カシノナガキクイムシの飛翔と寄主選択に関する生態学的研究

京都大学0048新制・課程博士博士(農学)甲第22787号農博第2430号新制||農||1081(附属図書館)学位論文||R2||N5307(農学部図書室)京都大学大学院農学研究科森林科学専攻(主査)教授 井鷺 裕司, 教授 森 直樹, 准教授 大澤 直哉学位規則第4条第1項該当Doctor of Agricultural ScienceKyoto UniversityDFA

ZnO/CdS Bilayer used for Electrode in Photovoltaic Device

In this article we present the fabrication and characterization of the nanoporous ZnO and/or ZnO/CdS thin films onto indium doped-tin oxide (ITO) substrates, based on the thermal evaporation technique followed by thermal treatment. The preparation method was relatively simple and low-cost for large scale uniform coating to produce clean, dense and strong adhesion to substrate thin films. The nanostructured ZnO and ZnO/CdS thin films were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). The nanostructured ZnO/CdS bilayer film was used in a photo-electrochemical (PEC) cell as a working electrode and a Pt net as a counter electrode. The results show that the photovoltaic cell with nanostructured ZnO/CdS bilayer film electrode has significantly improved photoelectric capability in comparison with that of ZnO electrode

Nanocomposite Thin Film TiO2/CdS Electrodes Prepared by Thermal Evaporation Process for Photovoltaic Applications

The incorporation of cadmium sulfide (CdS) into TiO2 nanoparticle thin films was investigated. The nanoparticle TiO2 thin film onto an indium doped–tin oxide (ITO) substrate was deposited by Electron Beam Deposition (EBD) combined with thermal process. Then a CdS thin film was vacuum-deposited onto the pre-deposited TiO2 film by a thermal evaporation technique. The obtained TiO2/CdS was characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM). The TiO2/CdS nanocomposite film was used in a photo-electrochemical (PEC) cell as a working electrode and a platinum electrode as a counter electrode. The electrolyte solution contains 1 M KCl and 0.1M Na2S. The results show that the cell with TiO2/CdS composite film electrode has significantly improved photoelectric capability in comparison with that of the pure TiO2 thin films

Exploring Value Co-Destruction Process in Customer Interactions with AI-Powered Mobile Applications

Background: Mobile applications have emerged as important touchpoints for addressing service requests and optimizing human resources. Within the service industry, the integration of artificial intelligence (AI) into these applications has enabled the inference of product demand, provision of personalized service offers, and enhancement of overall firm value. Customers now engage with these apps to stay informed, seek guidance, and make purchases. It is important to recognize that the interactive and human-like qualities of AI can either foster the co-creation of value with customers or potentially lead to the co-destruction of customer value. Although prior research has examined the process of value co-creation, the present study aims to investigate the underlying factors contributing to the value co-destruction process, specifically within AI-powered mobile applications. Method: Our research employs topic modelling and content analysis to examine the value co-destruction process that occurs when customers engage with AI apps. We analyze 7,608 negative reviews obtained from eleven AI apps available on Google Play and App Store AI apps. Results: Our findings reveal six distinct types of value - utilitarian, hedonic, symbolic, social, epistemic, and economic value - that can be co-destroyed during the process. System failure, self-threat and privacy violation are some contributing factors to this value co-destruction process. These values change over time and vary depending on the type of app. Conclusion: Theoretically, our findings extend the concept of value co-destruction in the context of AI apps. We also offer practical recommendations for designing an AI app in a more service-friendly way

Effect of Annealing Temperature on the Li+^{ + } Ionic Conductivity of La0.67−x_{0.67 - x}Li3x_{3x}TiO3_{3 }

Perovskite La0.67-xLi3xTiO3 with x = 0.10, 0.11, 0.12 and 0.13 were firstly annealed at 800 oC then treated by reactive milling, followed by post-annealing at temperatures from 1100 to 1200oC. The crystalline structure of grain and grain-boundary were characterized by XRD and SEM. The impedance measurements showed that nanocrystalline La0.67-xLi3xTiO3 after being annealed at 1150 oC possessed a grain conductivity as high as 1.3×10-3 S.cm-1. The grain-boundary conductivity was enhanced one order in magnitude after annealing at temperature higher 1100oC and consists of 5.8×10-5 S.cm-1. The results have also showed the limitation of the adiabatic thermal treatment for the improvement of the grain-boundary conductivity and suggested the way to overcome the limitation by rapidly cooling the samples from the high temperature to room temperature

Categorizing Young Facebook Users Based On Their Differential Preference of Social Media Heuristics: A Q-Methodology Approach

