1,814 research outputs found
Structural analysis of ultrafast extended x-ray absorption fine structure with subpicometer spatial resolution: Application to spin crossover complexes
We present a novel analysis of time-resolved extended x-ray absorption fine structure (EXAFS) spectra based on the fitting of the experimental transients obtained from optical pump/x-ray probe experiments. We apply it to the analysis of picosecond EXAFS data on aqueous [FeII (bpy)3] 2+, which undergoes a light induced conversion from its low-spin (LS) ground state to the short-lived (τ≈650 ps) excited high-spin (HS) state. A series of EXAFS spectra were simulated for a collection of possible HS structures from which the ground state fit spectrum was subtracted to generate transient difference absorption (TA) spectra. These are then compared with the experimental TA spectrum using a least-squares statistical analysis to derive the structural change. This approach reduces the number of required parameters by cancellation in the differences. It also delivers a unique solution for both the fractional population and the extracted excited state structure. We thus obtain a value of the Fe-N bond elongation in the HS state with subpicometer precision (0.203±0.008 Å). © 2009 American Institute of Physics.This work was funded by the Swiss National Science Foundation via Contract Nos. 620–066145, 200021–107956, PP002–110464, 200020–116023, 200021–105239, and 200020-116533.Peer Reviewe
Inactivation of the type I interferon pathway reveals long double‐stranded RNA ‐mediated RNA interference in mammalian cells
RNA interference (RNAi) elicited by long double-stranded (ds) or
base-paired viral RNA constitutes the major mechanism of antiviral
defence in plants and invertebrates. In contrast, it is controversial
whether it acts in chordates. Rather, in vertebrates, viral RNAs
induce a distinct defence system known as the interferon (IFN)
response. Here, we tested the possibility that the IFN response
masks or inhibits antiviral RNAi in mammalian cells. Consistent
with that notion, we find that sequence-specific gene silencing can
be triggered by long dsRNAs in differentiated mouse cells rendered
deficient in components of the IFN pathway. This unveiled response
is dependent on the canonical RNAi machinery and is lost upon
treatment of IFN-responsive cells with type I IFN. Notably, transfection with long dsRNA specifically vaccinates IFN-deficient cells
against infection with viruses bearing a homologous sequence.
Thus, our data reveal that RNAi constitutes an ancient antiviral
strategy conserved from plants to mammals that precedes but has
not been superseded by vertebrate evolution of the IFN system
Adaptive Optics Imaging of IRAS 18276-1431: a bipolar pre-planetary nebula with circumstellar "searchlight beams" and "arcs"
We present high-angular resolution images of the post-AGB nebula
IRAS18276-1431 (also known as OH17.7-2.0) obtained with the Keck II Adaptive
Optics (AO) system in its Natural Guide Star (NGS) mode in the Kp, Lp, and Ms
near-infrared bands. We also present supporting optical F606W and F814W HST
images as well as interferometric observations of the 12CO(J=1-0), 13CO(J=1-0),
and 2.6mm continuum emission with OVRO. The envelope of IRAS18276-1431 displays
a clear bipolar morphology in our optical and NIR images with two lobes
separated by a dark waist and surrounded by a faint 4.5"x3.4" halo. Our Kp-band
image reveals two pairs of radial ``searchlight beams'' emerging from the
nebula center and several intersecting, arc-like features. From our CO data we
derive a mass of M>0.38[D/3kpc]^2 Msun and an expansion velocity v_exp=17km/s
for the molecular envelope. The density in the halo follows a radial power-law
proportional to r^-3, which is consistent with a mass-loss rate increasing with
time. Analysis of the NIR colors indicates the presence of a compact central
source of ~300-500K dust illuminating the nebula in addition to the central
star. Modeling of the thermal IR suggests a two-shell structure in the dust
envelope: 1) an outer shell with inner and outer radius R_in~1.6E16cm and
R_out>~1.25E17cm, dust temperature T_d~105-50K, and a mean mass-loss rate of
Mdot~1E-3Msun/yr; and 2) an inner shell with R_in~6.3E14cm, T_dust~500-105K,
and Mdot~3E-5Msun/yr. An additional population of big dust grains (radius
a>~0.4mm) with T_dust=150-20K and mass M_dust=(0.16-1.6)E-3 [D/3kpc]^2 Msun can
account for the observed sub-mm and mm flux excess. The mass of the envelope
enclosed within R_out=1.25E17cm derived from SED modeling is ~1[D/3kpc]^2 Msun.Comment: 46 pages, 14 figures, 3 tables, accepted for publication in ApJ.
