Climate variability of Southern Chile since the Last Glacial Maximum: a continuous sedimentological record from Lago Puyehue (40°S)

A key region to study high resolution climate changes of the Southern Hemisphere is undoubtedly the southern part of Chile because it has the advantage to be far removed from the Northern Hemisphere ice sheets and thermohaline circulation influences. In order to reconstruct the regional climate evolution since the Last Glacial Maximum, we investigated the sedimentary infilling of Lago Puyehue (40°S, 164 km2, elevation 185 m) by a multi-proxy analyse of a 11 m long core. Sediments from this core are transported by interflow currents and are made of finely laminated silts, with only small disturbances due to volcanic and seismic activities. Several proxies were measured: grain-size, mineralogy, magnetic susceptibility, major elements geochemistry and biogenic silica concentration. These are used to reconstruct paleo-precipitation and paleo-productivity changes around 40°S. Results evidence that sediment grainsize is highly correlated with the biogenic sediment content and can be used as a proxy for lake paleoproductivity. On the other hand, the magnetic susceptibility signal is highly correlated with the aluminium and titanium concentrations and can be used as a proxy for the terrigenous supply. Temporal variations of sediment composition demonstrate that, since the Last Glacial Maximum, the Chilean Lake District was characterized by 3 abrupt climate changes superimposed on a long term climate evolution. These rapid climate changes are: (1) the end of the Last Glacial Maximum at 17,300 cal. yr. BP; (2) a 13,100-12,300 cal. yr. BP cold event, ending rapidly and interpreted as the local counter part of the European Younger Dryas event, and (3) a 3400-2900 cal. yr. BP climatic instability related to low solar activity. The timing of the 13,100-12,300 cold event is compared with similar records in both hemispheres and demonstrates that this Southern Hemisphere climate change lags behind the Northern Hemisphere Younger Dryas cold period by 500 to 1000 years

Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

International audienceThe global warming of Earth's near-surface, air and oceans in recent decades is a direct consequence of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions contribute approximately 60% to this climate change. This study investigates experimentally the aqueous carbonation mechanisms of an alkaline paper mill waste containing about 55 wt% portlandite (Ca(OH)2) as a possible mineralogical CO2 sequestration process. The overall carbonation reaction includes the following steps: (1) Ca release from portlandite dissolution, (2) CO2 dissolution in water and (3) CaCO3 precipitation. This CO2 sequestration mechanism was supported by geochemical modelling of final solutions using PHREEQC software, and observations by scanning electron microscope and X-ray diffraction of final reaction products. According to the experimental protocol, the system proposed would favour the total capture of approx. 218 kg of CO2 into stable calcite/ton of paper waste, independently of initial CO2 pressure. The final product from the carbonation process is a calcite (ca. 100 wt%)-water dispersion. Indeed, the total captured CO2 mineralized as calcite could be stored in degraded soils or even used for diverse industrial applications. This result demonstrates the possibility of using the alkaline liquid–solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere

Mineral sequestration of CO2 by aqueous carbonation of coal combustion fly-ash

International audienceThe increasing CO2 concentration in the Earth's atmosphere, mainly caused by fossil fuel combustion, has led to concerns about global warming. A technology that could possibly contribute to reducing carbon dioxide emissions is the in-situ mineral sequestration (long term geological storage) or the ex-situ mineral sequestration (controlled industrial reactors) of CO2. In the present study, we propose to use coal combustion fly-ash, an industrial waste that contains about 4.1 wt.% of lime (CaO), to sequester carbon dioxide by aqueous carbonation. The carbonation reaction was carried out in two successive chemical reactions, first, the irreversible hydration of lime. CaO + H2O → Ca(OH)2 second, the spontaneous carbonation of calcium hydroxide suspension. Ca(OH)2 + CO2 → CaCO3 + H2O A significant CaO–CaCO3 chemical transformation (approximately 82% of carbonation efficiency) was estimated by pressure-mass balance after 2 h of reaction at 30 °C. In addition, the qualitative comparison of X-ray diffraction spectra for reactants and products revealed a complete CaO–CaCO3 conversion. The carbonation efficiency of CaO was independent on the initial pressure of CO2 (10, 20, 30 and 40 bar) and it was not significantly affected by reaction temperature (room temperature “20–25”, 30 and 60 °C) and by fly-ash dose (50, 100, 150 g). The kinetic data demonstrated that the initial rate of CO2 transfer was enhanced by carbonation process for our experiments. The precipitate calcium carbonate was characterized by isolated micrometric particles and micrometric agglomerates of calcite (SEM observations). Finally, the geochemical modelling using PHREEQC software indicated that the final solutions (i.e. after reaction) are supersaturated with respect to calcium carbonate (0.7 ≤ saturation index ≤ 1.1). This experimental study demonstrates that 1 ton of fly-ash could sequester up to 26 kg of CO2, i.e. 38.18 ton of fly-ash per ton of CO2 sequestered. This confirms the possibility to use this alkaline residue for CO2 mitigation

Synthesis of a Se0/Calcite Composite Using Hydrothermal Carbonation of Ca(OH)2 Coupled to a Complex Selenocystine Fragmentation

International audienceElemental selenium (Se0)/calcite composites were synthesized in a batch system by hydrothermal carbonation of calcium hydroxide under high CO2−Ar pressure (90 bar) and high temperature (90 °C) coupled to a complex selenocystine fragmentation. Under O2-poor conditions, the composite consisted predominantly of spherical, amorphous nanoparticles of elemental red selenium (<500 nm) deposited on the calcite matrix. Conversely, under O2-rich conditions, the composite consisted rod-shaped, well-crystallized microparticles of elemental gray selenium (<25 µm) dispersed in the calcite matrix. The carbonate matrix was constituted by nano- to microrhombohedral crystals (<2 µm) and micrometric agglomerates and/or aggregates (<5 µm). Our results present a new synthesis path to Se0/calcite composites, with spherical or rod-shaped Se0 morphology with high potential for medical (e.g., dietary supplement) or industrial (e.g., pigments) applications. Furthermore, this study may have implications in the field of biomineralization

