Carbon doping of superconducting magnesium diboride

We present details of synthesis optimization and physical properties of nearly single phase carbon doped MgB2 with a nominal stoichiometry of Mg(B{0.8}C{0.2})2 synthesized from magnesium and boron carbide (B4C) as starting materials. The superconducting transition temperature is ~ 22 K (~ 17 K lower than in pure MgB2). The temperature dependence of the upper critical field is steeper than in pure MgB2 with Hc2(10K) ~ 9 T. Temperature dependent specific heat data taken in different applied magnetic fields suggest that the two-gap nature of superconductivity is still preserved for carbon doped MgB2 even with such a heavily suppressed transition temperature. In addition, the anisotropy ratio of the upper critical field for T/Tc ~ 2/3 is gamma ~ 2. This value is distinct from 1 (isotropic) and also distinct from 6 (the value found for pure MgB2).Comment: 11 pages, 13 figures, submitted to Physica

Effects of stoichiometry, purity, etching and distilling on resistance of MgB2 pellets and wire segments

We present a study of the effects of non-stoichiometry, boron purity, wire diameter and post-synthesis treatment (etching and Mg distilling) on the temperature dependent resistance and resistivity of sintered MgB2 pellets and wire segments. Whereas the residual resistivity ratio (RRR) varies between RRR \~ 4 to RRR > 20 for different boron purity, it is only moderately affected by non-stoichiometry (from 20% Mg deficiency to 20% Mg excess) and is apparently independent of wire diameter and presence of Mg metal traces on the wire surface. The obtained set of data indicates that RRR values in excess of 20 and residual resistivities as low as rho{0} ~ 0.4 mu Ohm cm are intrinsic material properties of high purity MgB2

Free energy and torque for superconductors with different anisotropies of H_{c2} and lambda

The free energy is evaluated for a uniaxial superconductor with the anisotropy of the upper critical field, gamma_H = H_{c2,ab}/H_{c2,c}, different from the anisotropy of the penetration depth gamma_{lambda} = lambda_c/lambda_{ab}. With increasing difference between gamma_H and gamma_{lambda}, the equilibrium orientation of the crystal relative to the applied field may shift from theta = pi/2 (theta is the angle between the field and the c axis) to lower angles and reach theta = 0 for large enough gamma_H. These effects are expected to take place in MgB_2.Comment: 4 pages, 3 fig

Physical properties of V1−x_{1-x}Tix_{x}O2_{2} (0 << x << 0.187) single crystals

Free standing, low strain, single crystals of pure and titanium doped VO$_{2}$ were grown out of an excess of V$_{2}$O$_{5}$ using high temperature solution growth techniques. At $T_{MI} \sim$ 340 K, pure VO$_{2}$ exhibits a clear first-order phase transition from a high-temperature paramagnetic tetragonal phase (R) to a low-temperature non-magnetic monoclinic phase (M1). With Ti doping, another monoclinic phase (M2) emerges between the R and M1 phases. The phase transition temperature between R and M2 increases with increasing Ti doping while the transition temperature between M2 and M1 decreases.Comment: 11 pages, 8 figure

Anisotropic magnetization and resistivity of single crystalline RNi1-xBi2+-y (R = La-Nd, Sm, Gd-Dy)

We present a detailed study of RNi1-xBi2+-y (R = La-Nd, Sm, Gd-Dy) single crystals by measurements of stoichiometry and temperature dependent magnetic susceptibility, magnetization, and electrical resistivity. This series forms with partial Ni occupancy as well as a variable Bi occupancy. For R = Ce-Nd, Sm, Gd-Dy, the RNi1-xBi2+-y compounds show local-moment like behavior and order antiferromagnetically at low temperatures. Determination of anisotropies as well as antiferromagnetic ordering temperatures for RNi1-xBi2+-y (R = Ce-Nd, Sm, Gd-Dy) have been made. Although crystalline samples from this family exhibit minority, second phase superconductivity at low temperatures associated with Ni-Bi and Bi contamination, no evidence of bulk superconductivity has been observed

