138 research outputs found

    Fabrication,properties and applications of the periodic plasmonic structures based on holographic lithography technique

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    表面等离激元结构与入射光波发生相互作用,即发生表面等离激元共振(surfaceplasmonresonance,SPR)作用时,伴随着局域电磁场的增强和对光在低于衍射极限尺度上的束缚。因此被广泛的用于表面增强光谱、生物化学传感、太阳能光伏器件、光催化等领域。其中表面增强的拉曼光谱(surface-enhancedRamanspectroscopy,SERS)和生物化学传感器(bio-chemicalsensor)是SPR现象的两个最主要的应用途径。由于表面等离激元共振现象具有极强的结构相关性,所以根据不同的应用途径来设计最优化的表面等离激元结构已经成为了一个重要的研究方向。这其中有三个核心问题...Surface plasmons (SPs) are collective excitation of free conductive electrons on noble metal thin films or nanoparticle surfaces excited by electromagnetic radiation at the metal-dielectric interface. The study of the interaction between light and metallic nanostructures is a rapidly emerging research area known as plasmonics, which is the branch of the nanophotonics field. Plasmonic nanostructure...学位:理学博士院系专业:化学化工学院_分析化学学号:2052011015370

    The Measurement of National Wealth and Substitution Analysis between Different Capitals

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    1995年6月,世界银行环境部发表《监测环境进展—关于工作进展的报告》,首次提出了新(或广义)国民财富(相对于SNA国民财富概念)的概念,并对测度方法作了探讨,给出了世界各国国民财富的初步测度结果。2006年,世界银行出版的《国民财富在哪里》,将国民财富划分为三个部分,分别为生产资产、自然资源和无形资本。生产资本是机械设备、建筑物和城市土地(包括基础设施)的总和;自然资源包括非再生资源(包括石油、天然气、煤和矿产资源)、耕地、草地、林地(包括用于用材开采和非用材林产品的地区)和自然保护区;无形资本是作为一种剩余资本计算的,包括人力资本、社会资本、国家及其制度基础、净国外金融资产等。 国民财富...Since the concept of new national wealth was first introduced by the World Bank in 1995.It explored the method of measurement and calculated national wealth of all countries in the world. In 2006, the World Bank published a book named “Where is the national wealth”. The national wealth was divided into three parts, the produced assets, natural resource and intangible capital. Produced capital is t...学位:经济学硕士院系专业:经济学院_统计学学号:1542010115190

    Design and measurements of the high gradient accelerating structures

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    The purpose of this thesis was to study on design and measurements of the high gradient accelerating structures. After introducing the main parameters to characterize Linacs we explained the application of the periodic accelerating structure. Then we studied TW accelerating structure operating at K-band frequency in order to linearize longitudinal space phase to increase beam brightness in the framework of the Compact Light XLS project in order to produce hard x-ray. We estimated group velocity as a function of frequency both analytically and numerically. Analytical results have a good agreement with the numerical results. The main parameters such as shunt impedance, quality factor (Geometric factor) and R/Q independently from the operating frequency for the TM010, TM110 and TM011 for a single cylindrical “pill-box” have been determined analytically as they provide accurate model for the accelerating structures. In order to characterize a normal conducting high accelerating structure with maximum gradients operating at X-band with extremely low probability of RF breakdown, an electroformed SW structures has been fabricated and characterized by SLAC and INFN with collaboration of other institute around the world at 11.424 GHz, coated with Au-Ni. We designed a gold plate RF high gradient structure operating at the X- band coated with Au-Ni. Bench measurements have been performed in the Department of SBAI of the University of Rome “La Sapienza”. The Slater method for the SW cavity has been employed in order to quantify the electric field inside the structure. Comparing the results with the results exposed from HFSS we report the features that have been quantified, showing good agreement. We continued working on the perturbation effect due to the aperture coupled between a waveguide and a cavity but for our application in SW multi-cell high gradient accelerating structure we studied on theoretical approach for reflection coefficient calculation in a SW cavity coupled to a waveguide. One method was based on circuit theory in which we found the overall Q of a resonant circuit for a cavity coupled to an external waveguide containing the RF generator. Q calculation led to the determining of the shunt impedance and consequently the reflection coefficient calculation. Comparison of the results shows a good agreement with the numerical results carried out by using the numerical code, HFSS. Another method of reflection coefficient calculation has been accomplished. We applied the modified Bethe’s theory presented by Collin and developed by De santis, Mostacci and L.Palumbo for TM01 mode cavities coupled by a small hole with a thickness size comparable to the wavelength. The amplitudes of forward and backward waves due to polarizabilites have been determined and we found equations for reflection and transmission coefficients. We demonstrated that our equation for reflection coefficient calculation is an analogous of the reflection coefficient obtained by Collin for TE10 using the circuit theory

    Effects of Nd element addition on microstructure and mechanical properties of Ti-6Al-4V-2Cr alloy

