Catalogue of the type fossils stored in the Palaeontological Museum of "Sapienza" University of Rome. 3

This paper is a third contribution towards a catalogue of all types stored in the Palaeontological Museum of "Sapienza" University of Rom

Two generalizations of Jacobi's derivative formula

In this paper we generalize the famous Jacobi's triple product identity, considered as an identity for theta functions with characteristics and their derivatives, to higher genus/dimension. By applying the results and methods developed in our previous paper math.AG/0310085 several generalizations to Siegel modular forms are obtained. These generalizations are identities satisfied by theta functions with characteristics and their derivatives at zero. Equating the coefficients of the Fourier expansion of these relations to zero yields non-trivial combinatorial identities.Comment: final version, to appea

Understanding the mechanism stabilizing intermediate spin states in Fe(II)-Porphyrin

Spin fluctuations in Fe(II)-porphyrins are at the heart of heme-proteins functionality. Despite significant progress in porphyrin chemistry, the mechanisms that rule spin state stabilisation remain elusive. Here, it is demonstrated by using multiconfigurational quantum chemical approaches, including the novel Stochastic-CASSCF method, that electron delocalization between the metal centre and the pi system of the macrocycle differentially stabilises the triplet spin states over the quintet. This delocalisation takes place via charge-transfer excitations, involving the out-of-plane iron d orbitals, key linking orbitals between metal and macrocycle. Through a correlated breathing mechanism, the 3d electrons can make transitions towards the pi orbitals of the macrocycle. This guarantees a strong coupling between the on-site radial correlation on the metal and electron delocalization. Opposite-spin 3d electrons of the triplet can effectively reduce electron repulsion in this manner. Constraining the out-of-plane orbitals from breathing hinders delocalization and reverses the spin ordering. Our results find a qualitative analogue in Kekul\'e resonance structures involving also the metal centre

Singularities of the theta divisor at points of order two

In this note we study the geometry of principally polarized abelian varieties (ppavs) with a vanishing theta-null (i.e. with a singular point of order two and even multiplicity lying on the theta divisor). We describe the locus within the theta-null divisor where this singularity is not an ordinary double point. By using theta function methods we first show that this locus does not equal the entire theta-null divisor (this was shown previously by O. Debarre). We then show that this locus is contained in the intersection of the theta-null divisor with the other irreducible components of the Andreotti-Mayer divisor N_0, and describe by using the geometry of the universal scheme of singularities of the theta divisor the components of this intersection that are contained in this locus. Some of the intermediate results obtained along the way of our proof were concurrently obtained independently by C. Ciliberto and G. van der Geer, and by R. de Jong

On the Coble quartic

We review and extend the known constructions relating Kummer threefolds, G¨opel systems, theta constants and their derivatives, and the GIT quotient for 7 points in P^2 to obtain an explicit expression for the Coble quartic. The Coble quartic was recently determined completely in [RSSS12], where it was computed completely explicitly, as a polynomial with 372060 monomials of bidegree (28, 4) in theta constants of the second order and theta functions of the second order, respectively. Our expression is in terms of products of theta constants with characteristics corresponding to G¨opel systems, and is a polynomial with 134 terms. Our approach is based on the beautiful geometry studied by Coble and further investigated by Dolgachev and Ortland and highlights the geometry and combinatorics of syzygetic octets of characteristics, and the corresponding representations of Sp(6, F_2). One new ingredient is the relationship of G¨opel systems and Jacobian determinants of theta functions. In genus 2, we similarly obtain a short explicit equation for the universal Kummer surface, and relate modular forms of level two to binary invariants of six points on P^

The modular variety of hyperelliptic curves of genus three

The modular variety of non singular and complete hyperelliptic curves with level-two structure of genus 3 is a 5-dimensional quasi projective variety which admits several standard compactifications. The first one, X, comes from the realization of this variety as a sub-variety of the Siegel modular variety of level two and genus three .We will be to describe the equations of X in a suitable projective embedding and its Hilbert function. It will turn out that X is normal. A further model comes from geometric invariant theory using so-called semistable degenerated point configurations in (P^1)^8 . We denote this GIT-compactification by Y. The equations of this variety in a suitable projective embedding are known. This variety also can by identified with a Baily-Borel compactified ball-quotient. We will describe these results in some detail and obtain new proofs including some finer results for them. We have a birational map between Y and X . In this paper we use the fact that there are graded algebras (closely related to algebras of modular forms) A,B such that X=proj(A) and Y=proj(B). This homomorphism rests on the theory of Thomae (19th century), in which the thetanullwerte of hyperelliptic curves have been computed. Using the explicit equations for $A,B$ we can compute the base locus of the map from Y to X. Blowing up the base locus and the singularity of Y, we get a dominant, smooth model {\tilde Y}. We will see that {\tilde Y} is isomorphic to the compactification of families of marked projective lines (P^1,x_1,...,x_8), usually denoted by {\bar M_{0,8}}. There are several combinatorial similarities between the models X and Y. These similarities can be described best, if one uses the ball-model to describe Y.Comment: 39 page

Some Siegel threefolds with a Calabi-Yau model II

In the paper [FSM] we described some Siegel modular threefolds which admit a Calabi-Yau model. Using a different method we give in this paper an enlarged list of such varieties that admits a Calabi-Yau model in the following weak sense: there exists a desingularization in the category of complex spaces of the Satake compactification which admits a holomorphic three-form without zeros and whose first Betti number vanishes Basic for our method is the paper [GN] of van Geemen and Nygaard.Comment: 23 pages, no figure