Phenol Deoxygenation over Hydrotreating Catalysts

Phenol deoxygenation has been investigated as a model reaction for the deoxygenation of fatty acid methyl esters in biodiesel. Hydrodeoxygenated biodiesel is a drop-in fuel for petroleum diesel, and is a premium diesel with a high cetane number. As the first step in this research, two molybdenum catalysts were prepared, characterized and tested in a small-scale reactor. These catalysts were found to produce small amounts of benzene and cyclohexanol in the product stream, and confirmed the activity of the catalyst. A commercial cobalt molybdenum catalyst (Harshaw HT-400) was also tested and benzene, cyclohexanol, and cyclohexane were identified as products. Future work aims to synthesize catalysts to produce a high yield of cyclohexane. Once the conditions are optimized, we will do tests with biodiesel

A Summary of the Pioneer 10 Maneuver Strategy

The Pioneer Project placed a number of interesting and precise requirements on the navigation of the Pioneer 10 spacecraft flyby mission to Jupiter during 1972-1973. To satisfy these requirements the Pioneer navigation team employed a number of versatile computer programs to evaluate the strategies and maneuver sequences required to execute midcourse corrections. The Pioneer 10 mission objectives and the midcourse strategies used to satisfy these objectives are summarized

Incompatible sets of gradients and metastability

We give a mathematical analysis of a concept of metastability induced by incompatibility. The physical setting is a single parent phase, just about to undergo transformation to a product phase of lower energy density. Under certain conditions of incompatibility of the energy wells of this energy density, we show that the parent phase is metastable in a strong sense, namely it is a local minimizer of the free energy in an $L^1$ neighbourhood of its deformation. The reason behind this result is that, due to the incompatibility of the energy wells, a small nucleus of the product phase is necessarily accompanied by a stressed transition layer whose energetic cost exceeds the energy lowering capacity of the nucleus. We define and characterize incompatible sets of matrices, in terms of which the transition layer estimate at the heart of the proof of metastability is expressed. Finally we discuss connections with experiment and place this concept of metastability in the wider context of recent theoretical and experimental research on metastability and hysteresis.Comment: Archive for Rational Mechanics and Analysis, to appea

Estimated Surface Motions of the Earth's Core

Estimated surface fluid motions of earth core, and rotational and irrotational flow dat

Comparison of estimates of surface fluid motions of the earth's core various epochs

Method of determining velocity of surface fluid motions of earth core for various epoch

On the determination of surface motions of the earth's core

Surface motion of earth cor

Nature of surface flow in the earth's central core

Nonuniform fluid velocity effect at surface of earth core on nature of surface flo

Comparing teacher roles in Denmark and England

This article reports the findings of a comparative study of teaching in Denmark and England; its broader aim is to help develop an approach for comparing pedagogy. Lesson observations and interviews identified the range of goals towards which teachers in each country worked and the actions these prompted. These were clustered using the lens of Bernstein’s pedagogic discourse (1990; 1996) to construct teacher roles which provided a view of pedagogy. Through this approach we have begun to identify variations in pedagogy across two countries. All teachers in this study adopted a variety of roles; of significance was the ease with which competent English teachers moved between roles. The English teachers observed adopted roles consistent with a wider techno-rationalist discourse. There was a greater subject emphasis by Danish teachers whose work was set predominantly within a democratic humanist discourse, whilst the English teachers placed a greater emphasis on applied skills

TM digital image products for applications

Computer compatible tapes (CCTs) of LANDSAT 4 thematic mapper (TM) digital image products are compared and reviewed. The following tape formats are discussed: (1) raw band-sequential data (CCT-BT); (2) calibrated data (CCT-AT); and (3) geometrically resampled data (CCT-PT). Each format represents different steps in the process of producing fully corrected TM data. The CCT-BT images are uncorrected radiometrically or geometrically, CCT-AT data are radiometrically calibrated, and CCT-PT images are both radiometrically and geometrically corrected

TM digital image products for applications

The image characteristics of digital data generated by LANDSAT 4 thematic mapper (TM) are discussed. Digital data from the TM resides in tape files at various stages of image processing. Within each image data file, the image lines are blocked by a factor of either 5 for a computer compatible tape CCT-BT, or 4 for a CCT-AT and CCT-PT; in each format, the image file has a different format. Nominal geometric corrections which provide proper geodetic relationships between different parts of the image are available only for the CCT-PT. It is concluded that detector 3 of band 5 on the TM does not respond; this channel of data needs replacement. The empty bin phenomenon in CCT-AT images results from integer truncations of mixed-mode arithmetric operations