Room-Temperature Alternative to the Arbuzov Reaction: The Reductive Deoxygenation of Acyl Phosphonates

The reductive deoxygenation of acyl phosphonates using a Wolff−Kishner-like sequence is described. This transformation allows direct access to alkyl phosphonates from acyl phosphonates at room temperature. The method can be combined with acyl phosphonate synthesis into a one pot, four-step procedure for the conversion of carboxylic acids into alkyl phosphonates. The methodology works well for a variety of aliphatic acids and shows a functional group tolerance similar to that of other hydrazone-forming reactions

Effects of Hyperbaric Hypoxia on Some Enzyme Systems in the Mammalian Liver

The metabolic effects of hypobaric hypoxic stress on the mammalian liver were studied. The lactate dehydrogenase (LDH) and succinate dehydrogenase (SDH) activity of mouse liver homogenates were measured after exposure to an equivalent altitude of 36,000 feet and compared to controls kept at zero altitude. After six and twelve hour incubation periods, the altitude exposed samples demonstrated a significantly higher LDH activity than controls. SDH activity remained unchanged from controls after six hours but was significantly lower than controls after a 12 hour exposure to altitude. It is concluded that the changes in enzyme activity reflect a metabolic control mechanism attempting to maintain adequate energy production during periods of exposure to hypobaric hypoxic stress

The Gibbs Paradox and the Distinguishability of Identical Particles

Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy. This result is usually considered incorrect because of its inconsistency with thermodynamics. It is sometimes concluded from this inconsistency that identical particles are fundamentally indistinguishable after all; and even that quantum mechanics is indispensable for making sense of this. In contrast, we argue that the classical statistics of distinguishable particles and the resulting non-extensive entropy function are perfectly acceptable from both a theoretical and an experimental perspective. The inconsistency with thermodynamics can be removed by taking into account that the entropy concept in statistical mechanics is not completely identical to the thermodynamical one. We observe that even identical quantum particles are in some cases distinguishable, and conclude that quantum mechanics is irrelevant to the Gibbs paradox.Comment: 15 page

Rhythms of social interaction: messaging within a massive online network

We have analyzed the fully-anonymized headers of 362 million messages exchanged by 4.2 million users of Facebook, an online social network of college students, during a 26 month interval. The data reveal a number of strong daily and weekly regularities which provide insights into the time use of college students and their social lives, including seasonal variations. We also examined how factors such as school affiliation and informal online friend lists affect the observed behavior and temporal patterns. Finally, we show that Facebook users appear to be clustered by school with respect to their temporal messaging patterns

Assessing Information Bias and Food Safety

Imperfect information can lead to market failure and be an external factor impacting managers of agribusiness firms. A matrix method approach to content analysis was conducted by independent judges based upon established typologies. Food safety articles from consumer publications were examined, and information received by consumers was found to be biased.food safety, information bias, consumers, media, Food Consumption/Nutrition/Food Safety, Marketing, Q10, Q13, Q16,

Hematology as Related to Diving Characteristics of Elaphe obsoleta, Nerodia erythrogaster, Nerodia Fasciata and Nerodia rhombifera

The diving capabilities of Nerodia erythrogaster flavigaster and Nerodia fasciata confluens were investigated and the results were compared with similar studies on Nerodia rhombifera rhombifera and Elaphe obsoleta obsoleta (Baeyens et al., 1978). In addition, morphological and hematological parameters contributing to underwater survival were examined. The duration of underwater survival for N. erythrogaster and N. fasciata was approximately one hour with no difference between the species. The lung volumes of the two species were also similar but were significantly less than lung volumes reported for E. obsoleta. There were no significant differences in hemoglobin concentration, red blood cell count or hematocrit between N. rhombifera, N. erythrogaster, N. fasciata, and E. obsoleta. Based on similarities in underwater tolerance, lung morphology and hematology, Nerodia more closely resembles the terrestrial E. obsoleta than those reptiles specifically adapted to an underwater existance

Solar Cell Light Trapping beyond the Ray Optic Limit

In 1982, Yablonovitch proposed a thermodynamic limit on light trapping within homogeneous semiconductor slabs, which implied a minimum thickness needed to fully absorb the solar spectrum. However, this limit is valid for geometrical optics but not for a new generation of subwavelength solar absorbers such as ultrathin or inhomogeneously structured cells, wire-based cells, photonic crystal-based cells, and plasmonic cells. Here we show that the key to exceeding the conventional ray optic or so-called ergodic light trapping limit is in designing an elevated local density of optical states (LDOS) for the absorber. Moreover, for any semiconductor we show that it is always possible to exceed the ray optic light trapping limit and use these principles to design a number of new solar absorbers with the key feature of having an elevated LDOS within the absorbing region of the device, opening new avenues for solar cell design and cost reduction

Light trapping beyond the 4n^2 limit in thin waveguides

We describe a method for determining the maximum absorption enhancement in thin film waveguides based on optical dispersion relations. For thin film structures that support one, well-confined guided mode, we find that the absorption enhancement can surpass the traditional limit of 4n^2 when the propagation constant is large and/or the modal group velocity is small compared to the bulk value. We use this relationship as a guide to predicting structures that can exceed the 4n^2 light trapping limit, such as plasmonic and slot waveguides. Finally, we calculate the overall absorption for both single and multimode waveguides, and show examples of absorption enhancements in excess of 4n^2 for both cases