, cited for Cruz, 1996), and the Cuestionario de Cooperación Deportiva (CCD),equally in the Portuguese version of Almeida, Garcia-Mas, Lameiras, Olmedílla, Ortega, Martins, (2006). A sample of 52 athletes, of diverse modalities

Study on the evaluation of the clinical effects of traditional chinese medicine in heart failure by complex intervention: protocol of SECETCM-HF

<p>Abstract</p> <p>Background</p> <p>Experts in Traditional Chinese Medicine (TCM) have studied the TCM subject of the pathogenesis of heart failure (HF) for several decades. As a result, the general idea is <it>ben </it>deficiency and <it>biao </it>excess. However, the clinical evaluation system which combined the TCM and western medicine in HF has not been developed yet. The objective is to establish the evaluation index system for the integration of TCM and western medicine. The evaluation indexes which include TCM items will specify the research design and methods.</p> <p>Methods</p> <p>Nine medical centers in different cities in China will participate in the trial. A population of 340 patients with HF will be enrolled through a central randomized system for different test groups. Group A will be treated with only western medicine, while group B with western and Chinese medicine together. The study will last for 12 months from the date of enrollment. The cardiovascular death will be the primary outcome.</p> <p>Discussion</p> <p>By putting the protocol into practice, the clinical effects of TCM for HF will be identified scientifically, objectively as well as rationally. The proper index system which built in the study will be helpful for the clinical effect expression of HF by integrated medicine in future.</p> <p>Trial Registration</p> <p>ChiCTR-TRC-00000059</p

Rice Soluble Starch Synthase I: Allelic Variation, Expression, Function, and Interaction With Waxy

Starch, which is composed of amylose and amylopectin, is the key determinant of rice quality. Amylose is regulated by the Waxy (Wx) gene, whereas amylopectin is coordinated by various enzymes including eight soluble starch synthases (SSSs), of which SSSI accounts for ∼70% of the total SSS activity in cereal endosperm. Although great progress has been made in understanding SSSI gene expression and function, allelic variation and its effects on gene expression, rice physicochemical properties and qualities, and interactions with the Wx gene remain unclear. Herein, SSSI nucleotide polymorphisms were analyzed in 165 rice varieties using five distinct molecular markers, three of which reside in an SSSI promoter and might account for a higher expression of the SSSIi allele in indica ssp. than of the SSSIj allele in japonica ssp. The results of SSSI promoter-Beta-Glucuronidase (β-GUS) analysis were consistent with the expression results. Moreover, analysis of near isogenic lines (NILs) in the Nipponbare (Nip) background showed that Nip (SSSIi) and Nip (SSSIj) differed in their thermal properties, gel consistency (GC), and granule crystal structure. Knockdown of SSSI expression using the SSSI-RNA interference (RNAi) construct in both japonica and indica backgrounds caused consistent changes in most tested physicochemical characteristics except GC. Moreover, taste value analysis (TVA) showed that introduction of the SSSI allele in indica or knockdown of SSSI expression in japonica cultivars significantly reduced the comprehensive taste value, which was consistent with the superior taste of japonica against indica. Furthermore, to test the potential interaction between SSSI and different Wx alleles, three NILs within the Wx locus were generated in the indica cv. Longtefu (LTF) background, which were designated as LTF (Wxa), LTF (Wxb), and LTF (wx). The SSSI-RNAi construct was also introduced into these three NILs, and physiochemical analysis confirmed that the knockdown of SSSI significantly increased the rice apparent amylose content (AAC) only in the Wxa and Wxb background and caused different changes in GC in the NILs. Therefore, the effect of SSSI variation on rice quality also depends on its crosstalk with other factors, especially the Wx gene. These findings provide fundamental knowledge for future breeding of rice with premium eating and cooking qualities