45 research outputs found

    Observation of exclusive DVCS in polarized electron beam asymmetry measurements

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    We report the first results of the beam spin asymmetry measured in the reaction e + p -> e + p + gamma at a beam energy of 4.25 GeV. A large asymmetry with a sin(phi) modulation is observed, as predicted for the interference term of Deeply Virtual Compton Scattering and the Bethe-Heitler process. The amplitude of this modulation is alpha = 0.202 +/- 0.028. In leading-order and leading-twist pQCD, the alpha is directly proportional to the imaginary part of the DVCS amplitude.Comment: 6 pages, 5 figure

    Q2Q^2 Dependence of Quadrupole Strength in the γpΔ+(1232)pπ0\gamma^*p\to\Delta^+(1232)\to p \pi^0 Transition

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    Models of baryon structure predict a small quadrupole deformation of the nucleon due to residual tensor forces between quarks or distortions from the pion cloud. Sensitivity to quark versus pion degrees of freedom occurs through the Q2Q^2 dependence of the magnetic (M1+M_{1+}), electric (E1+E_{1+}), and scalar (S1+S_{1+}) multipoles in the γpΔ+pπ0\gamma^* p \to \Delta^+ \to p \pi^0 transition. We report new experimental values for the ratios E1+/M1+E_{1+}/M_{1+} and S1+/M1+S_{1+}/M_{1+} over the range Q2Q^2= 0.4-1.8 GeV2^2, extracted from precision p(e,ep)πp(e,e 'p)\pi^{\circ} data using a truncated multipole expansion. Results are best described by recent unitary models in which the pion cloud plays a dominant role.Comment: 5 pages, 5 figures, 1 table. To be published in Phys. Rev. Lett. (References, figures and table updated, minor changes.

    Tensor Polarization of the phi meson Photoproduced at High t

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    As part of a measurement of the cross section of ϕ\phi meson photoproduction to high momentum transfer, we measured the polar angular decay distribution of the outgoing K+K^+ in the channel ϕK+K\phi \to K^+K^- in the ϕ\phi center-of-mass frame (the helicity frame). We find that s-channel helicity conservation (SCHC) holds in the kinematical range where tt-channel exchange dominates (up to t2.5-t \sim 2.5 GeV2^2 for EγE_{\gamma}=3.6 GeV). Above this momentum, uu-channel production of a ϕ\phi meson dominates and induces a violation of SCHC. The deduced value of the ϕNN\phi NN coupling constant lies in the upper range of previously reported values.Comment: 6 pages; 5 figure

    Le projet AteCop : méthodologie et premiers résutats [sur l’atelier de copie d'Henri Foucault]

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    Page du blog Hypothèses consacrée au séminaire AteCop.Présentation des objectifs et de la méthodologie du projet AteCop (CMBV-IREMUS) sur les premiers ateliers de copistes français (ca. 1670-1730). Exposé des premiers résultats concernant l'atelier de copistes de Henri Foucault (Paris, ca. 1690-1720)

    The AteCop project : early music copyists in France, up to ca 1730.

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    Launched in 2021, the AteCop project aims to identify the music copyists active inFrance until around 1730, their workshop, if any, and their production. After recallingthe contributions of some scholars (C. Massip, D. Herlin, L. Rosow, L. Sawkins, B. Hertz,S. Bouissou, B. Gustafson, J. H. Heyer in particular), the presentation specifies themethodology implemented, presents the first results and the products planned tobe delivered, and concludes with a call to foreign musicologists likely to become referentsof this project.Lancé en 2021, le projet AteCop a pour objectif d'identifier les copistes de musique actifs en France jusque vers 1730, leur atelier éventuel et leur production. Après avoir rappelé les contributions de quelques chercheurs (C. Massip, D. Herlin, L. Rosow, L. Sawkins, B. Hertz, S. Bouissou, B. Gustafson, J. H. Heyer en particulier), la présentation précise la méthodologie mise en œuvre, présente les premiers résultats, la méthodologie mise en œuvre, les produits prévus, et se conclut par un appel aux musicologues étrangers susceptibles de devenir des référents de ce projet

    Développement de nouveaux catalyseurs à base de ruthénium pour l'oxydation : vers des systèmes photoactivables.

