Synthesis and characterization of germanophosphates with low-dimensional structure

锗磷酸盐作为锗酸盐和磷酸盐研究方向的交叉，是一个新兴的研究领域，与其他金属磷酸盐相比数量有限。然而，在这些数量有限的锗磷酸盐化合物中却发现了诸多有趣的结构化学。比如，以GeO6作为“粘结剂”，使结构从二维磷酸盐到三维锗磷酸盐的结构自组装现象；具有沸石分子筛结构基元的锌锗磷酸盐(DABCO)•ZnGe(HPO4)3；在锗磷酸盐中引入F–离子使结构从高维到低维的结构裁剪现象等。同时锗磷酸盐也具有许多优异的物理化学性能，比如NASICON结构化合物MⅠGe(PO4)3(MⅠ=Na，K，Ag)被广泛运用于快离子导体材料；具有KTiOPO4结构的Rb2(Ge0.35Ti1.65)O2(PO4...As the intersection of germanate and phosphate, germanophosphates is an emerging field compared with other metal phosphates. However, a number of interesting structural chemistry has been found in such a limited number of germanophosphates, for instance, structural assembly from two dimensional layer structure to three dimensional network structure via the addition of germanium to the reaction sys...学位：工学硕士院系专业：材料学院_工程硕士(材料工程)学号：2072014115009