Investigation of Halogenated Components Formed from Chlorination of Natural Waters: Preliminary Studies

Chlorination of power plant cooling water is extensively used as a means of controlling biofouling. This practice presents the potential for formation of halogenated organic compounds hazardous to man and his environment. Accordingly, the organic composition resulting from the chlorination of natural waters (northern Olympic Penn1sula sea water and the Columbia River in Washington State} has been investigated. Nonpolar lipophilic organic halogens were extracted by passing large volumes of water over columns of XAD-2 macroreticular resins. Examination of ether extracts from the resin columns using capillary gas chromatography revealed the presence of halogenated methanes, as well as other electron-capturing components~ that were not found when unchlorinated water was sampled. Examination of the chlorinated water extracts using gas chromatography/mass spectrometry revealed complex mixtures which generally were not separable into individual components~ even when high efficiency WCOT capillary columns were used. The samples were separated into fractions of increasing polarity using a water-deactivated silica gel column. Fractions were thus obtained which were more amenable to GC/MS investigation. Haloforms were identified as the major halogenated product from chlorination of the waters studied. Other halogenated products were found at much lower concentrations

Avoidability of formulas with two variables

In combinatorics on words, a word $w$ over an alphabet $\Sigma$ is said to avoid a pattern $p$ over an alphabet $\Delta$ of variables if there is no factor $f$ of $w$ such that $f=h(p)$ where $h:\Delta^*\to\Sigma^*$ is a non-erasing morphism. A pattern $p$ is said to be $k$-avoidable if there exists an infinite word over a $k$-letter alphabet that avoids $p$. We consider the patterns such that at most two variables appear at least twice, or equivalently, the formulas with at most two variables. For each such formula, we determine whether it is $2$-avoidable, and if it is $2$-avoidable, we determine whether it is avoided by exponentially many binary words

Cosmology from String Theory

We explore the cosmological content of Salam-Sezgin six dimensional supergravity, and find a solution to the field equations in qualitative agreement with observation of distant supernovae, primordial nucleosynthesis abundances, and recent measurements of the cosmic microwave background. The carrier of the acceleration in the present de Sitter epoch is a quintessence field slowly rolling down its exponential potential. Intrinsic to this model is a second modulus which is automatically stabilized and acts as a source of cold dark matter with a mass proportional to an exponential function of the quintessence field (hence realizing VAMP models within a String context). However, any attempt to saturate the present cold dark matter component in this manner leads to unacceptable deviations from cosmological data -- a numerical study reveals that this source can account for up to about 7% of the total cold dark matter budget. We also show that (1) the model will support a de Sitter energy in agreement with observation at the expense of a miniscule breaking of supersymmetry in the compact space; (2) variations in the fine structure constant are controlled by the stabilized modulus and are negligible; (3) ``fifth''forces are carried by the stabilized modulus and are short range; (4) the long time behavior of the model in four dimensions is that of a Robertson-Walker universe with a constant expansion rate (w = -1/3). Finally, we present a String theory background by lifting our six dimensional cosmological solution to ten dimensions.Comment: Version to be published in Physical Review

Metallicities of M Dwarf Planet Hosts from Spectral Synthesis

We present the first spectroscopic metallicities of three M dwarfs with known or candidate planetary mass companions. We have analyzed high resolution, high signal-to-noise spectra of these stars which we obtained at McDonald Observatory. Our analysis technique is based on spectral synthesis of atomic and molecular features using recently revised cool-star model atmospheres and spectrum synthesis code. The technique has been shown to yield results consistent with the analyses of solar-type stars and allows measurements of M dwarf [M/H] values to 0.12 dex precision. From our analysis, we find [M/H] = -0.12, -0.32, and -0.33 for GJ 876, GJ 436, and GJ 581 respectively. These three M dwarf planet hosts have sub-solar metallicities, a surprising departure from the trend observed in FGK-type stars. This study is the first part of our ongoing work to determine the metallicities of the M dwarfs included in the McDonald Observatory planet search program.Comment: 13 pages, 2 figures, accepted for publication in ApJ

