1,019 research outputs found
Non equilibrium anisotropic excitons in atomically thin ReS
We present a systematic investigation of the electronic properties of bulk
and few layer ReS van der Waals crystals using low temperature optical
spectroscopy. Weak photoluminescence emission is observed from two
non-degenerate band edge excitonic transitions separated by 20 meV. The
comparable emission intensity of both excitonic transitions is incompatible
with a fully thermalized (Boltzmann) distribution of excitons, indicating the
hot nature of the emission. While DFT calculations predict bilayer ReS to
have a direct fundamental band gap, our optical data suggests that the
fundamental gap is indirect in all cases
Bilayer graphene inclusions in rotational-stacked multilayer epitaxial graphene
Additional component in multi-layer epitaxial graphene grown on the
C-terminated surface of SiC, which exhibits the characteristic electronic
properties of a AB-stacked graphene bilayer, is identified in magneto-optical
response of this material. We show that these inclusions represent a
well-defined platform for accurate magneto-spectroscopy of unperturbed graphene
bilayers.Comment: 5 pages, 2 figures, to appear in Phys. Rev.
Probing the inter-layer exciton physics in a MoS/MoSe/MoS van der Waals heterostructure
Stacking atomic monolayers of semiconducting transition metal dichalcogenides
(TMDs) has emerged as an effective way to engineer their properties. In
principle, the staggered band alignment of TMD heterostructures should result
in the formation of inter-layer excitons with long lifetimes and robust valley
polarization. However, these features have been observed simultaneously only in
MoSe/WSe heterostructures. Here we report on the observation of long
lived inter-layer exciton emission in a MoS/MoSe/MoS trilayer van
der Waals heterostructure. The inter-layer nature of the observed transition is
confirmed by photoluminescence spectroscopy, as well as by analyzing the
temporal, excitation power and temperature dependence of the inter-layer
emission peak. The observed complex photoluminescence dynamics suggests the
presence of quasi-degenerate momentum-direct and momentum-indirect bandgaps. We
show that circularly polarized optical pumping results in long lived valley
polarization of inter-layer exciton. Intriguingly, the inter-layer exciton
photoluminescence has helicity opposite to the excitation. Our results show
that through a careful choice of the TMDs forming the van der Waals
heterostructure it is possible to control the circular polarization of the
inter-layer exciton emission.Comment: 19 pages, 3 figures. Just accepted for publication in Nano Letters
(http://pubs.acs.org/doi/10.1021/acs.nanolett.7b03184
Black chokeberry fruit polyphenols: A valuable addition to reduce lipid oxidation of muffins containing xylitol
The study aimed at assessing effects of black chokeberry polyphenol extract (ChPE) added (0.025â0.075%) to xylitol-containing muffins to reduce lipid oxidation, especially in preventing degradation of hydroperoxides throughout the storage period. Among polyphenolic compounds (3092 mg/100 g in total) in ChPE, polymeric procyanidins were the most abundant (1564 mg/100 g). ChPE addition resulted in a significantly increased capacity of scavenging free radicals and markedly inhibited hydroperoxides decomposition, as reflected by low anisidine values (AnV: 3.25â7.52) throughout the storage. On the other hand, sucrose-containing muffins had increased amounts of primary lipid oxidation products and differed significantly from other samples in conjugated diene hydroperoxides (CD values), which was in accordance with the decrease of C18:2 9c12c in those muffins after storage. In addition, sucrose-containing muffins were found to be those with the highest level of contamination with toxic carbonyl lipid oxidation products. Throughout the storage, no yeast or moulds contamination were found in higher enriched muffins. The incorporation of polyphenols to xylitol-containing muffins resulted in preventing decomposition of polyunsaturated fatty acids (PUFAs), and in reducing the content of some toxic aldehydes. ChPE could be regarded as a possible solution to xylitol-containing muffins to extend their shelf life. The results support the use of xylitol in muffin manufacture as being favourable in terms of suitability for diabetics
Static and Dynamic Disorder in Triple-Cation Hybrid Perovskites
A detailed understanding of the carrier dynamics and emission characteristics
of organic-inorganic lead halide perovskites is critical for their
optoelectronic and energy harvesting applications. In this work, we reveal the
impact of the crystal lattice disorder on the photo-generated electron-hole
pairs through low-temperature photoluminescence measurements. We provide strong
evidence that the intrinsic disorder forms a sub-bandgap tail density of
states, which determines the emission properties at low temperature. The PL
spectra indicate that the disorder evolves with increasing temperature,
changing its character from static to dynamic. This change is accompanied by a
rapid drop of the PL efficiency, originating from the increased mobility of
