2,463 research outputs found
Optical implementation of systolic array processing
Algorithms for matrix vector multiplication are implemented using acousto-optic cells for multiplication and input data transfer and using charge coupled devices detector arrays for accumulation and output of the results. No two dimensional matrix mask is required; matrix changes are implemented electronically. A system for multiplying a 50 component nonnegative real vector by a 50 by 50 nonnegative real matrix is described. Modifications for bipolar real and complex valued processing are possible, as are extensions to matrix-matrix multiplication and multiplication of a vector by multiple matrices
A variational framework for flow optimization using semi-norm constraints
When considering a general system of equations describing the space-time
evolution (flow) of one or several variables, the problem of the optimization
over a finite period of time of a measure of the state variable at the final
time is a problem of great interest in many fields. Methods already exist in
order to solve this kind of optimization problem, but sometimes fail when the
constraint bounding the state vector at the initial time is not a norm, meaning
that some part of the state vector remains unbounded and might cause the
optimization procedure to diverge. In order to regularize this problem, we
propose a general method which extends the existing optimization framework in a
self-consistent manner. We first derive this framework extension, and then
apply it to a problem of interest. Our demonstration problem considers the
transient stability properties of a one-dimensional (in space) averaged
turbulent model with a space- and time-dependent model "turbulent viscosity".
We believe this work has a lot of potential applications in the fluid
dynamics domain for problems in which we want to control the influence of
separate components of the state vector in the optimization process.Comment: 30 page
The Dimer Model for k-phase Organic Superconductors
We prove that the upper electronic bands of k-phase BEDT-TTF salts are
adequately modeled by an half-filled tight-binding lattice with one site per
cell. The band parameters are derived from recent ab-initio calculations,
getting a very simple but extremely accurate one-electron picture. This picture
allows us to solve the BCS gap equation adopting a real-space pairing
potential. Comparison of the calculated superconducting properties with the
experimental data points to isotropic s_0-pairing. Residual many-body or
phonon-mediated interactions offer a plausible explanation of the large variety
of physical properties observed in k-phase BEDT-TTF salts.Comment: 8 pages, 6 PostScript figures, uses RevTe
The angular dependent magnetoresistance in alpha-(BEDT-TTF)_2KHg(SCN)_4
In spite of extensive experimental studies of the angular dependent
magnetoresistance (ADMR) of the low temperature phase (LTP) of
alpha-(BEDT-TTF)_2KHg(SCN)_4 about a decade ago, the nature of LTP remains
elusive. Here we present a new study of ADMR of LTP in alpha-(ET)_2 salts
assuming that LTP is unconventional charge density wave (UCDW). In the presence
of magnetic field the quasiparticle spectrum in UCDW is quantized, which gives
rise to striking ADMR in UCDW. The present model appears to account for many
existing ADMR data of alpha-(BEDT-TTF)_2KHg(SCN)_4 remarkably well.Comment: 6 pages, 4 figure
Recent developments in the determination of the amplitude and phase of quantum oscillations for the linear chain of coupled orbits
De Haas-van Alphen oscillations are studied for Fermi surfaces (FS)
illustrating the model proposed by Pippard in the early sixties, namely the
linear chain of orbits coupled by magnetic breakdown. This FS topology is
relevant for many multiband quasi-two dimensional (q-2D) organic metals such as
-(BEDT-TTF)Cu(NCS) and
-(BEDT-TTF)CoBr(CHCl) which are considered in
detail. Whereas the Lifshits-Kosevich model only involves a first order
development of field- and temperature-dependent damping factors, second order
terms may have significant contribution on the Fourier components amplitude for
such q-2D systems at high magnetic field and low temperature. The strength of
these second order terms depends on the relative value of the involved damping
factors, which are in turns strongly dependent on parameters such as the
magnetic breakdown field, effective masses and, most of all, effective
Land\'{e} factors. In addition, the influence of field-dependent Onsager phase
factors on the oscillation spectra is considered.Comment: arXiv admin note: text overlap with arXiv:1304.665
Solvent extraction of PDMS tubing as a new method for the capture of volatile organic compounds from headspace
Polydimethylsiloxane (PDMS) tubing is increasingly being used to collect volatile organic compounds (VOCs) from static biological headspace. However, analysis of VOCs collected using PDMS tubing often deploys thermal desorption, where samples are considered as ‘one-offs’ and cannot be used in multiple experiments. In this study, we developed a static headspace VOC collection method using PDMS tubing which is solvent-based, meaning that VOC extracts can be used multiple times and can be linked to biological activity. Using a synthetic blend containing a range of known semiochemicals (allyl isothiocyanate, (Z)-3-hexen-1-ol, 1-octen-3-one, nonanal, (E)-anethol, (S)-bornyl acetate, (E)-caryophyllene and pentadecane) with differing chemical and physicochemical properties, VOCs were collected in static headspace by exposure to PDMS tubing with differing doses, sampling times and lengths. In a second