The terminal amino acids of wheat gliadin

Wheat gliadin has been found by two different methods to contain three N-terminal histidine residues for each molecular weight of 27,000. Trace amounts of N-terminal aspartic acid, glutamic acid, alanine, valine, and serine were also detected in the preparation used. Hydrolysis in boiling hydrochloric acid partially destroyed the di-2,4-dinitrophenyl derivative of histidine. Losses of from 5% to 25% occurred depending upon the time and conditions of hydrolysis. Carboxypeptidase did not release free amino acids from wheat gliadin but qualitative evidence for the occurrence of C-terminal glutamic acid and C-terminal "leucine" was obtained

The action of sulpeiuric acid on gliadin: with special reference to the N-Peptpdyl→O-Peptpdyl bond rearrangement

Treatment of gliadin with sulphuric acid transposes peptide bonds of serine from the amino to the hydroxyl group. Maximum transposition, 60-70% of the theoretical, occurs when the protein is treated with anhydrous sulphuric acid at 0° C. for 35 hr. No rearrangement was detected at threonine residues. Examination of the peptide material, obtained from the rearranged protein by Elliott's degradation method, indicates apparent "homogeneity". In an alternative scheme for the degradation, nitrous acid deamination of free amino groups was used. The resulting loss in serine content of the protein is direct evidence for the acyl migration of peptide bonds. Incorporation of sulphur and partial disappearance of several amino acids accompany the sulphuric acid treatment. The occurrence of these secondary reactions imposes limitations on the use of sulphuric acid as a reagent for the specific fission of peptide bonds

SONTRAC—A low background, large area solar neutron spectrometer

SONTRAC is a scintillating fiber neutron detector designed to measure solar flare neutrons from a balloon or spacecraft platform. The instrument is comprised of alternating orthogonal planes of scintillator fibers viewed by photomultiplier tubes and image intensifier/CCD camera optics. It operates by tracking the paths of recoil protons from the double scatter of 20 to 200 MeV neutrons off hydrogen in the plastic scintillator, thereby providing the necessary information to determine the incident neutron direction and energy. SONTRAC is also capable of detecting and measuring high-energy gamma rays \u3e20 MeV as a “solid-state spark chamber.” The self-triggering and track imaging features of a prototype for tracking in two dimensions have been demonstrated in calibrations with cosmic-ray muons, 14 to ∼65 MeV neutrons and ∼20 MeV protons

Optimization of Single-Sided Charge-Sharing Strip Detectors

Simulation of the charge sharing properties of single-sided CZT strip detectors with small anode pads are presented. The effect of initial event size, carrier repulsion, diffusion, drift, trapping and detrapping are considered. These simulations indicate that such a detector with a 150 µm pitch will provide good charge sharing between neighboring pads. This is supported by a comparison of simulations and measurements for a similar detector with a coarser pitch of 225 µm that could not provide sufficient sharing. The performance of such a detector used as a gamma-ray imager is discussed

Further studies of single-sided charge-sharing CZT strip detectors

We report progress in the study of a thick CZT strip detector module designed to perform gamma-ray spectroscopy and 3-D imaging. We report preliminary performance measurements of 7.5 mm thick single-sided charge-sharing strip detector prototype devices. This design features both row and column contacts on the anode surface. This electron-only approach addresses problems associated with poor hole transport in CZT that limit the thickness and energy range of double-sided strip detectors. This work includes laboratory and simulation studies aimed at developing compact, efficient, detector modules for 0.05 to 1 MeV gamma measurements while minimizing the number and complexity of the electronic readout channels. This is particularly important in space-based coded aperture and Compton telescope instruments that require large area, large volume detector arrays. Such arrays will be required for the NASA Black Hole Finder Probe (BHFP)and Advanced Compton Telescope (ACT). This new design requires an anode pattern with contacts whose dimensions and spacing are roughly the size of the ionization charge cloud. The first prototype devices have 125 μm anode contacts on 225 μm pitch. Our results demonstrate the principle of operation but suggest that even finer anode contact feature sizes will be necessary to achieve the desired performance

