285 research outputs found
Defects drive the tribocharging strength of PTFE: An ab-initio study
If polytetrafluoroethylene (PTFE), commonly known as Teflon, is put into contact and rubbed against another material, almost surely it will be more effective than its counterpart in collecting negative charges. This simple, basic property is captured by the so called triboelectric series, where PTFE ranks extremely high, and that qualitatively orders materials in terms of their ability to electrostatically charge upon contact and rubbing. However, while classifying materials, the series does not provide an explanation of their triboelectric strength, besides a loose correlation with the workfunction. Indeed, despite being an extremely familiar process, known from centuries, tribocharging is still elusive and not fully understood.
In this work we employ density functional theory to look for the origin of PTFE tribocharging strength. We study how charge transfers when pristine or defective PTFE is put in contact with different clean and oxidized metals. Our results show the important role played by defects in enhancing charge transfer. Interestingly and unexpectedly our results show that negatively charged chains are more stable than neutral ones, if slightly bent. Indeed deformations can be easily promoted in polymers as PTFE, especially in tribological contacts. These results suggest that, in designing materials in view of their triboelectric properties, the characteristics of their defects could be a performance determining factor
Impact of ‘Ideal Clinic’ implementation on patient waiting time in primary healthcare clinics in KwaZulu-Natal Province, South Africa: A before-and-after evaluation
Background. Long waiting times are a major source of dissatisfaction for patients attending public healthcare facilities in South Africa (SA). The National Department of Health has identified this as one of six priority areas for improvement. Health system-strengthening (HSS) interventions to improve patient waiting time are being implemented in public health facilities across SA as part of the ‘Ideal Clinic’ model. The effect of these interventions on patient waiting time needs to be assessed and evidence generated for system improvement.Objectives. To determine the effect of Ideal Clinic HSS intervention on patient waiting time in public health facilities in Amajuba District, KwaZulu-Natal Province, SA.Methods. We implemented 12 months of HSS activity, including facility reorganisation and patient appointment scheduling. The major outcome of interest was the total time spent by patients in a facility during a visit. This was calculated as the median time spent, obtained through a ‘before-and-after’ intervention survey. Univariate and multivariate factors associated with waiting time were determined.Results. A total of 1 763 patients from nine clinics were surveyed before and after the intervention (n=860 at baseline and n=903 at follow-up). The median overall waiting time after the intervention was 122 minutes (interquartile range (IQR) 81 - 204), compared with 116 minutes (IQR 66 - 168) before (p<0.05). Individual facility results after the intervention were mixed. Two facilities recorded statistically significant reductions in patient waiting time, while three recorded significant increases (p<0.05). Patient load per nurse, type of service received and time of arrival in facilities were all independently associated with waiting time. Patients’ arrival patterns, which were determined by appointment scheduling, played a significant role in the results obtained.Conclusions. Implementation of the Ideal Clinic model in the selected facilities led to changes in patient waiting time. Observed changes were positive when a clinic appointment system was successfully implemented and negative when this was unsuccessful. We recommend strengthening of the appointment system component of the Ideal Clinic model to improve patient waiting time. Assessing facility waiting time performance in terms of average time spent by patients during a clinic visit was shown to be inadequate, and we suggest the inclusion of ‘proportion of clients who spent above the national waiting time threshold during their visit’ as a sensitive measure of performance
25 hydroxyvitamin D deficiency and its relationship to autoimmune thyroid disease in the elderly
Background: Low 25(OH) vitamin D levels have been associated with several autoimmune diseases and recently with autoimmune thyroiditis (AT). The aim of the study was to investigate the association of AT with low 25(OH) vitamin D levels in the elderly. Methods: One hundred sixty-eight elderly subjects (mean age: 81.6 ± 9.4 years) were enrolled. Serum levels of 25(OH) vitamin D, anti-thyroid peroxidase (TPO-Ab), anti-thyroglobulin (TG-Ab) antibodies, free triiodothyronine (FT3), free thyroxine (FT4) and thyroid stimulating hormone (TSH) were measured. Results: The prevalence of AT was significantly higher in subjects with vitamin D deficiency (25(OH) vitamin D < 20 ng/mL) when compared with subjects with normal 25(OH) vitamin D (25(OH) vitamin D ≥ 20 ng/mL) levels (28% vs. 8%, respectively, p = 0.002). Patients with AT and vitamin D deficiency had a comparable hormonal profile compared to patients with AT and vitamin D sufficiency in terms of TSH (p = 0.39), FT3 (p = 0.30), FT4 (p = 0.31), TG-Ab (0.44) and TPO-Ab (0.35). Interestingly, a significant correlation between 25(OH) vitamin D and TPO-Ab (r = −0.27, p = 0.03) and FT3 (r = 0.35, p = 0.006) has been found in subjects with AT while no correlation was found between 25(OH) vitamin D levels and TG-Ab (r = −0.15, p = 0.25), TSH (r = −0.014, p = 0.09) and FT4 (r = 0.13, p = 0.32). Conclusions: These findings suggest that vitamin D deficiency was significantly associated with AT in the elderly. Therefore, the screening for AT should be suggested in subjects with vitamin D deficiency
Friction of the surface plasmon by high-energy particle-hole pairs: Are memory effects important?