An Overview of the Basic Physical Properties of MgB2_2

The basic physical properties of MgB$_2$ have been well established over the past two years of intensive research. At this point there is a general consensus about the values for the isotope shift, critical fields, most of the salient length scales, and general anisotropies. In this paper we will review the determination of these parameters and set the stage for further, more detailed discussions of specific aspects of the physics of MgB$_2$.Comment: accepted to Physica C, special MgB2 iss

Quantum bicriticality in the heavy-fermion metamagnet YbAgGe

Bicritical points, at which two distinct symmetry-broken phases become simultaneously unstable, are typical for spin-flop metamagnetism. Interestingly, the heavy-fermion compound YbAgGe also possesses such a bicritical point (BCP) with a low temperature T_BCP ~ 0.3 K at a magnetic field of mu_0 H_BCP ~ 4.5 T. In its vicinity, YbAgGe exhibits anomalous behavior that we attribute to the influence of a quantum bicritical point (QBCP), that is close in parameter space yet can be reached by tuning T_BCP further to zero. Using high-resolution measurements of the magnetocaloric effect, we demonstrate that the magnetic Grueneisen parameter Gamma_H indeed both changes sign and diverges as required for quantum criticality. Moreover, Gamma_H displays a characteristic scaling behavior but only on the low-field side, H < H_BCP, indicating a pronounced asymmetry with respect to the critical field. We speculate that the small value of T_BCP is related to the geometric frustration of the Kondo-lattice of YbAgGe.Comment: submitted to PR

Effects of Boron Purity, Mg Stoichiometry and Carbon Substitution on Properties of Polycrystalline MgB2_{2}

By synthesizing MgB$_{2}$ using boron of different nominal purity we found values of the residual resistivity ratio ($RRR = R(300 K) / R(42 K)$) from 4 to 20, which covers almost all values found in literature. To obtain high values of $RRR$, high purity reagents are necessary. With the isotopically pure boron we obtained the highest $RRR \sim$ 20 for the stoichiometric compound. We also investigated Mg$_{x}$$^{11}$B$_{2}$ samples with 0.8 $< x <$ 1.2. For the range Mg$_{0.8}$$^{11}$B$_{2}$ up to Mg$_{1.2}$$^{11}$B$_{2}$ we found average values of $RRR$ between 14 and 24. For smaller variations in stoichiometry ($x=1\pm 0.1$) $RRR = 18 \pm 3$. All of our data point to the conclusion that high $RRR$ ($\sim 20$) and low $\rho_{0}$ ($\leq 0.4 \mu \Omega cm$) are intrinsic material properties associated with high purity MgB$_{2}$. In addition we have performed initial work on optimizing the formation of carbon doped MgB$_{2}$ via the use of B$_{4}$C. Nearly single phase material can be formed by reaction of nominal Mg(B$_{0.8}$C$_{0.2}$)$_{2}$ for 24 hours at $1200^{\circ}C$. The $T_{c}$ for this composition is between $21.9 K$ and $22.7 K$ (depending on criterion).Comment: accepted to Physica C, special MgB2 issu

Temperature-dependent Hc2H_{c2} anisotropy in MgB2_2 as inferred from measurements on polycrystals

We present data on temperature-dependent anisotropy of the upper critical field of MgB$_2$ obtained from the analysis of measurements on high purity, low resistivity polycrystals. The anisotropy decreases in a monotonic fashion with increase of temperature

Anisotropy parameters of superconducting MgB2_2

Data on macroscopic superconducting anisotropy of MgB$_2$ are reviewed. The data are described within a weak coupling two-gaps anisotropic s-wave model of superconductivity. The calculated ratio of the upper critical fields $\gamma_H=H_{c2,ab}/H_{c2,c}$ increases with decreasing temperature in agreement with available data, whereas the calculated ratio of London penetration depths $\gamma_{\lambda}=\lambda_c/\lambda_{ab}$ decreases to reach $\approx 1.1$ at T=0. Possible macroscopic consequences of $\gamma_{\lambda}\ne\gamma_H$ are discussed.Comment: accepted to Physica C, special MgB2 issu