Background: Social media have become an integral part of our modern society by providing platforms for users to create and exchange news, ideas, and information. The increasing use of social media has raised concerns about the reliability of the shared information, particularly information that is generated from anonymous users. Though prior studies have confirmed the important roles of heuristics and cues in the users’ evaluation of trustworthy information, there has been no research–to our knowledge–that categorized Facebook users based on their approaches to evaluating information credibility. Method: We employed Q-methodology to extract insights from 55 young Vietnamese users and to categorize them into different groups based on the distinct sets of heuristics that they used to evaluate the trustworthiness of online information on Facebook. Results: We identified four distinct types of young Facebook user groups that emerged based on their evaluation of online information trustworthiness. When evaluating online information trustworthiness on Facebook, these user groups assigned priorities differently to the characteristics of the online content, its original source, and the sharers or aggregators. We named these groups: (1) the balanced analyst, (2) the critical analyst, (3) the source analyst, and (4) the social network analyst. Conclusion: The findings offer insights that contribute to information processing literature. Moreover, marketing practitioners who aim to disseminate information effectively on social networks should take these user groups’ perspectives into consideration

Using Solvent Vapor Annealing for the Enhancement of the Stability and Efficiency of Monolithic Hole-conductor-free Perovskite Solar Cells

In the last few years, perovskite solar cells have attracted enormous interest in the photovoltaic community due to their low cost of materials, tunable band gap, excellent photovoltaic properties and easy process ability at low temperature. In this work, we fabricated hole-conductor-free carbon-based perovskite solar cells with the monolithic structure: glass/FTO/bl-TiO$_{2}$/(mp-TiO$_{2}$/mp-ZrO$_{2}$/mp-carbon) perovskite. The mixed 2D/3D perovskite precursor solution composed of PbI$_{2}$, methylammonium iodide (MAI), and 5-ammoniumvaleric acid iodide (5-AVAI) was drop-casted through triple mesoporous TiO$_{2}$/ZrO$_{2}$/carbon electrode films. We found that the isopropyl alcohol (IPA) solvent vapor annealing strongly influenced on the growth of mixed 2D/3D perovskite on triple mesoscopic layers. It resulted in the better pore filling, better crystalline quality of perovskite layer, thus the improved stability and efficiency of perovskite solar cell was attributed to lower defect concentration and reduced recombination

Hydrothermal Synthesis and Enhanced Photocatalytic Activity of TiO2_{2}-Fe@CNTs Nanocomposite for Methylene Blue Degradation under Visible Light Irradiation

TiO2 is one of the most attractive metal oxides because of the excellent chemical and photocatalytic properties. However, a problem in the application of TiO2 is the large band gap energy of 3.2 eV, corresponding to its photocatalytic activity under UV-light irradiation of wavelengths 387 nm. In this work, TiO2 nanoparticles doped with iron were grown on the surface of functionalized carbon nanotubes (TiO2-Fe@CNTs) to expand the photoabsorbance of the nanocomposite materials in the visible light region and improve their photocatalytic activity. TiO2-Fe@CNTs nanocomposite materials were synthesized by hydrothermal route in Teflon-sealed autoclave at 180oC for 10h. The FE-SEM and X-Ray diffraction measurements were taken for morphology and structural analysis of TiO2 nanoparticles doped with Fe coating on CNTs. The effects of the iron and CNTs on the enhanced photocatalytic activity for methylene blue degradation under AM 1.5 illumination of 100 mW.cm−2 were investigated

EFFECTS OF SUBSTITUENTS ON CH BOND DISSOCIATION ENTHALPIES OF ENT-KAURANE DITERPENOIDS: A DFT STUDY

C-H bond dissociation enthalpies (BDEs) of seven ent-kaurane diterpenoids extracted from Croton tonkinensis Gagnep. have been investigated by using density functional theory (DFT) method. The calculations were performed at the M05-2X/6-31+G(d) level of theory. Additionally, insight into the effects of different substituents including –NH2, –OH, –NO2, –SH, –CN, –Cl, –CONH2, –CH-(CH3)2, –NHCOCH3, –OCOCH3 and –C2H5 on BDE have also been provided. The results showed that the BDE value of ent-16(S)-18-acetoxy-7b-hydroxykaur-15-one compound is lowest, being 83.5 kcal/mol. Among substituents binding at C16 position of this molecule, –NH2 has the most remarkable influence on the BDE (C-H) value. Indeed, the BDE of C16-H significantly decreases from 83.5 to 68.4 kcal/mol when replacing –CH3 group by –NH2 one at the C16 position. The obtained results may provide more information for organic synthesis of ent-kaurane based – novel antioxidant compounds