We show that the dynamics of the surface plasmon in metallic nanoparticles
damped by its interaction with particle-hole excitations can be modelled by a
single degree of freedom coupled to an environment. In this approach, the fast
decrease of the dipole matrix elements that couple the plasmon to particle-hole
pairs with the energy of the excitation allows a separation of the Hilbert
space into low- and high-energy subspaces at a characteristic energy that we
estimate. A picture of the spectrum consisting of a collective excitation built
from low-energy excitations which interacts with high-energy particle-hole
states can be formalised. The high-energy excitations yield an approximate
description of a dissipative environment (or "bath") within a finite confined
system. Estimates for the relevant timescales establish the Markovian character
of the bath dynamics with respect to the surface plasmon evolution for
nanoparticles with a radius larger than about 1 nm.Comment: 8 pages, 1 figure; see also cond-mat/070372
Nonequilibrium Electron Interactions in Metal Films
Ultrafast relaxation dynamics of an athermal electron distribution is
investigated in silver films using a femtosecond pump-probe technique with 18
fs pulses in off-resonant conditions. The results yield evidence for an
increase with time of the electron-gas energy loss rate to the lattice and of
the free electron damping during the early stages of the electron-gas
thermalization. These effects are attributed to transient alterations of the
electron average scattering processes due to the athermal nature of the
electron gas, in agreement with numerical simulations
Continuum limit of amorphous elastic bodies: A finite-size study of low frequency harmonic vibrations
The approach of the elastic continuum limit in small amorphous bodies formed
by weakly polydisperse Lennard-Jones beads is investigated in a systematic
finite-size study. We show that classical continuum elasticity breaks down when
the wavelength of the sollicitation is smaller than a characteristic length of
approximately 30 molecular sizes. Due to this surprisingly large effect
ensembles containing up to N=40,000 particles have been required in two
dimensions to yield a convincing match with the classical continuum predictions
for the eigenfrequency spectrum of disk-shaped aggregates and periodic bulk
systems. The existence of an effective length scale \xi is confirmed by the
analysis of the (non-gaussian) noisy part of the low frequency vibrational
eigenmodes. Moreover, we relate it to the {\em non-affine} part of the
displacement fields under imposed elongation and shear. Similar correlations
(vortices) are indeed observed on distances up to \xi~30 particle sizes.Comment: 28 pages, 13 figures, 3 table
Characterizing the double-sided cascade of care for adolescents living with HIV transitioning to adulthood across Southern Africa
INTRODUCTION: As adolescents and young people living with HIV (AYLH) age, they face a "transition cascade," a series of steps associated with transitions in their care as they become responsible for their own healthcare. In high-income countries, this usually includes transfer from predominantly paediatric/adolescent to adult clinics. In sub-Saharan Africa, paediatric HIV care is mostly provided in decentralized, non-specialist primary care clinics, where "transition" may not necessarily include transfer of care but entails becoming more autonomous for one's HIV care. Using different age thresholds as proxies for when "transition" to autonomy might occur, we evaluated pre- and post-transition outcomes among AYLH. METHODS: We included AYLH aged <16 years at enrolment, receiving antiretroviral therapy (ART) within International epidemiology Databases to Evaluate AIDS Southern Africa (IeDEA-SA) sites (2004 to 2017) with no history of transferring care. Using the ages of 16, 18, 20 and 22 years as proxies for "transition to autonomy," we compared the outcomes: no gap in care (≥2 clinic visits) and viral suppression (HIV-RNA <400 copies/mL) in the 12 months before and after each age threshold. Using log-binomial regression, we examined factors associated with no gap in care (retention) in the 12 months post-transition. RESULTS: A total of 5516 AYLH from 16 sites were included at "transition" age 16 (transition-16y), 3864 at 18 (transition-18y), 1463 at 20 (transition-20y) and 440 at 22 years (transition-22y). At transition-18y, in the 12 months pre- and post-transition, 83% versus 74% of AYLH had no gap in care (difference 9.3 (95% confidence interval (CI) 7.8 to 10.9)); while 65% versus 62% were virally suppressed (difference 2.7 (-1.0 to 6.5%)). The strongest predictor of being retained post-transition was having no gap in the preceding year, across all transition age thresholds (transition-16y: adjusted risk ratio (aRR) 1.72; 95% CI (1.60 to 1.86); transition-18y: aRR 1.76 (1.61 to 1.92); transition-20y: aRR 1.75 (1.53 to 2.01); transition-22y: aRR 1.47; (1.21 to 1.78)). CONCLUSIONS: AYLH with gaps in care need targeted support to prevent non-retention as they take on greater responsibility for their healthcare. Interventions to increase virologic suppression rates are necessary for all AYLH ageing to adulthood
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