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    Ce travail de thèse repose sur le développement de nouveaux catalyseurs d'oxydation utilisant les principes de la chimie verte. Dans un premier temps, afm d'exploiter les propriétés d'induction des complexes tris-diimine de ruthénium en catalyse asymétrique, des complexes hétérodinucléaires Ru-Mn et Ru-Zn ont été synthétisés et caractérisés. Ces complexes sont constitués de l'association d'une entité chirale de ruthénium et d'un fragment de type Mn- ou Zn-salen. Une espèce Ru(II)-Mn(IV) a notamment été caractérisée et un transfert très efficace d'électrons du centre ruthénium excité vers le centre manganèse a également été mis en évidence. Par contre, leur activité catalytique lors d'oxydation d'alcènes s'est avérée être relativement modeste. Dans la seconde partie, nous nous sommes attachés à exploiter simultanément les propriétés photosensibles et catalytiques des complexes de ruthénium. Ainsi, des systèmes homodinucléaires ont été synthétisés et également complètement caractérisés. Ces systèmes se sont montrés particulièrement efficaces lors de l'oxydation de sulfures sous irradiation lumineuse, en utilisant l'eau comme seule source d'atome d'oxygène et un sel ce Co(III) comme accepteur d'électron. Dans le contexte du développement d'une chimie plus respectueuse de l'environnement, nous avons montré que la combinaison d'un photosensiblisateur et de l'énergie lumineuse permettait d'utiliser des conditions douces pour réaliser des réactions d'oxydation.This the sis deals with the development of new homo and heterodinuclear complexes. At fIrst, with the objective to use chiral properties of tris-diimine ruthenium complexes in asymmetric catalysis, modifIed manganese salen complexes constituted by the assembly of a ruthenium and Mn or Zn-salen fragments were synthesized and fully characterized. More particularly, a Ru(II)-Mn(IV) species was characterized and a very efficient electron transfer has been also observed from the excited state of the ruthenium to the manganese. ln the second part of the thesis, the photo sensitive and the catalytic properties of ruthenium complexes were both associated within a unique complex. Two chromophore catalyst dyad families were synthesized and fully characterized. Both of them showed high abilities to convert sulfIdes into sulfoxides under light exposure, using water as the only source of oxygen atom and a Co(III) salt as electron acceptor. ln the context of sustainable development, we have shown that the association of a photosensitizer and solar energy allow soft conditions to perform oxidation reactions.GRENOBLE1-BU Sciences (384212103) / SudocSudocFranceF

    Le médecin généraliste face au diagnostic d'hypertension artérielle (Enquête qualitative auprès de médecins généralistes d'Ille et Vilaine)

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    RENNES1-BU Santé (352382103) / SudocPARIS-BIUM (751062103) / SudocSudocFranceF

    Organic Solvent-Free Olefins and Alcohols (ep)oxidation Using Recoverable Catalysts Based on [PM12O40]3− (M = Mo or W) Ionically Grafted on Amino Functionalized Silica Nanobeads

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    International audienceCatalyzed organic solvent-free (ep)oxidation were achieved using H3PM12O40 (M = Mo or W) complexes ionically grafted on APTES-functionalized nano-silica beads obtained from straightforward method (APTES = aminopropyltriethoxysilane). Those catalysts have been extensively analyzed through morphological studies (Dynamic Light Scattering (DLS), TEM) and several spectroscopic qualitative (IR, multinuclear solid-state NMR) and quantitative (1H and 31P solution NMR) methods. Interesting catalytic results were obtained for the epoxidation of cyclooctene, cyclohexene, limonene and oxidation of cyclohexanol with a lower [POM]/olefin ratio. The catalysts were found to be recyclable and reused during three runs with similar catalytic performances

    Complexation to [Ru(bpy)2]2+: the trick to functionalize 3,3′-disubstituted-2,2′-bipyridine

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    International audienceWhile many papers reported the synthesis and chemical transformations of x,x′-disubstituted-2,2′-bipyridine with x = 4, 5 or 6, this is not the case when x = 3. Though, such 3,3′-disubstituted-2,2′-bipyridines would be a useful building block for the design of new original complexes. Here we report the results of our investigation concerning the synthesis of members of this family. This study led to the formation of several [(2,2′-bipyridine)2Ru(3,3′-dialkylated-2,2′-bipyridine)]2+ complexes highlighting a surprising chemical behaviour of the 3,3′-disubstituted-2,2′-bipyridine ligand compared to its 4,4′, 5,5′ and 6,6′-homologues
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