13 research outputs found

    Evaluation of mechanical and electrical parameters of individual polyaniline nanoparticles

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    The work was carried out according to the state task of the Omsk Scientific Center SB RAS (project registration number AAAA-A17-117041210227-8)

    Dielectric characterization of erythrocytes by electrostatic force microscopy

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    The work was carried out according to the state task of the Omsk Scientific Center SB RAS (project registration number AAAA-A17-117041210227-8)

    Gas sensing properties of individual composite nanostructures TiO2-x/MWCNT and SnOx/MWCNT measured by scanning force microscopy

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    The work was carried out according to the state task of the Omsk Scientific Center SB RAS (project registration number AAAA-A17-117041210227-8)

    AFM study of the supramolecular structure transformation of polyaniline and composite "polyaniline/carbon nanotubes" upon doping with dodecylbenzenesulfonic acid in the presence of a solvent

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    На основС Π°Π½Π°Π»ΠΈΠ·Π° АБМ ΠΈΠ·ΠΎΠ±Ρ€Π°ΠΆΠ΅Π½ΠΈΠΉ ΠΈΠ·ΡƒΡ‡Π΅Π½ ΠΌΠ΅Ρ…Π°Π½ΠΈΠ·ΠΌ трансформации надмолСкулярной структуры ΠΏΠ»Π΅Π½ΠΎΠΊ ΠΏΠΎΠ»ΠΈΠ°Π½ΠΈΠ»ΠΈΠ½Π° ΠΈ ΠΊΠΎΠΌΠΏΠΎΠ·ΠΈΡ‚Π° Β«ΠΏΠΎΠ»ΠΈΠ°Π½ΠΈΠ»ΠΈΠ½/ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Π΅ Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΊΠΈΒ» Π² Ρ„ΠΎΡ€ΠΌΠ΅ основания Π² Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π΅ совмСстного воздСйствия Π΄ΠΎΠΏΠ°Π½Ρ‚Π° – Π΄ΠΎΠ΄Π΅Ρ†ΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΡΡƒΠ»ΡŒΡ„ΠΎΠΊΠΈΡΠ»ΠΎΡ‚Ρ‹ ΠΈ растворитСля.Based AFM image analysis, the supramolecular structure transformation mechanism of polyaniline films and the "polyaniline/carbon nanotube" composite films in the base form as a result of combined effect of dopant–dodecylbenzenesulfonic acid and a solvent was studied

    Combination of scanning force microscopy methods to evaluation the electrophysical parameters of individual multiwalled carbon nanotubes

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    ΠŸΡƒΡ‚Π΅ΠΌ совмСстного использования ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ² элСктростатичСской силовой микроскопии ΠΈ проводящСй Π°Ρ‚ΠΎΠΌΠ½ΠΎ-силовой микроскопии Ρ€Π°Π·Ρ€Π°Π±ΠΎΡ‚Π°Π½Π° ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΈΠΊΠ° опрСдСлСния элСктрофизичСских ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² ΠΈΠ½Π΄ΠΈΠ²ΠΈΠ΄ΡƒΠ°Π»ΡŒΠ½Ρ‹Ρ… многостСнных ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ.Based on a combination of electrostatic force microscopy and conductive atomic force microscopy, the technique for determining the electrical parameters of individual multiwalled carbon nanotubes was developed

    Effect of Nitrogen Atoms in the CNT Structure on the Gas Sensing Properties of PANI/CNT Composite

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    Herein we report the gas-sensitive properties to ammonia (at 2–10 ppm) of individual nanostructures of a polyaniline/nitrogen-doped carbon nanotube composite with a nitrogen content of 0 at.% (uCNTs), 2 at.% (N-CNTs) and 4 at.% (N+-CNTs). Doping of nanotubes with nitrogen was carried out in order to both reduce the electron work function, to form a potential barrier at the β€œPANI-CNTs” interface, and reduce the contribution of nanotubes to the composite conductivity. An increase in the nitrogen content in CNTs leads to an increase in conductivity, a decrease in the work function, and the formation of defects in the outer walls of CNTs. It was found that the structural and chemical state of the polymer layer of all composites is the same. However, polymer morphology on nanotubes changes dramatically with increasing nitrogen content in CNTs: a thin smooth layer on uCNTs, a globular layer on N-CNTs, and a thick layer with a sheet-like structure on N+-CNTs. All composites showed the same response time (~20 s) and recovery time (~120 s). Ammonia sensitivity was 10.5 Β± 0.2, 15.3 Β± 0.5 and 2.2 Β± 0.1 ppmβˆ’1 for PANI/uCNTs, PANI/N-CNTs and PANI/N+-CNTs, respectively. Based on the results obtained here, we came to the conclusion that the morphological features of the polymer layer on CNTs with different nitrogen content have a dominant effect on the gas reaction than the change in the electronic properties of the polymer at the interface β€œPANI-CNT”
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