Evolving temperature field in a fossil subduction channel during the transition from subduction to collision (Tauern Window, Eastern Alps)

We investigate the evolution of the three-dimensional thermal structure of a palaeo-subduction channel exposed in the Penninic units of the central Tauern Window (Eastern Alps). Structural and petrological observations reveal a sheath fold with an amplitude of some 20 km that formed under high-Pconditions (similar to 2 GPa). The fold is a composite structure that isoclinally folded the thrust of an ophiolitic nappe derived from Alpine Tethys Ocean onto a unit of the distal European continental margin, also affected by the high-Pconditions. This structural assemblage is preserved between two younger domes at either end of the Tauern Window. The domes deform isograds of theT-dominated Barrovian metamorphism that itself overprints the high-Pmetamorphism partly preserved in the sheath fold. Using Raman spectroscopy on carbonaceous material (RSCM), we are able to distinguish peak-temperature domains related to the original subduction metamorphism from domains associated with the later temperature-dominated (Barrovian) metamorphism. The distribution of RSCM temperatures in the Barrovian domain indicates a lateral and vertical decrease of peak temperature with increasing distance from the centres of the thermal domes. This represents a downward increase of palaeo-temperature, in line with previous studies. However, we observe the opposite palaeo-temperature trend in the lower limb of the sheath fold, namely an upward increase. We interpret this inverted palaeo-temperature domain as the relic of a subduction-related temperature field. Towards the central part of the sheath fold's upper limb, RSCM temperatures increase to a maximum of similar to 520 degrees C. Further upsection in the hangingwall of the sheath fold, palaeo-peak temperatures decrease to where they are indistinguishable from the peak temperatures of the overprinting Barrovian metamorphism. Peak-temperature contours of the subduction-related metamorphism are oriented roughly parallel to the folded nappe contacts and lithological layering. The contours close towards the northern, western and eastern parts of the fold, resulting in an eye-shaped, concentric pattern in cross-section. The temperature contour geometry therefore mimics the fold geometry itself, indicating that these contours were also folded in a sheath-like manner. We propose that this sheath-like pattern is the result of a two-stage process that reflects a change of the mode of nappe formation in the subduction zone from thrusting to fold nappe formation. First, thrusting of a hot oceanic nappe onto a colder continental nappe created an inverted peak-thermal gradient. Second, sheath folding of this composite nappe structure together with the previously established peak-temperature pattern during exhumation. This pattern was preserved because temperatures decreased during retrograde exhumation metamorphism and remained less than the subduction-related peak temperatures during the later Barrovian overprint. The fold ascended with diapir-like kinematics in the subduction channel

Runoff sources and land cover change in the Amazon : an end-member mixing analysis from small watersheds

Author Posting. © The Author(s), 2011. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Biogeochemistry 105 (2011): 7-18, doi:10.1007/s10533-011-9597-8.The flowpaths by which water moves from watersheds to streams has important consequences for the runoff dynamics and biogeochemistry of surface waters in the Amazon Basin. The clearing of Amazon forest to cattle pasture has the potential to change runoff sources to streams by shifting runoff to more surficial flow pathways. We applied end member mixing analysis (EMMA) to ten small watersheds throughout the Amazon in which solute composition of streamwater and groundwater, overland flow, soil solution, throughfall and rainwater were measured, largely as part of the Large-Scale Biosphere-Atmosphere Experiment in Amazonia. We found a range in the extent to which streamwater samples fell within the mixing space determined by potential flowpath end members, suggesting that some water sources to streams were not sampled. The contribution of overland flow as a source of stream flow was greater in pasture watersheds than in forest watersheds of comparable size. Increases in overland flow contribution to pasture streams ranged in some cases from 0% in forest to 27 to 28% in pasture and were broadly consistent with results from hydrometric sampling of Amazon forest and pasture watersheds that indicate 17- to 18-fold increase in the overland flow contribution to stream flow in pastures. In forest, overland flow was an important contribution to stream flow (45 to 57%) in ephemeral streams where flows were dominated by stormflow. Overland flow contribution to stream flow decreased in importance with increasing watershed area, from 21 to 57% in forest and 60 to 89% in pasture watersheds 100 ha. Soil solution contributions to stream flow were similar across watershed area and groundwater inputs generally increased in proportion to decreases in overland flow. Application of EMMA across multiple watersheds indicated patterns across gradients of stream size and land cover that were consistent with patterns determined by detailed hydrometric sampling.This work was supported by National Science Foundation (DEB-0315656, DEB-0640661), the NASA LBA Program (NCC5-686, NCC5-69, NCC5-705, NNG066E88A) and by grants from Brazilian agencies FAPESP (03/13172-2) and CNPq (20199/2005-5)