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    本试验采用冷等静压法及粉末冶金法制备钛合金,消除了成分偏析对合金性能的影响。在Ti-6Al-4V-2Cr中加入稀土Nd元素并进行热处理,运用光学; 显微镜、XRD和TEM对其组织和性能进行观察和分析。通过观察发现合金的组织为均匀的alpha +; beta相。运用XRD和TEM观察发现,晶界和晶内均有Nd_2O_3析出物,Nd_2O_3的出现细化了晶粒,提高了形核率,降低了晶粒尺寸。运用精; 密万能试验机进行了力学性能测试,当Nd元素含量为1%时,合金的综合力学性能最好,合金的抗拉强度提高了10.7%,伸长率提高了49.1%。The Ti-6Al-4V-2Cr-xNd alloys were prepared by the cold isostatic; pressing method and powder metallurgy with addition of Nd element,the; effect of composition segregation on properties of the titanium alloy; was eliminated,and microstructure and the properties of the alloy after; heat treatment were studied by means of optical microscope,XRD and TEM.; The results show that the microstructure of the Ti-6Al-4V-2Cr-xNd is; composed of homogeneous alpha + beta phase. Nd_2O_3 precipitates are; observed in the grain boundaries and in the grains by XRD and TEM,and it; can refine the grains,increase the nucleation rate and decrease the; grain size. The optimal mechanical properties of the alloy are obtained; when the Nd content is 1%,and the tensile strength and elongation of the; alloy increase by 10.7% and 49.1%,respectively.军工863项目; 国防973支持项

    Evaluation technique of the loss of coastal ecosystem services caused by sea reclamation project with three methods

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    在分析填海工程对海洋环境影响的基础上,结合《海洋生态资本评估技术导则》(gb/T 28058-2011)综合构建了填海工程对海洋生态系统服务功能损耗评估指标体系。分别采用价值评估法、能值分析法和物种丰度经验公式法对生态损耗进行价值评估,以福鼎市塔下新建填海工程为分析对象进行了实证评估,生态系统服务价值总损失量分别为672.0万元·年–1、809.2万元·年–1和133.3万元·年–1。通过与国内相关研究成果进行比较,分析三种评估方法的可行性和适用性,以期在实际环境影响评价工作中将工程外部成本纳入项目经济损益分析,为海岸带经济可持续发展提供技术支撑。Based on the effects of marine environment caused by sea reclamation and Technical Directives for Marine Ecological Capital Assessment(GB/T 28058-2011), the indexes of the losses of coastal ecosystem services caused by sea reclamation were built.The lost value of sea reclamation was calculated with three methods including economic evaluation, emergy analysis and biodiversity experiential formula which were applied in the new sea reclamation in Taxia Fuding Fujian Province separately, and the total ecosystem lost value was 672.0×104yuan·a–1, 809.2×104yuan·a–1, and 133.3×104yuan·a–1 correspondingly.Compared with other relevant researches, the methods are expected to apply in EIA economic evaluation in order to consider external cost and to apply in coastal economic sustainable development.海洋渔业安全环境保障服务系统关键技术研究及示范应用(201205006

    Anti-resonance features of destructive quantum interference in single-molecule thiophene junctions achieved by electrochemical gating

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    基于单个有机分子来构筑电子器件为电子器件微型化提供潜在技术方案。本研究发展了可集成电化学门控的单分子电子器件测试芯片技术和科学仪器方法,在实验和理论两个层面对具有相消量子干涉效应的噻吩衍生物分子器件的电输运过程进行了电化学调控研究,从而首次在室温下实现了对单分子电子器件中量子干涉效应的反共振现象的直接观测和调控,为制备基于量子干涉效应的新型分子材料和器件提供了全新的设计思路和策略。该研究充分展示了电化学调控技术在信息材料和器件领域的重要应用潜力,也体现了我校固体表面物理化学国家重点实验室在电化学研究和科学仪器研发领域的技术积累,以及面向科学前沿开展交叉学科探索的研究特色。 该研究工作是在洪文晶教授、上海电力大学陈文博教授、英国兰卡斯特大学Colin Lambert教授指导下完成的。化学化工学院博士生白杰和李晓慧为论文的共同第一作者,刘俊扬副研究员、师佳副教授、研究生唐永翔、刘帅、黄晓娟、谭志冰和萨本栋微纳研究院的杨杨副教授等也参与了研究工作。田中群教授和毛秉伟教授为该工作提供了重要指导。【Abstract】Controlling the electrical conductance and in particular the occurrence of quantum interference in single-molecule junctions through gating effects, has potential for the realization of high-performance functional molecular devices. In this work, we used an electrochemically-gated, mechanically-controllable break junction technique to tune the electronic behaviour of thiophene-based molecular junctions that show destructive quantum interference (DQI) features. By varying the voltage applied to the electrochemical gate at room temperature, we reached a conductance minimum that provides direct evidence of charge transport controlled by an anti-resonance arising from DQI. Our molecular system enables conductance tuning close to two orders of magnitude within the non-faradaic potential region, which is significantly higher than that achieved with molecules not showing DQI. Our experimental results, interpreted using quantum transport theory, demonstrate that electrochemical gating is a promising strategy for obtaining improved in-situ control over the electrical performance of interference-based molecular devices.This research was supported by the National Key R&D Program of China (2017YFA0204902), National Natural Science Foundation of China (21722305, 21673195, 21503179, 21703188), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, Natural Science Foundation of Shanghai (17ZR1447100), Science and Technology Commission of Shanghai Municipality (14DZ2261000), China Postdoctoral Science Foundation (2017M622060) for funding work in Xiamen. It was also supported by EU Horizon 2020 project QuIET under grant agreement no. 767187EC FP7 ITN ‘MOLESCO’ project no. 606728 and UK EPSRC grants EP/N017188/1 and EP/M014452/1 and Leverhulme Trust (Leverhulme Early Career Fellowships no. ECF-2017-186 and ECF-2018-375) for funding instrumentation used in Lancaster. It was also supported by Hungarian and Czech Academies of Sciences (P2015-107) and Hungarian Research Foundation (OTKA 112034) for funding instrumentation used in Hungary. The authors thank Z.-Q. Tian and B.-W. Mao, Xiamen University, for useful discussions. 该工作获得科技部国家重点研发计划课题(2017YFA0204902),国家自然科学基金委优秀青年科学基金等项目(21722305、21673195、21703188、21503179)以及中国博士后科学基金(2017M622060)等项目的资助,也得到了固体表面物理化学国家重点实验室、能源材料化学协同创新中心的支持