experiment, VOCs from oranges were collected using PDMS sampling of static headspace versus dynamic headspace collection. VOCs were eluted with diethyl ether and analysed using gas chromatography – flame ionization detector analysis and coupled GC – mass spectrometry analysis. GC-FID analysis of collected samples showed that longer PDMS tubes captured significantly greater quantities of compounds than shorter tubes, and that sampling duration significantly altered the recovery of all tested compounds. Moreover, greater quantities of compounds were recovered from closed compared to open systems. Finally, analysis of orange headspace VOCs showed only a few qualitative differences in VOCs recovered compared to dynamic headspace collections, although quantities sampled using PDMS tubing were lower. In summary, extraction of PDMS tubing with diethyl ether solvent captures VOCs from the headspace of synthetic blends and biological samples, and the resulting extracts can be used for multiple experiments linking VOC content to biological activity
Photoluminescence dispersion as a probe of structural inhomogeneity in silica
We report time-resolved photoluminescence spectra of point defects in
amorphous silicon dioxide (silica), in particular the decay kinetics of the
emission signals of extrinsic Oxygen Deficient Centres of the second type from
singlet and directly-excited triplet states are measured and used as a probe of
structural inhomogeneity. Luminescence activity in sapphire
(-AlO) is studied as well and used as a model system to compare
the optical properties of defects in silica with those of defects embedded in a
crystalline matrix. Only for defects in silica, we observe a variation of the
decay lifetimes with emission energy and a time dependence of the first moment
of the emission bands. These features are analyzed within a theoretical model
with explicit hypothesis about the effect introduced by the disorder of
vitreous systems. Separate estimations of the homogenous and inhomogeneous
contributions to the measured emission linewidth are obtained: it is found that
inhomogeneous effects strongly condition both the triplet and singlet
luminescence activities of oxygen deficient centres in silica, although the
degree of inhomogeneity of the triplet emission turns out to be lower than that
of the singlet emission. Inhomogeneous effects appear to be negligible in
sapphire
Two-color holography concept (T-CHI)
The Material Processing in the Space Program of NASA-MSFC was active in developing numerous optical techniques for the characterization of fluids in the vicinity of various materials during crystallization and/or solidification. Two-color holographic interferometry demonstrates that temperature and concentration separation in transparent (T-CHI) model systems is possible. The experiments were performed for particular (succinonitrile) systems. Several solutions are possible in Microgravity Sciences and Applications (MSA) experiments on future Shuttle missions. The theory of the T-CHI concept is evaluated. Although particular cases are used for explanations, the concepts developed will be universal. A breadboard system design is also presented for ultimate fabrication and testing of theoretical findings. New developments in holography involving optical fibers and diode lasers are also incorporated
A statistical model for the intrinsically broad superconducting to normal transition in quasi-two-dimensional crystalline organic metals
Although quasi-two-dimensional organic superconductors such as
-(BEDT-TTF)Cu(NCS) seem to be very clean systems, with apparent
quasiparticle mean-free paths of several thousand \AA, the superconducting
transition is intrinsically broad (e.g K wide for K).
We propose that this is due to the extreme anisotropy of these materials, which
greatly exacerbates the statistical effects of spatial variations in the
potential experienced by the quasiparticles. Using a statistical model, we are
able to account for the experimental observations. A parameter , which
characterises the spatial potential variations, may be derived from
Shubnikov-de Haas oscillation experiments. Using this value, we are able to
predict a transition width which is in good agreement with that observed in MHz
penetration-depth measurements on the same sample.Comment: 8 pages, 2 figures, submitted to J. Phys. Condens. Matte
Inefficient weapon—the role of plant secondary metabolites in cotton defence against the boll weevil
Plant cultivar selection for resistance to herbivore pests is an effective, environmentally safe and inexpensive method to implement in integrated pest management programs.
In this study, we evaluated seven cotton genotypes with respect to the production of volatile organic compounds (VOCs) and non-volatile compounds (terpenoid aldehydes
(TAs)), and the attraction and feeding preference of adult boll weevils. Chemical analyses of VOCs from BRS-293, BRS-Rubi, CNPA TB-15, CNPA TB-85, CNPA TB-90, Delta Opal, and Empire Glandless showed that there were few qualitative and
quantitative differences across the range of genotypes. In contrast, major differences in TA content were observed, with CNPA TB-15 and CNPA TB-85 producing higher levels of TAs compared to the other genotypes. Our results showed that boll weevil attraction and feeding behaviour was not positively or negatively influenced by the terpenoid content (volatile and non-volatile compounds) of cotton genotypes. The results in this study suggest that boll weevils have adapted physiologically to cope with cotton chemical defence mechanisms
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