Advanced development of Pb-salt semiconductor lasers for the 8.0 to 15.0 micrometer spectral region

The technology was studied for producing Pb-salt diode lasers for the 8-51 micron spectral region suitable for use as local oscillators in a passive Laser Heterodyne Spectrometer (LHS). Consideration was given to long range NASA plans for the utilization of the passive LHS in a space shuttle environment. The general approach was to further develop the method of compositional interdiffusion (CID) recently reported, and used successfully at shorter wavelength. This technology was shown to provide an effective and reproducible method of producing a single-heterostructure (SH) diode of either the heterojunction or single-sided configuration. Performance specifications were exceeded in several devices, with single-ended CW power outputs as high as 0.88 milliwatts in a mode being achieved. The majority of the CID lasers fabricated had CW operating temperatures of over 60K; 30% of them operated CW above the boiling temperature of liquid nitrogen. CW operation above liquid nitrogen temperature was possible for wavelengths as long as 10.3 microns. Operation at 77K is significant with respect to space shuttle operations since its allows considerable simplification of cooling method

Comment on "Valence QCD: Connecting QCD to the Quark Model"

I criticize certain conclusions about the physics of hadrons drawn from a "valence QCD" approximation to QCD.Comment: 12 pages, 8 figures; some minor improvements made to the tex

How did the Welsh government manage to reform council tax in 2005?

Repeated calls have been made for council tax (CT) in the UK to be reformed. A ‘tyranny of the status quo’ suggests that politicians will avoid this because they fear a backlash from the losers of reform. This paper claims that the tyranny of the status quo is not a fixed law. The Welsh government revalued CT in 2005 but did not communicate the complexity of reform sufficiently. Reform requires greater efforts to communicate the complexity of winning and losing

A knowledge-based flight status monitor for real-time application in digital avionics systems

The Dryden Flight Research Facility of the National Aeronautics and Space Administration (NASA) Ames Research Center (Ames-Dryden) is the principal NASA facility for the flight testing and evaluation of new and complex avionics systems. To aid in the interpretation of system health and status data, a knowledge-based flight status monitor was designed. The monitor was designed to use fault indicators from the onboard system which are telemetered to the ground and processed by a rule-based model of the aircraft failure management system to give timely advice and recommendations in the mission control room. One of the important constraints on the flight status monitor is the need to operate in real time, and to pursue this aspect, a joint research activity between NASA Ames-Dryden and the Royal Aerospace Establishment (RAE) on real-time knowledge-based systems was established. Under this agreement, the original LISP knowledge base for the flight status monitor was reimplemented using the intelligent knowledge-based system toolkit, MUSE, which was developed under RAE sponsorship. Details of the flight status monitor and the MUSE implementation are presented

(η5-Cyclopentadienyl)(2-naphthylethynyl)(triphenylphosphine-κP)nickel(II)

The title compound, [Ni(C₅H₅)(C₁₂H₇)(C₁₈H₁₅P)], does not contain strong hydrogen-bond donors or acceptors and the primary interactions are limited to those of the weak C-H...π(arene) type and mainly involving the arene rings

C-Cl Bond Fission, Hcl Elimination, And Secondary Radical Decomposition In The 193 Nm Photodissociation Of Allyl Chloride

The primary photodissociation dynamics of allyl chloride upon excitation at 193 nm is investigated in a crossed laser-molecular beam scattering apparatus. Tunable vacuum ultraviolet (VUV) photoionization of the products provides a unique ability to learn about the secondary reaction products of the nascent photoproducts formed. The data show evidence for four significant primary reaction channels: a previously unidentified low kinetic energy C-Cl bond fission channel producing unstable allyl radicals, an excited state C-Cl bond fission channel producing Cl atoms with high translational energy, an HCl elimination pathway releasing significant energy to product translation to HCl and its momentum-matched mass 40 partner, and an HCl elimination channel producing low kinetic energy HCl products and predominantly unstable mass 40 products. The measured branching of these primary reaction channels of [all C-Cl] : [fast C-Cl] : [slow C-Cl] : [fast HCl] : [slow HCl] : [all HCl] is 1.00: 0.971: 0.029: 0.291: 0.167: 0.458 (where fast refers to the high recoil kinetic energy channels). The high internal energy allyl radicals formed in the slow C-Cl fission pathway of allyl chloride further dissociate/isomerize, as do the unstable mass 40 products formed in the HCl elimination pathways, and these products are investigated. Photoionization efficiency (PIE) curves of the HCl product suggest that a three-centered elimination mechanism contributes significantly to an observed HCl elimination reaction. (C) 2002 American Institute of Physics

Investigation of potential of differential absorption Lidar techniques for remote sensing of atmospheric pollutants

The NASA multipurpose differential absorption lidar (DIAL) system uses two high conversion efficiency dye lasers which are optically pumped by two frequency-doubled Nd:YAG lasers mounted rigidly on a supporting structure that also contains the transmitter, receiver, and data system. The DIAL system hardware design and data acquisition system are described. Timing diagrams, logic diagrams, and schematics, and the theory of operation of the control electronics are presented. Success in obtaining remote measurements of ozone profiles with an airborne systems is reported and results are analyzed