    Current Progress and Development Trend of Woody Oil-plant Derived Biodiesel Production in China

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    作者简介: 杨文博(1985-) , 女, 河南安阳人, 硕士, 主要从事植物分子生物学科研工作。 通讯作者: 郑文明( 1964-) , 男, 河南永城人, 博士, 教授, 主要研究方向: 植物分子营养和基因工程。Email: zhengwenming@ yahoo.cn[中文文摘]木本油料植物生产生物柴油是适合中国国情的生物柴油发展策略之一。我国虽有丰富的木本油料植物资源,但是实施其开发和产业化都面临许多问题。分析了我国此项产业的现状,阐述了在资源调查、产学研结合、企业管理和政策法规等方面的问题和对策,总结了当前全球注重发展‘环保能源’的大背景下我国利用木本油料植物生产生物柴油的发展趋势。[英文文摘]The woody oil - plants derived biodiesel production is suitable for China"s biodiesel develop ment strategy Although China is rich in woody oil-plant resources, the implementation of its develop ment and industrialization is facing many problems.This paper systematically analyzed current status of the industry, described the issues and countermeasures in resource survey, production management, policies and gulations, summarized the trend of biodiesel production in China by using woody oil plants under the current background of global focus on the development of 'green energy '.河南省杰出青年基金项目(084100410025);河南省农业科技攻关项目(112102110112

    1978~2008年中国湿地类型变化

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    分别基于美国陆地卫星(Landsat MSS/TM/ETM+)和中巴资源卫星(CBERS-02B)影像数据,以人工目视解译为主,完成了中国1978~2008年4期(基准年分别为1978,1990,2000和2008年)湿地遥感制图,并进行了大量的室内外验证.在此基础上,对我国湿地现状及近30年来湿地变化进行了初步分析,得到以下主要结论:(ⅰ)截止2008年,中国湿地面积约为324097km2,其中以内陆沼泽(35%)和湖泊湿地(26%)为主.(ⅱ)1978~2008年,中国湿地面积减少了约33%,而人工湿地增加了约122%.过去30年里湿地减少的速度大幅降低,由最初5523km2/a(1978~1990年)降为831km2/a(2000~2008年).(ⅲ)减少的自然湿地(包括滨海湿地和内陆湿地),其类型变化由湿地向非湿地转化的比例逐渐降低.初期(1978~1990年)几乎全部(98%)转换为非湿地;在1990~2000年间减少的自然湿地约有86%转化为非湿地,而在2000~2008年,这一比例下降为77%.(ⅳ)气候变化和农业活动是中国湿地变化的主要驱动因素,湿地变化在中国分为三大不同特征区域,即西部三省/自治区(西藏、新疆和青海)、北部两省/自治区(黑龙江和内蒙古)和其他省市区.其中西部区域尤其是青藏高原,湿地变化的驱动因子以气候增温为主;新疆湿地由于气候增温和农业活动共同作用造成变化不大.北部省/自治区的湿地变化则主要由农业活动引起;而其他省市区的湿地变化几乎完全受控于人类的农业经济活动

    利用ZEMAX软件分析光器件中的PDL

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    文章简要介绍了常用的偏振相关损耗(PDL)的计算和分析方法,在此基础上利用ZEMAX软件的POLARIZATION A-NALYSIS(偏振分析)功能对光器件的PDL进行了分析和计算,并且与常用数学软件的计算结果和实际器件的测量结果进行了比较,证明了利用ZEMAX软件模拟计算和分析光器件PDL的可行性和准确性,说明了利用ZEMAX软件不仅可以提高设计人员的工作效率,而且能取得精确的计算和分析结果
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