Chronic Pancreatitis and Neoplasia: Correlation or Coincidence

Any link between pancreatic carcinoma and chronic pancreatitis could reflect the malignant potential of a chronic inflammatory process. Four patients with ductal adenocarcinomas had a long history of pancreatic pain (median duration 5 years) and showed clearcut evidence of chronic pancreatitis “downstream” of the tumour. Four were alcoholics and two heavy smokers. These four cases arose within a surgical series of approximately 250 patients with chronic pancreatitis, giving an incidence of 1.6 per cent. The incidence and anatomical distribution of carcinoma and chronic pancreatitis could possibly be consistent with a casual relationship

Delayed Recombination and Standard Rulers

Measurements of Baryonic Acoustic Oscillations in galaxy surveys have been recognized as a powerful tool for constraining dark energy. However, this method relies on the knowledge of the size of the acoustic horizon at recombination derived from Cosmic Microwave Background Anisotropy measurements. This estimate is typically derived assuming a standard recombination scheme; additional radiation sources can delay recombination altering the cosmic ionization history and the cosmological inferences drawn from CMB and BAO data. In this paper we quantify the effect of delayed recombination on the determination of dark energy parameters from future BAO surveys such as BOSS and WFMOS. We find the impact to be small but still not negligible. In particular, if recombination is non-standard (to a level still allowed by CMB data), but this is ignored, future surveys may incorrectly suggest the presence of a redshift dependent dark energy component. On the other hand, in the case of delayed recombination, adding to the analysis one extra parameter describing deviations from standard recombination, does not significantly degrade the error-bars on dark energy parameters and yields unbiased estimates.Comment: 8 pages, 5 figure

The dynamical viability of scalar-tensor gravity theories

We establish the dynamical attractor behavior in scalar-tensor theories of dark energy, providing a powerful framework to analyze classes of theories, predicting common evolutionary characteristics that can be compared against cosmological constraints. In the Jordan frame the theories are viewed as a coupling between a scalar field, \Phi, and the Ricci scalar, R, F(\Phi)R. The Jordan frame evolution is described in terms of dynamical variables m \equiv d\ln F/d\ln \Phi and r \equiv -\Phi F/f, where F(\Phi) = d f(\Phi)/d\Phi. The evolution can be alternatively viewed in the Einstein frame as a general coupling between scalar dark energy and matter, \beta. We present a complete, consistent picture of evolution in the Einstein and Jordan frames and consider the conditions on the form of the coupling F and \beta required to give the observed cold dark matter (CDM) dominated era that transitions into a late time accelerative phase, including transitory accelerative eras that have not previously been investigated. We find five classes of evolutionary behavior of which four are qualitatively similar to those for f(R) theories (which have \beta=1/2). The fifth class exists only for |\beta| < \sqrt{3}/4, i.e. not for f(R) theories. In models giving transitory late time acceleration, we find a viable accelerative region of the (r,m) plane accessible to scalar-tensor theories with any coupling, \beta (at least in the range |\beta| \leq 1/2, which we study in detail), and an additional region open only to theories with |\beta| < \sqrt{3}/4.Comment: 24 pages, 3 figure

Vector magnetic hysteresis of hard superconductors

Critical state problems which incorporate more than one component for the magnetization vector of hard superconductors are investigated. The theory is based on the minimization of a cost functional ${\cal C}[\vec{H}(\vec{x})]$ which weighs the changes of the magnetic field vector within the sample. We show that Bean's simplest prescription of choosing the correct sign for the critical current density $J_c$ in one dimensional problems is just a particular case of finding the components of the vector $\vec{J}_c$. $\vec{J}_c$ is determined by minimizing ${\cal C}$ under the constraint $\vec{J}\in\Delta (\vec{H},\vec{x})$, with $\Delta$ a bounded set. Upon the selection of different sets $\Delta$ we discuss existing crossed field measurements and predict new observable features. It is shown that a complex behavior in the magnetization curves may be controlled by a single external parameter, i.e.: the maximum value of the applied magnetic field $H_m$.Comment: 10 pages, 9 figures, accepted in Phys. Rev.