908 research outputs found
Synthesis and structural characterization of 2Dioxane.2H2O.CuCl2: metal-organic compound with Heisenberg antiferromagnetic S=1/2 chains
A novel organometallic compound 2Dioxane.CuCl2.2H2O has been synthesized and
structurally characterized by X-ray crystallography. Magnetic susceptibility
and zero-field inelastic neutron scattering have also been used to study its
magnetic properties. It turns out that this material is a weakly coupled
one-dimensional S=1/2 Heisenberg antiferromagnetic chain system with chain
direction along the crystallographic c axis and the nearest-neighbor
intra-chain exchange constant J=0.85(4) meV. The next-nearest-neighbor
inter-chain exchange constant J' is also estimated to be 0.05 meV. The observed
magnetic excitation spectrum from inelastic neutron scattering is in excellent
agreement with numerical calculations based on the Muller ansatz.Comment: 4 pages; 5 figure
Direct evidence of a zigzag spin chain structure in the honeycomb lattice: A neutron and x-ray diffraction investigation on single crystal
We have combined single crystal neutron and x-ray diffractions to investigate
the magnetic and crystal structures of the honeycomb lattice .
The system orders magnetically below K with Ir ions forming
zigzag spin chains within the layered honeycomb network with ordered moment of
/Ir site. Such a configuration sharply contrasts the
N{\'{e}}el or stripe states proposed in the Kitaev-Heisenberg model. The
structure refinement reveals that the Ir atoms form nearly ideal 2D honeycomb
lattice while the octahedra experience a trigonal distortion that
is critical to the ground state. The results of this study provide much-needed
experimental insights into the magnetic and crystal structure crucial to the
understanding of the exotic magnetic order and possible topological
characteristics in the 5-electron based honeycomb lattice.Comment: Revised version as that to appear in PR
Decoupling of the Antiferromagnetic and Insulating States in Tb doped Sr2IrO4
Sr2IrO4 is a spin-orbit coupled insulator with an antiferromagnetic (AFM)
transition at TN=240 K. We report results of a comprehensive study of
single-crystal Sr2Ir1-xTbxO4. This study found that mere 3% (x=0.03)
tetravalent Tb4+(4f7) substituting for Ir4+ (rather than Sr2+) completely
suppresses the long-range collinear AFM transition but retains the insulating
state, leading to a phase diagram featuring a decoupling of magnetic
interactions and charge gap. The insulating state at x=0.03 is characterized by
an unusually large specific heat at low temperatures and an incommensurate
magnetic state having magnetic peaks at (0.95, 0, 0) and (0, 0.95, 0) in the
neutron diffraction, suggesting a spiral or spin density wave order. It is
apparent that Tb doping effectively changes the relative strength of the SOI
and the tetragonal CEF and enhances the Hund's rule coupling that competes with
the SOI, and destabilizes the AFM state. However, the disappearance of the AFM
accompanies no metallic state chiefly because an energy level mismatch for the
Ir and Tb sites weakens charge carrier hopping and renders a persistent
insulating state. This work highlights an unconventional correlation between
the AFM and insulating states in which the magnetic transition plays no
critical role in the formation of the charge gap in the iridate.Comment: 8 figure
Degradation Studies of Cyanex 301
International audienceDespite the numerous studies found in the literature on CYANEX® 301, very few explain its degradation in depth. To the best of our knowledge none has explained the inconsistency between the “common knowledge” of “CYANEX® 301 degrades into CYANEX® 272” (dithiophosphinic acid degrading into the corresponding phosphinic acid) and the 31P spectrum obtained by NMR of the degradation compound. The 31P {1H} NMR analysis of a solution of CYANEX® 301 in prolonged contact with nitric acid shows a very complex spectrum, with resonances about 20 ppm downfield from what could have been expected.The degradation product giving those multiple resonances in a pattern that could be interpreted as a triplet of triplet is actually a dimer, where two molecules of CYANEX® 301 are linked by a disulfide bridge, corresponding to the condensation of the SH groups. The explanation of the complexity of the spectrum comes from the comparison with the spectrum obtained for the degradation of a stereoisomerically-purified CYANEX® 301. This purification led to the removal of the [R;S] and [S;R] isomers from the initial mixture, and yielded a white crystalline solid proven to comprise exclusively [R;R] and [S;S] isomers by XRD analysis. It was determined that the carbon chirality induced an asymmetry of the phosphorus atoms upon condensation, leading to a wide combination of magnetically non-equivalent P-31 nuclei, which can also exhibit coupling through the S-S bond The complete explanation of the NMR spectra was established and corroborated by elemental analysi
Structurally simple lipid bilayer transport agents for chloride and bicarbonate
A new series of structurally simple compounds containing thiourea groups have been shown by a combination of ion-selective electrode and 13C NMR techniques to be potent chloride-bicarbonate exchange agents that function at low concentration in POPC and POPC/cholesterol membranes.<br/
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