excitons/polarons, which enables them to reach deep non-radiative recombination
centers more easily
Versatile transporter apparatus for experiments with optically trapped Bose-Einstein condensates
We describe a versatile and simple scheme for producing magnetically and
optically-trapped Rb-87 Bose-Einstein condensates, based on a moving-coil
transporter apparatus. The apparatus features a TOP trap that incorporates the
movable quadrupole coils used for magneto-optical trapping and long-distance
magnetic transport of atomic clouds. As a stand-alone device, this trap allows
for the stable production of condensates containing up to one million atoms. In
combination with an optical dipole trap, the TOP trap acts as a funnel for
efficient loading, after which the quadrupole coils can be retracted, thereby
maximizing optical access. The robustness of this scheme is illustrated by
realizing the superfluid-to-Mott insulator transition in a three-dimensional
optical lattice
The spin-1/2 XXZ Heisenberg chain, the quantum algebra U_q[sl(2)], and duality transformations for minimal models
The finite-size scaling spectra of the spin-1/2 XXZ Heisenberg chain with
toroidal boundary conditions and an even number of sites provide a projection
mechanism yielding the spectra of models with a central charge c<1 including
the unitary and non-unitary minimal series. Taking into account the
half-integer angular momentum sectors - which correspond to chains with an odd
number of sites - in many cases leads to new spinor operators appearing in the
projected systems. These new sectors in the XXZ chain correspond to a new type
of frustration lines in the projected minimal models. The corresponding new
boundary conditions in the Hamiltonian limit are investigated for the Ising
model and the 3-state Potts model and are shown to be related to duality
transformations which are an additional symmetry at their self-dual critical
point. By different ways of projecting systems we find models with the same
central charge sharing the same operator content and modular invariant
partition function which however differ in the distribution of operators into
sectors and hence in the physical meaning of the operators involved. Related to
the projection mechanism in the continuum there are remarkable symmetry
properties of the finite XXZ chain. The observed degeneracies in the energy and
momentum spectra are shown to be the consequence of intertwining relations
involving U_q[sl(2)] quantum algebra transformations.Comment: This is a preprint version (37 pages, LaTeX) of an article published
back in 1993. It has been made available here because there has been recent
interest in conformal twisted boundary conditions. The "duality-twisted"
boundary conditions discussed in this paper are particular examples of such
boundary conditions for quantum spin chains, so there might be some renewed
interest in these result
Polarons with a twist
We consider a polaron model where molecular \emph{rotations} are important.
Here, the usual hopping between neighboring sites is affected directly by the
electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This
model may be of relevance for electronic transport in complex molecules and
polymers with torsional degrees of freedom, such as DNA, as well as in
molecular electronics experiments where molecular twist motion is significant.
We use a tight-binding representation and find that very different polaronic
properties are already exhibited by a two-site model -- these are due to the
nonlinearity of the restoring force of the twist excitations, and of the
electron-phonon interaction in the model. In the adiabatic regime, where
electrons move in a {\em low}-frequency field of twisting-phonons, the
effective splitting of the energy levels increases with coupling strength. The
bandwidth in a long chain shows a power-law suppression with coupling, unlike
the typical exponential dependence due to linear phonons.Comment: revtex4 source and one eps figur
Nonadiabatic approach to dimerization gap and optical absorption coefficient of the Su-Schrieffer-Heeger model
An analytical nonadiabatic approach has been developed to study the
dimerization gap and the optical absorption coefficient of the
Su-Schrieffer-Heeger model where the electrons interact with dispersive quantum
phonons. By investigating quantitatively the effects of quantum phonon
fluctuations on the gap order and the optical responses in this system, we show
that the dimerization gap is much more reduced by the quantum lattice
fluctuations than the optical absorption coefficient is. The calculated optical
absorption coefficient and the density of states do not have the
inverse-square-root singularity, but have a peak above the gap edge and there
exist a significant tail below the peak. The peak of optical absorption
spectrum is not directly corresponding to the dimerized gap. Our results of the
optical absorption coefficient agree well with those of the experiments in both
the shape and the peak position of the optical absorption spectrum.Comment: 14 pages, 7 figures. to be published in PR
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