Figures 12 & 13 in low resolution. Full resolution versions are available
upon request to the first autho
The Anomalous Infrared Emission of Abell 58
We present a new model to explain the excess in mid and near infrared
emission of the central, hydrogen poor dust knot in the planetary nebula (PN)
Abell 58. Current models disagree with ISO measurement because they apply an
average grain size and equilibrium conditions only. We investigate grain size
distributions and temperature fluctuations affecting infrared emission using a
new radiative transfer code and discuss in detail the conditions requiring an
extension of the classical description. The peculiar infrared emission of V605
Aql, the central dust knot in Abell 58, has been modeled with our code. V605
Aql is of special interest as it is one of only three stars ever observed to
move from the evolutionary track of a central PN star back to the post-AGB
state.Comment: 17 pages, 4 figures; accepted and to be published in Ap
ICESat Measurements Reveal Complex Pattern of Elevation Changes on Siple Coast Ice Streams, Antarctica
We compare ICESat data (2003-2004) to airborne laser altimetry data (1997-98 and 1999-2000) to monitor surface changes over portions of Van der Veen (VdVIS), Whillans (WIS) and Kamb ice streams (KIS) in the Ross Embayment of the West Antarctic Ice Sheet. The spatial pattern of detected surface changes is generally consistent with earlier observations. However, important changes have occurred during the past decade. For example, areas on the VdVIS and WIS, where large thinning was detected by the airborne surveys, are now closer to being in balance. The upper trunk of KIS continues to build up with thickening rates reaching 0.4 m/year. Our results provide new evidence that the overall mass balance of the region is becoming more positive, but a significant spatial variability exists. They also demonstrate the potential of ICESat data for detecting spatial patterns of surface elevation change in Antarctica
Echelle long-slit optical spectroscopy of evolved stars
We present echelle long-slit optical spectra of a sample of objects evolving
off the AGB, most of them in the pre-planetary nebula (pPN) phase, obtained
with the ESI and MIKE spectrographs at Keck-II and Magellan-I, respectively.
The total wavelength range covered with ESI (MIKE) is ~3900 to 10900 A (~3600
to 7200A). In this paper, we focus our analysis mainly on the Halpha profiles.
Prominent Halpha emission is detected in half of the objects, most of which
show broad Halpha wings (up to ~4000 km/s). In the majority of the
Halpha-emission sources, fast, post-AGB winds are revealed by P-Cygni profiles.
In ~37% of the objects Halpha is observed in absorption. In almost all cases,
the absorption profile is partially filled with emission, leading to complex,
structured profiles that are interpreted as an indication of incipient post-AGB
mass-loss. All sources in which Halpha is seen mainly in absorption have F-G
type central stars, whereas sources with intense Halpha emission span a larger
range of spectral types from O to G. Shocks may be an important excitation
agent of the close stellar surroundings for objects with late type central
stars. Sources with pure emission or P Cygni Halpha profiles have larger J-K
color excess than objects with Halpha mainly in absorption, which suggests the
presence of warm dust near the star in the former. The two classes of profile
sources also segregate in the IRAS color-color diagram in a way that intense
Halpha-emitters have dust grains with a larger range of temperatures.
(abridged)Comment: 68 pages, 14 figures, accepted for publication in ApJS (abstract
abridged
Pulsations and Long-Term Light Variability of Three Candidates to Protoplanetary Nebulae
We present new photometric data and analysis of the long-duration UBV
photoelectric observations for three candidates to protoplanetary objects -
F-supergiants with IR-excesses located at large galactic latitudes, IRAS
18095+2704, IRAS 19386+0155, and IRAS 19500-1709. All three stars have revealed
quasiperiodic low-amplitude variabilities caused by pulsations observed against
the long-term trends of brightnesses. For IRAS 18095+2704=V887 Her we have
found a pulsation period of 109 days and a linear trend of brightness under the
constant colours if being averaged over the year timescale. The light curve of
IRAS 19386+0155=V1648 Aql over 2000-2008 can be approximated by a wave with a
main period of 102 days which is modulated by close frequency, with a period of
98 days, that results in brightness oscillations with a variable amplitude.