Continued Studies of Single-Sided Charge-Sharing CZT Strip Detectors

In this paper, we report progress in the study of thick single-sided charge-sharing cadmium zinc telluride (CZT) strip detector modules designed to perform gammaray spectroscopy and 3-D imaging. We report on continuing laboratory and simulation measurements of prototype detectors with 11×11 unit cells (15×15×7.5mm3 ). We report preliminary measurements of the 3-D spatial resolution. Our studies are aimed at developing compact, efficient, detector modules for 0.05 to 1 MeV gamma measurements while minimizing the number and complexity of the electronic readout channels. This is particularly important in space-based coded aperture and Compton telescope instruments that require large area, large volume detector arrays. Such arrays will be required for the NASA’s Black Hole Finder Probe (BHFP) and Advanced Compton Telescope (ACT). This design requires an anode pattern with contacts whose dimensions and spacing are roughly the size of the ionization charge cloud. The first prototype devices have 125µm anode contacts on 225µm pitch. Our studies conclude that finer pitch contacts will be required to improve imaging efficiency

Dental problems and Familismo: social network discussion of oral health issues among adults of Mexican origin living in the Midwest United States

Objective: To examine the influence of collectivist orientation (often called familismo when applied to the Latino sub-group in the United States) in oral health discussion networks. Basic Research Design: Through respondent-driven sampling and face-to-face interviews, we identified respondents' (egos) personal social network members (alters). Egos stated whom they talked with about oral health, and how often they discussed dental problems in the preceding 12 months. Participants: An urban community of adult Mexican-American immigrants in the Midwest United States. We interviewed 332 egos (90% born in Mexico); egos named an average of 3.9 alters in their networks, 1,299 in total. Method: We applied egocentric network methods to examine the ego, alter, and network variables that characterize health discussion networks. Results: Kin were most often leveraged when dental problems arose; egos relied on individuals whom they perceive to have better knowledge about dental matters. However, reliance on knowledgeable alters decreased among egos with greater behavioral acculturation. Conclusions: This paper developed a network-based conceptualization of familismo. We describe the structure of oral health networks, including kin, fictive kin, peers, and health professionals, and examine how networks and acculturation help shape oral health among these Mexican-Americans

Single-sided CZT strip detectors

We report progress in the study of thick CZT strip detectors for 3-d imaging and spectroscopy and discuss two approaches to device design. We present the spectroscopic, imaging, detection efficiency and response uniformity performance of prototype devices. Unlike double-sided strip detectors, these devices feature both row and column contacts implemented on the anode surface. This electron-only approach circumvents problems associated with poor hole transport in CZT that normally limit the thickness and energy range of double-sided strip detectors. These devices can achieve similar performance to pixel detectors. The work includes laboratory and simulation studies aimed at developing compact, efficient, detector modules for 0.05 to 1 MeV gamma radiation measurements. The low channel count strip detector approach can significantly reduce the complexity and power requirements of the readout electronics. This is particularly important in space-based coded aperture or Compton telescope instruments requiring large area, large volume detector arrays. Such arrays will be required for NASA\u27s Black Hole Finder Probe (BHFP) and Advanced Compton Telescope (ACT)

Gamma-Ray Observations of GRO J1655-40

The bright transient X-ray source GRO J1655-40 = XN Sco 1994 was observed by the OSSE instrument on the Compton Gamma Ray Observatory (GRO). Preliminary results are reported here. The initial outburst from GRO J1655-40 was detected by BATSE on 27 Jul 1994. OSSE observations were made in five separate viewing periods starting between 4 Aug 1994 and 4 Apr 1995. The first, third, and fifth observations are near the peak luminosity. In the second observation, the source flux had dropped by several orders of magnitude and we can only set an upper limit. The fourth observation is a weak detection after the period of maximum outburst. In contrast with other X-ray novae such as GRO J0422+32, the spectrum determined by OSSE is consistent with a simple power law over the full range of detection, about 50 - 600 keV. The photon spectral index is in the range of -2.5 to 2.8 in all of the observations. We set an upper limit on fractional rms variation \u3c5% in the frequency range 0.01 – 60 Hz. No significant narrow or broad line features are observed at any energy

The Opportunity Spectrum -- Concept and Behavioral Information in Outdoor Recreation Resource Supply Inventories: Background and Application

The paper describes an outdoor recreation resource (ORR) Supply Inventory and Classification (SIC) System that is being developed for multiple use natural resource planning. Four previously developed ORR SIC’s on which this system was built are described briefly. A general model for natural resource planning is presented to show how the proposed ORR SIC fits into a larger planning framework. The proposed SIC System is described and its application for regional and unit planning is explained. Relationships between OR consumers\u27 preferences for specific types of satisfying experiences and their preferences for specific attributes of the physical, social, and managerial settings are translated into specific and objective criteria proposed for inventorying and classifying lands as to their potential for providing particular types of OR opportunities on the spectrum