Microstructure mapping of a friction stir welded AA2050 Al–Li–Cu in the T8 state

The heterogeneous precipitate microstructure of a AA2050 Al–Li–Cu in the T8 state after friction stir welding has been mapped by small-angle X-ray scattering (SAXS). 2D resolved maps of the fraction and size of both T1 platelets precipitates and clusters/GP zones formed at room temperature are provided. TEM micrographs of selected zone confirm the interpretation of SAXS intensities. This microstructure mapping is compared to microhardness mapping and a direct correlation is shown. Short duration heat treatments made in a salt bath help understanding precipitate stability and suggest that the temperature exploration alone explains to a large extent the distribution of the precipitates microstructure across the welded structure

Clustering kinetics during natural ageing of Al-Cu based alloys with (Mg, Li) additions

Room temperature solute clustering in aluminium alloys, or natural ageing, despite its industrial relevance, is still subject to debate, mostly due to its experimentally challenging nature. To better understand the complex multi-constituents' interactions at play, we have studied ternary and quaternary subsystems based on the Al-Cu alloys, namely Al-Cu-Mg, Al-Cu-Li and Al-Cu-Li-Mg. We used a recently introduced correlative technique using small-angle neutrons and X-ray scattering (SANS and SAXS) to extract the chemically resolved kinetics of room temperature clustering in these alloys, which we completed with differential scanning calorimetry (DSC) and micro-hardness measurements. The comparison of the clustering behaviours of each subsystem allowed us to highlight the paramount role of Mg as a trigger for diffusion and clustering. Indeed, while a strong natural ageing was observed in the Al-Cu-Mg alloy, virtually none was shown for Al-Cu-Li. A very slight addition of Mg (0.4%) to this system, however, drastically changed the situation to a rapid formation of essentially Cu-rich hardening clusters, Mg only joining them later in the reaction. This diffusion enabling effect of Mg is discussed in terms of diffusion mechanism and complex interactions with the quenched-in vacancies

Microstructure distribution in an AA2050 T34 friction stir weld and its evolution during post-welding heat treatment

This paper presents a systematic study where the distribution of precipitate microstructures is mapped in the cross-section of a friction stir weld made with an AA2050 Al–Cu–Li alloy in the naturally aged temper, as well as the evolution of this microstructure during subsequent post-welding heat treatment (PWHT). This study is carried out using spatially resolved small-angle X-ray scattering, supported by transmission electron microscopy, differential scanning calorimetry and microhardness mapping. The as-welded microstructure is dominated by solute clusters, while very little precipitation has taken place during the welding operation. During PWHT, the precipitation kinetics in the different zones of the weld is mainly controlled by the local dislocation density inherited from welding, and by the amount of solute available for precipitation, which depends on the volume fraction of welding-induced intermetallics. Pre-deforming the weld before the PWHT results in a very effective strength recovery and a nearly homogeneous distribution of hardness

Intermixing of Fe and Cu on the atomic scale by high-pressure torsion as revealed by DC- and AC-SQUID susceptometry and atom probe tomography

The capability of high-pressure torsion on the preparation of supersaturated solid solutions, consisting of Cu-14Fe (wt.%), is studied. From microstructural investigations a steady state is obtained with nanocrystalline grains. The as-deformed state is analyzed with atom probe tomography, revealing an enhanced solubility and the presence of Fe-rich particles. The DC-hysteresis loop shows suppressed long range interactions in the as-deformed state and evolves towards a typical bulk hysteresis loop when annealed at 500{\deg}C. AC-susceptometry measurements of the as-deformed state reveal the presence of a superparamagnetic blocking peak, as well as a magnetic frustrated phase, whereas the transition of the latter follows the Almeida-Thouless line, coinciding with the microstructural investigations by atom probe tomography. AC-susceptometry shows that the frustrated state vanishes for annealing at 250{\deg}C

Precipitation in original Duralumin A-U4G versus modern 2017A alloy

Precipitation in Duralumin, a historic quaternary alloy of the type: Al–Cu–Mg–Si, was never fully studied nor observed by current electron microscopy techniques. This article presents the full characterization and comparison of two alloys: a Duralumin (A-U4G) from the 1950s collected on a vintage aircraft and its modern equivalent: a 2017A alloy. The as-received and peak-aging states were analysed with DSC, SAXS and TEM advanced techniques. It is shown that old Duralumin and modern 2017A present a similar nanoprecipitation in the as-received state and behave similarly upon artificial aging. As opposed to what has been reported in the past, three types of precipitates participating in hardening were found upon aging: θ’-Al2Cu, Q’(Q)-AlCuMgSi and Ω-Al2Cu

Precipitation in metallic alloys by small-angle scattering: from microstructure mapping to combinatorial metallurgy

Plenary conferenceInternational audienc

Precipitation in metallic alloys by small-angle scattering: from microstructure mapping to combinatorial metallurgy

Plenary conferenceInternational audienc

Bridging Reciprocal and Direct Space by Using the Small-Angle Scattering Formalism for Atom Probe Tomography

International audienc