First measurements of 15N fractionation in N2H+ toward high-mass star forming cores

We report on the first measurements of the isotopic ratio 14N/15N in N2H+ toward a statistically significant sample of high-mass star forming cores. The sources belong to the three main evolutionary categories of the high-mass star formation process: high-mass starless cores, high-mass protostellar objects, and ultracompact HII regions. Simultaneous measurements of 14N/15N in CN have been made. The 14N/15N ratios derived from N2H+ show a large spread (from ~180 up to ~1300), while those derived from CN are in between the value measured in the terrestrial atmosphere (~270) and that of the proto-Solar nebula (~440) for the large majority of the sources within the errors. However, this different spread might be due to the fact that the sources detected in the N2H+ isotopologues are more than those detected in the CN ones. The 14N/15N ratio does not change significantly with the source evolutionary stage, which indicates that time seems to be irrelevant for the fractionation of nitrogen. We also find a possible anticorrelation between the 14N/15N (as derived from N2H+) and the H/D isotopic ratios. This suggests that 15N enrichment could not be linked to the parameters that cause D enrichment, in agreement with the prediction by recent chemical models. These models, however, are not able to reproduce the observed large spread in 14N/15N, pointing out that some important routes of nitrogen fractionation could be still missing in the models.Comment: 2 Figures, accepted for publication in ApJ

Resolving the chemical substructure of Orion-KL

The Kleinmann-Low nebula in Orion (Orion-KL) is the nearest example of a high-mass star-forming environment. For the first time, we complemented 1.3 mm Submillimeter Array (SMA) interferometric line survey with IRAM 30 m single-dish observations of the Orion-KL region. Covering a 4 GHz bandwidth in total, this survey contains over 160 emission lines from 20 species (25 isotopologues), including 11 complex organic molecules (COMs). At a spatial resolution of 1200 AU, the continuum substructures are resolved. Extracting the spectra from individual substructures and providing the intensity-integrated distribution map for each species, we studied the small-scale chemical variations in this region. Our main results are: (1) We identify lines from the low-abundance COMs CH3COCH3 and CH3CH2OH, as well as tentatively detect CH3CHO and long carbon-chains C6H and HC7N. (2) We find that while most COMs are segregated by type, peaking either towards the hot core (e.g., N-bearing species) or the compact ridge (e.g., O-bearing species like HCOOCH3 and CH3OCH3), while the distributions of others do not follow this segregated structure (e.g., CH3CH2OH, CH3OH, CH3COCH3). (3) We find a second velocity component of HNCO, SO2, 34SO2, and SO lines, which may be associated with a strong shock event in the low-velocity outflow. (4) Temperatures and molecular abundances show large gradients between central condensations and the outflow regions, illustrating a transition between hot molecular core and shock-chemistry dominated regimes. Our observations of spatially resolved chemical variations in Orion-KL provide the nearest reference source for hot molecular core and outflow chemistry, which will be an important example for interpreting the chemistry of more distant HMSFRs.Comment: 51 pages, 17 figures, accepted on 12 March 2015 Dashed lines in Figure 10 of the published paper was missin

The evolution and hybridization of reportage: characteristics of the genre in «La Vanguardia» and «ABC» (1982-2018)

The article herein presents the results of a research study focused on the evolution of reportage in the Spanish press over a span of four decades. This is the first longitudinal study covering such an extensive period (1982-2018) with regard to this narrative journalistic genre, through publications in La Vanguardia and ABC, the two oldest national newspapers in Spain. The aim of the study is to discover how the genre has evolved in recent decades, in terms of authorship, length, section in which it is published, headlines, visual and complementary elements, and the degree of hybridisation with other journalistic genres. Based on a quantitative and qualitative methodology, a sample was analysed using the constructed week sampling technique (N=346 issues). The results obtained show an increase in the amount and general length of the reports published from the year 2000 onward, as well as a tendency toward hybridisation with genres such as the crónica and the news report. However, there is no evidence of a commitment to narrative aspects. The increase in pagination has been fostered by the incorporation of visual and design elements, while the Society section continues to have the highest share of reportage pieces. Most of the reportage items analysed were by-lined by one person, who were predominantly men, which suggests a gender gap in the authorship of prestigious journalistic genres.Este artículo presenta una investigación centrada en la evolución del reportaje en la prensa impresa española a lo largo de cuatro décadas. Se trata del primer estudio longitudinal que abarca un período tan extenso (1982-2018) sobre este género periodístico narrativo, a través de las publicaciones en La Vanguardia y ABC, los dos diarios españoles de alcance estatal más antiguos. El objetivo es conocer cómo se ha desarrollado el género en las últimas décadas, atendiendo a la autoría, extensión, sección en que se publica, titulación, elementos visuales y complementarios, o grado hibridación con otros géneros periodísticos. A partir de una metodología cuantitativa y cualitativa se ha analizado una muestra configurada siguiendo la técnica de la semana construida (N=346 ejemplares). Los resultados obtenidos permiten constatar un aumento del volumen y extensión general de los reportajes publicados a partir del año 2000, así como una tendencia a la hibridación, con géneros como la crónica y la noticia. Sin embargo, no se aprecia una apuesta por elementos narrativos. El aumento de la paginación coincide con la incorporación de elementos visuales y de diseño, mientras la sección de sociedad se mantiene como la que reúne el mayor porcentaje de reportajes. La mayoría de los trabajos analizados están firmados por una única persona, con un predominio de la presencia masculina, lo que evidencia una brecha de género en la autoría de una modalidad periodística de prestigio