Paleoproductivity of Puyehue Lake (Southern Chile) during the last millenium: climatic significance

Southern Chile is a key site for the understanding of past climatic variations since it is influenced by the El Nino Southern Oscillation (ENSO). We investigated high resolution climate changes during the last millennium by a multi-proxy analyse of short cores (60 cm long) collected in Puyehue lake (40°S): magnetic susceptibility, grain-size, mineralogy, density, gamma-density, LOI, biogenic silica content and bulk XRF geochemistry. According to age-depth model (210Pb, 137Cs and varve counting - Boës et al., this session), the cores cover the last 600 yr. The sediment is characterized by volcanic minerals and a high diatom content, due to the important lacustrine silica supply characteristic of volcanic environments. Moreover, the active volcanism of the Chilean Lake District is responsible of a high number of tephra deposits. Our main aim is to quantify biogenic particles fluxes throughout the last millennium by Na2CO3 dissolution and by normative calculation based on bulk XRF analyses. The result shows that volcanic eruptions do not influence the biogenic productivity of the lake. From 1400 to 1880 yr. AD, paleoproductivity shows a global trend from low to high biogenic production. Important paleoproductivity changes are observed over the last 120 yr. Results are compared with historical data and discussed in terms of climate changes and/or anthropic influence

Indoor radon levels in relation to geology in southern Belgium

A statistical study of an indoor radon data set of about 1700 short-term measurements shows a striking relationship between indoor radon concentration and the geological factors, such as stratigraphic unit and rock type

Holocene tectonic, sedimentary, and erosive processes in a volcanic-dammed intramontane lacustrine basin: Lago Laja, Chile

Lago Laja is located near the drainage divide of the south-central high Andes at 37°S. The active Antuco volcano, adjacent to the lake, forms a natural dam confining the Laja intramontane basin. We use field observations, lake reflection-seismic profiles, bathymetry, and remote sensing data to reconstruct the late Quaternary erosion and sedimentation history of the Laja basin and to document the existence of an active fault system that runs parallel to the volcanic arc, the Lago Laja fault system (LLFS).Activity of the Antuco volcano started at ~124 ka with formation of the basaltic edifice, which dammed the catchments forming the intramone Laja basin and lake. At 7.1 cal ka BP, a caldera-collapse event of the Antuco opened the Laja’s dam generating an outburst megaflood and emptying the lake. Fluvial systems advanced into the former lake eroding the poorly-consolidated lacustrine sediments. Subsequent Late Holocene post-caldera lavas dammed the Laja’s outflow generating the present-day lake and renewed lacustrine sedimentation. The fluvial erosion episode is recorded in a regional unconformity, which is well observed in seismic profiles and thus represents an excellent structural marker to quantify fault activity. A post-7.1 ka lacustrine drape covers the erosional surface.Normal faults of the LLFS cut the -14 s-1. Pyroclastic deposits of the Chillan volcano in the northern segment yield a vertical slip rate of 1.0 ± 0.05 mm/a.We interpret soft-sediment deformation layers in an exposed late Pleistocene glaciolacustrine sequence as seismites, which evidence M>6 paleoearthquakes. This is in agreement with magnitudes expected from Holocene surface ruptures.The Main Cordillera at ~37°S is a large-scale pop-up structure uplifted by Quaternary thrusting along both its foothills. In this light, we interpret extension in the axial and highest part of the Andes as incipient gravitational collapse in response to surface uplift and crustal thickening. Thermal weakening due to elevated heat flow in the vicinity of the volcanic arc and post-glacial lithospheric rebound have probably contributed to the arc-limited collapse and late Quaternary acceleration of deformation rates

Expression of expanded FMR1-CGG repeats alters mitochondrial miRNAs and modulates mitochondrial functions and cell death in cellular model of FXTAS

Fragile X-associated tremor/ataxia syndrome (FXTAS) is a progressive neurodegenerative disorder caused by an expansion of 55 to 200 CGG repeats located within 5′UTR of FMR1.These CGG repeats are transcribed into RNAs, which sequester several RNA binding proteins and alter the processing of miRNAs. CGG repeats are also translated into a toxic polyglycine-containing protein, FMRpolyG, that affects mitochondrial and nuclear functions reported in cell and animal models and patient studies. Nuclear-encoded small non-coding RNAs, including miRNAs, are transported to mitochondria; however, the role of mitochondrial miRNAs in FXTAS pathogenesis is not understood. Here, we analyzed mitochondrial miRNAs from HEK293 cells expressing expanded CGG repeats and their implication in the regulation of mitochondrial functions. The analysis of next generation sequencing (NGS) data of small RNAs from HEK293 cells expressing CGG premutation showed decreased level of cellular miRNAs and an altered pattern of association of miRNAs with mitochondria (mito-miRs). Among such mito-miRs, miR-320a was highly enriched in mitoplast and RNA immunoprecipitation of Ago2 (Argonaute-2) followed by Droplet digital PCR (ddPCR)suggested that miR-320a may form a complex with Ago2 and mitotranscripts. Finally, transfection of miR-320a mimic in cells expressing CGG permutation recovers mitochondrial functions and rescues cell death. Overall, this work reveals an altered translocation of miRNAs to mitochondria and the role of miR-320a in FXTAS pathology