Non-affine response: jammed packings versus spring networks

We compare the elastic response of spring networks whose contact geometry is derived from real packings of frictionless discs, to networks obtained by randomly cutting bonds in a highly connected network derived from a well-compressed packing. We find that the shear response of packing-derived networks, and both the shear and compression response of randomly cut networks, are all similar: the elastic moduli vanish linearly near jamming, and distributions characterizing the local geometry of the response scale with distance to jamming. Compression of packing-derived networks is exceptional: the elastic modulus remains constant and the geometrical distributions do not exhibit simple scaling. We conclude that the compression response of jammed packings is anomalous, rather than the shear response.Comment: 6 pages, 6 figures, submitted to ep

Memory formation in matter

Memory formation in matter is a theme of broad intellectual relevance; it sits at the interdisciplinary crossroads of physics, biology, chemistry, and computer science. Memory connotes the ability to encode, access, and erase signatures of past history in the state of a system. Once the system has completely relaxed to thermal equilibrium, it is no longer able to recall aspects of its evolution. Memory of initial conditions or previous training protocols will be lost. Thus many forms of memory are intrinsically tied to far-from-equilibrium behavior and to transient response to a perturbation. This general behavior arises in diverse contexts in condensed matter physics and materials: phase change memory, shape memory, echoes, memory effects in glasses, return-point memory in disordered magnets, as well as related contexts in computer science. Yet, as opposed to the situation in biology, there is currently no common categorization and description of the memory behavior that appears to be prevalent throughout condensed-matter systems. Here we focus on material memories. We will describe the basic phenomenology of a few of the known behaviors that can be understood as constituting a memory. We hope that this will be a guide towards developing the unifying conceptual underpinnings for a broad understanding of memory effects that appear in materials

Catalysis from the bottom-up

Catalysis, the acceleration of chemical reactions by molecules that are not consumed in the process, is essential to living organisms but currently absent in physical systems that aspire to emulate biological functionalities with artificial components. Here we demonstrate how to design a catalyst using spherical building blocks interacting via programmable potentials, and show that a minimal catalyst design, a rigid dimer, can accelerate a ubiquitous elementary reaction, the cleaving of a bond. By combining coarse-grained molecular dynamics simulations and theory, and by comparing the mean reaction time in the presence and absence of the catalyst, we derive geometrical and physical constraints for its design and determine the reaction conditions under which catalysis emerges in the system. The framework and design rules that we introduce are general and can be applied to experimental systems on a wide range of scales, from micron size DNA-coated colloids to centimeter size magnetic handshake materials, opening the door to the realization of self-regulated artificial systems with bio-inspired functionalities.Comment: 8 pages, 4 figures. Submitte

Vibrations in materials with granularity

This thesis concerns the vibrational properties of different classical disordered condensed matter systems. In the first part we focus on materials that exhibit a rigidity transition as their density is increased. By introducing a new method into the field, we were able to look into the localization behavior of vibrational modes of jammed packings of soft spherical particles, both in the localized regime where the localization length is much less and in the regime where it is grater than the linear system size. We also analyze the nature of vibrational modes of jammed packings of soft elliptical particles, where we uncover the change of the structure of the spectrum, compared to the simplest model of sphere packings, due to the rotational degrees of freedom of the particles. In the second part of this thesis we explore the localization properties of collective modes and response to uniform driving of bubble clouds. We find that the response is often very different from that of a typical mode because the frequency response of each mode is sufficiently wide that many modes are excited when the cloud is driven by an ultrasound.UBL - phd migration 201

Contact Changes near Jamming

We probe the onset and effect of contact changes in soft harmonic particle packings which are sheared quasistatically. We find that the first contact changes are the creation or breaking of contacts on a single particle. We characterize the critical strain, statistics of breaking versus making a contact, and ratio of shear modulus before and after such events, and explain their finite size scaling relations. For large systems at finite pressure, the critical strain vanishes but the ratio of shear modulus before and after a contact change approaches one: linear response remains relevant in large systems. For finite systems close to jamming the critical strain also vanishes, but here linear response already breaks down after a single contact change.Comment: 5 pages, 4 figure

Memory formation in Matter

Memory formation in matter is a theme of broad intellectual relevance; it sits at the interdisciplinary crossroads of physics, biology, chemistry, and computer science. Memory connotes the ability to encode, access, and erase signatures of past history in the state of a system. Once the system has completely relaxed to thermal equilibrium, it is no longer able to recall aspects of its evolution. The memory of initial conditions or previous training protocols will be lost. Thus many forms of memory are intrinsically tied to far-from-equilibrium behavior and to transient response to a perturbation. This general behavior arises in diverse contexts in condensed-matter physics and materials, including phase change memory, shape memory, echoes, memory effects in glasses, return-point memory in disordered magnets, as well as related contexts in computer science. Yet, as opposed to the situation in biology, there is currently no common categorization and description of the memory behavior that appears to be prevalent throughout condensed-matter systems. Here the focus is on material memories. The basic phenomenology of a few of the known behaviors that can be understood as constituting a memory will be described. The hope is that this will be a guide toward developing the unifying conceptual underpinnings for a broad understanding of memory effects that appear in materials

Critical jamming of frictional grains in the generalized isostaticity picture

While frictionless spheres at jamming are isostatic, frictional spheres at jamming are not. As a result, frictional spheres near jamming do not necessarily exhibit an excess of soft modes. However, a generalized form of isostaticity can be introduced if fully mobilized contacts at the Coulomb friction threshold are considered as slipping contacts. We show here that, in this framework, the vibrational density of states (DOS) of frictional discs exhibits a plateau when the generalized isostaticity line is approached. The crossover frequency to elastic behavior scales linearly with the distance from this line. Moreover, we show that the frictionless limit, which appears singular when fully mobilized contacts are treated elastically, becomes smooth when fully mobilized contacts are allowed to slip.Comment: 4 pages, 4 figures, submitted to PR

Excitations of Ellipsoid Packings near Jamming

We study the vibrational modes of three-dimensional jammed packings of soft ellipsoids of revolution as a function of particle aspect ratio $\epsilon$ and packing fraction. At the jamming transition for ellipsoids, as distinct from the idealized case using spheres where $\epsilon = 1$, there are many unconstrained and non-trivial rotational degrees of freedom. These constitute a set of zero-frequency modes that are gradually mobilized into a new rotational band as $|\epsilon - 1|$ increases. Quite surprisingly, as this new band is separated from zero frequency by a gap, and lies below the onset frequency for translational vibrations, $\omega^*$, the presence of these new degrees of freedom leaves unaltered the basic scenario that the translational spectrum is determined only by the average contact number. Indeed, $\omega^*$ depends solely on coordination as it does for compressed packings of spheres. We also discuss the regime of large $|\epsilon - 1|$, where the two bands merge.Comment: 6 pages, 4 figure

Effects of particle-size ratio on jamming of binary mixtures

We perform a systematic numerical study of the effects of the particle-size ratio $R \ge 1$ on the properties of jammed binary mixtures. We find that changing $R$ does not qualitatively affect the critical scaling of the pressure and coordination number with the compression near the jamming transition, but the critical volume fraction at the jamming transition varies with $R$. Moreover, the static structure factor (density correlation) $S(k)$ strongly depends on $R$ and shows distinct long wave-length behaviors between large and small particles. Thus the previously reported behavior of $S(k)\sim k$ in the long wave-length limit is only a special case in the $R\to 1$ limit, and cannot be simply generalized to jammed systems with $R>1$.Comment: 5 pages and 4 figures, submitted to Soft Matter, special issue on Granular and Jammed Material