A line confusion-limited millimeter survey of Orion KL. III. Sulfur oxide species

We present a study of the sulfur-bearing species detected in a line confusion-limited survey towards Orion KL performed with the IRAM 30m telescope in the range 80-281 GHz. The study is part of an analysis of the line survey divided into families of molecules. Our aim is to derive accurate physical conditions and molecular abundances in the different components of Orion KL from observed SO and SO2 lines. First we assumed LTE conditions obtain rotational temperatures. We then used a radiative transfer model, assuming either LVG or LTE excitation to derive column densities of these molecules in the different components of Orion KL. We have detected 68 lines of SO, 34SO, 33SO, and S18O and 653 lines of SO2, 34SO2, 33SO2, SO18O and SO2 v2=1. We provide column densities for all of them and also upper limits for the column densities of S17O, 36SO, 34S18O, SO17O and 34SO2 v2=1 and for several undetected sulfur-bearing species. In addition, we present 2'x2' maps around Orion IRc2 of SO2 transitions with energies from 19 to 131 K and also maps with four transitions of SO, 34SO and 34SO2. We observe an elongation of the gas along the NE-SW direction. An unexpected emission peak appears at 20.5 km/s in most lines of SO and SO2. A study of the spatial distribution of this emission feature shows that it is a new component ~5" in diameter, which lies ~4" west of IRc2. We suggest the emission from this feature is related to shocks associated to the BN object. The highest column densities for SO and SO2 are found in the high-velocity plateau (a region dominated by shocks) and in the hot core. These values are up to three orders of magnitude higher than the results for the ridge components. We also find high column densities for their isotopologues in both components. Therefore, we conclude that SO and SO2 are good tracers, not only of regions affected by shocks, but also of regions with warm dense gas.Comment: Paper (ref AA/2013/21285) accepted for publication by A&A. 52 Pages, 26 figures, 13 table

Extended warm gas in Orion KL as probed by methyl cyanide

In order to study the temperature distribution of the extended gas within the Orion Kleinmann-Low nebula, we have mapped the emission by methyl cyanide (CH3CN) in its J=6_K-5_K, J=12_K-11_K, J=13_K-12_K, and J=14_K-13_K transitions at an average angular resolution of ~10 arcsec (22 arcsec for the 6_K-5_K lines), as part of a new 2D line survey of this region using the IRAM 30m telescope. These fully sampled maps show extended emission from warm gas to the northeast of IRc2 and the distinct kinematic signatures of the hot core and compact ridge source components. We have constructed population diagrams for the four sets of K-ladder emission lines at each position in the maps and have derived rotational excitation temperatures and total beam-averaged column densities from the fitted slopes. In addition, we have fitted LVG model spectra to the observations to determine best-fit physical parameters at each map position, yielding the distribution of kinetic temperatures across the region. The resulting temperature maps reveal a region of hot (T > 350 K) material surrounding the northeastern edge of the hot core, whereas the column density distribution is more uniform and peaks near the position of IRc2. We attribute this region of hot gas to shock heating caused by the impact of outflowing material from active star formation in the region, as indicated by the presence of broad CH3CN lines. This scenario is consistent with predictions from C-shock chemical models that suggest that gas-phase methyl cyanide survives in the post-shock gas and can be somewhat enhanced due to sputtering of grain mantles in the passing shock front.Comment: 24 pages, 20 figures, accepted for publication in A&