V1648 Aql has also shown synchronous reddening together with a persistent rise
of brightness in the V-band. IRAS 19500-1709=V5112 Sgr experiences irregular
pulsations with the periods of 39 and 47 days. The long-term component of the
variability of V5112 Sgr may be related to the binary character of this star.Comment: 11 pages, 6 figures, accepted for publication in Pis'ma Astron. Z
Correlation between Infrared Colors and Intensity Ratios of SiO Maser Lines
We present the results of SiO millimeter-line observations of a sample of
known SiO maser sources covering a wide dust-temperature range. A cold part of
the sample was selected from the SiO maser sources found in our recent SiO
maser survey of cold dusty objects. The aim of the present research is to
investigate the causes of the correlation between infrared colors and SiO maser
intensity ratios among different transition lines. In particular, the
correlation between infrared colors and SiO maser intensity ratio among the
J=1-0 v=1, 2, and 3 lines are mainly concerned in this paper. We observed in
total 75 SiO maser sources with the Nobeyama 45m telescope quasi-simultaneously
in the SiO J=1-0 v=0, 1, 2, 3, 4 and J=2-1 v=1, 2 lines. We also observed the
sample in the 29SiO J=1-0 v=0 and J=2-1 v=0, and 30SiO J=1-0 v=0 lines, and the
H2O 6(1,6)-5(2,3) line. As reported in previous papers, we confirmed that the
intensity ratios of the SiO J=1-0 v=2 to v=1 lines clearly correlate with
infrared colors. In addition, we found possible correlation between infrared
colors and the intensity ratios of the SiO J=1-0 v=3 to v=1&2 lines. Two
overlap lines of H2O (i.e., 11(6,6) nu_2=1 -> 12(7,5) nu_2=0 and 5(0,5) nu_2=2
-> 6(3,4) nu_2=1) might explain these correlation if these overlap lines become
stronger with increase of infrared colors, although the phenomena also might be
explained by more fundamental ways if we take into account the variation of
opacity from object to object.Comment: 49 pages, 7 figures, 3 tables, accepted for publication in ApJ. Full
resolution version available at
http://www.asiaa.sinica.edu.tw/~junichi/paper
Mid-Infrared interferometry of dust around massive evolved stars
We report long-baseline interferometric measurements of circumstellar dust
around massive evolved stars with the MIDI instrument on the Very Large
Telescope Interferometer and provide spectrally dispersed visibilities in the
8-13 micron wavelength band. We also present diffraction-limited observations
at 10.7 micron on the Keck Telescope with baselines up to 8.7 m which explore
larger scale structure. We have resolved the dust shells around the late type
WC stars WR 106 and WR 95, and the enigmatic NaSt1 (formerly WR 122), suspected
to have recently evolved from a Luminous Blue Variable (LBV) stage. For AG Car,
the protoypical LBV in our sample, we marginally resolve structure close to the
star, distinct from the well-studied detached nebula. The dust shells around
the two WC stars show fairly constant size in the 8-13 micron MIDI band, with
gaussian half-widths of ~ 25 to 40 mas. The compact dust we detect around NaSt1
and AG Car favors recent or ongoing dust formation.
Using the measured visibilities, we build spherically symmetric radiative
transfer models of the WC dust shells which enable detailed comparison with
existing SED-based models. Our results indicate that the inner radii of the
shells are within a few tens of AU from the stars. In addition, our models
favor grain size distributions with large (~ 1 micron) dust grains. This
proximity of the inner dust to the hot central star emphasizes the difficulty
faced by current theories in forming dust in the hostile environment around WR
stars. Although we detect no direct evidence for binarity for these objects,
dust production in a colliding-wind interface in a binary system is a feasible
mechanism in WR systems under these conditions.Comment: 21 pages, 4 tables, 13 figures. Accepted for publication in the
Astrophysical Journa
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Arable weed seeds as indicators of regional cereal provenance: a case study from Iron Age and Roman central-southern Britain
The ability to provenance crop remains from archaeological sites remains an outstanding research question in archaeology. Archaeobotanists have previously identified the movement of cereals on the basis of regional variations in the presence of cereal grain, chaff and weed seeds (the consumer–producer debate), and weed seeds indicative of certain soil types, principally at Danebury hillfort. Whilst the former approach has been heavily criticised over the last decade, the qualitative methods of the latter have not been evaluated. The first interregional trade in cereals in Britain is currently dated to the Iron Age hillfort societies of the mid 1st millennium bc. Several centuries later, the development of urban settlements in the Late Iron Age and Roman period resulted in populations reliant on food which was produced elsewhere. Using the case study of central-southern Britain, centred on the oppidum (large fortified settlement) and civitas capital of Silchester, this paper presents the first regional quantitative analysis of arable weed seeds in order to identify the origin of the cereals consumed there. Analysis of the weed seeds which were present with the fine sieve by-products of the glume wheat Triticum spelta (spelt) shows that the weed floras of samples from diverse geological areas can be separated on the basis of the soil requirements of individual taxa. A preliminary finding is that, rather than being supplied with cereals from the wider landscape of the chalk region of the Hampshire Downs, the crops were grown close to Late Iron Age Silchester. The method presented here requires further high quality samples to evaluate this conclusion and other instances of cereal movement in the past
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