Biomass gasification plant and syngas clean-up system

Gasification is recognized as one of the most promising technologies to convert low quality fuels into more valuable ones. The principal problem related with the use of biomass in gasification processes is the high amount of tar released during the pyrolysis step. It is thus necessary to recover tar and to transform it in lighter combustible gas species such as CH4, CO and H-2. In this work the experimental results of a medium industrial scale plant fed with olive husk and having a capacity of 250 kWt are presented. The gasifier is composed by a up-draft reactor which is followed by a secondary fixed bed reactor filled with alluminium oxide spheres having high porosity dedicated to the tar conversion reactions. The syngas is then used to feed an internal combustion engine with a production of 60 kWe

Characterizing the nature of Fossil Groups with XMM

We present an X-ray follow-up, based on XMM plus Chandra, of six Fossil Group (FG) candidates identified in our previous work using SDSS and RASS data. Four candidates (out of six) exhibit extended X-ray emission, confirming them as true FGs. For the other two groups, the RASS emission has its origin as either an optically dull/X-ray bright AGN, or the blending of distinct X-ray sources. Using SDSS-DR7 data, we confirm, for all groups, the presence of an r-band magnitude gap between the seed elliptical and the second-rank galaxy. However, the gap value depends, up to 0.5mag, on how one estimates the seed galaxy total flux, which is greatly underestimated when using SDSS (relative to Sersic) magnitudes. This implies that many FGs may be actually missed when using SDSS data, a fact that should be carefully taken into account when comparing the observed number densities of FGs to the expectations from cosmological simulations. The similarity in the properties of seed--FG and non-fossil ellipticals, found in our previous study, extends to the sample of X-ray confirmed FGs, indicating that bright ellipticals in FGs do not represent a distinct population of galaxies. For one system, we also find that the velocity distribution of faint galaxies is bimodal, possibly showing that the system formed through the merging of two groups. This undermines the idea that all selected FGs form a population of true fossils.Comment: 9 pages, 3 figures. Submitted 01/12/2011 to MNRAS, referee report received 21/02/2012, accepted 22/02/201

Steps toward a classifier for the Virtual Observatory. I. Classifying the SDSS photometric archive

Modern photometric multiband digital surveys produce large amounts of data that, in order to be effectively exploited, need automatic tools capable to extract from photometric data an objective classification. We present here a new method for classifying objects in large multi-parametric photometric data bases, consisting of a combination of a clustering algorithm and a cluster agglomeration tool. The generalization capabilities and the potentialities of this approach are tested against the complexity of the Sloan Digital Sky Survey archive, for which an example of application is reported.Comment: To appear in the Proceedings of the "1st Workshop of Astronomy and Astrophysics for Students" - Naples, 19-20 April 200

A spatially distributed, physically-based modeling approach for estimating agricultural nitrate leaching to groundwater

Nitrogen-nitrate, while being fundamental for crop production, is of particular concern in the agricultural sector, as it can easily leach to the water table, worsening groundwater quality. Numerical models and Geographic Information System may support the estimation of nitrate leaching rates in space and time, to support sustainable agricultural management practices. In this paper, we present a module for the simulation of the processes involved in the nitrogen cycle in the unsaturated zone, including nitrate leaching. This module was developed taking steps from the ANIMO and EPIC model frameworks and coupled to the hydrological models integrated within the FREEWAT platform. As such, the nitrogen cycle module was then included in the FREEWAT platform. The developed module and the coupling approach were tested using a simple synthetic application, where we simulated nitrate leaching through the unsaturated zone for a sunflower crop irrigated district during a dry year. The results of the simulation allow the estimation of daily nitrate concentration values at the water table. These spatially distributed values may then be further used as input concentration in models for simulating solute transport in aquifers

Steps towards a map of the nearby universe

We present a new analysis of the Sloan Digital Sky Survey data aimed at producing a detailed map of the nearby (z < 0.5) universe. Using neural networks trained on the available spectroscopic base of knowledge we derived distance estimates for about 30 million galaxies distributed over ca. 8,000 sq. deg. We also used unsupervised clustering tools developed in the framework of the VO-Tech project, to investigate the possibility to understand the nature of each object present in the field and, in particular, to produce a list of candidate AGNs and QSOs.Comment: 3 pages, 1 figure. To appear in Nucl Phys. B, in the proceedings of the NOW-2006 (Neutrino Oscillation Workshop - 2006), R. Fogli et al. ed

Effects of electron-phonon coupling range on the polaron formation

The polaron features due to electron-phonon interactions with different coupling ranges are investigated by adopting a variational approach. The ground-state energy, the spectral weight, the average kinetic energy, the mean number of phonons, and the electron-lattice correlation function are discussed for the system with coupling to local and nearest neighbor lattice displacements comparing the results with the long range case. For large values of the coupling with nearest neighbor sites, most physical quantities show a strong resemblance with those obtained for the long range electron-phonon interaction. Moreover, for intermediate values of interaction strength, the correlation function between electron and nearest neighbor lattice displacements is characterized by an upturn as function of the electron-phonon coupling constant.Comment: 5 pages and 4 figure

Effects of the electron-phonon coupling near and within the insulating Mott phase

The role of the electron-phonon interaction in the Holstein-Hubbard model is investigated in the metallic phase close to the Mott transition and in the insulating Mott phase. The model is studied by means of a variational slave boson technique. At half-filling, mean-field static quantities are in good agreement with the results obtained by numerical techniques. By taking into account gaussian fluctuations, an analytic expression of the spectral density is derived in the Mott insulating phase showing that an increase of the electron-phonon coupling leads to a sensitive reduction of the Mott gap through a reduced effective repulsion. The relation of the results with recent experimental observations in strongly correlated systems is discussed.Comment: 4 pages, 4 figure

Non-Bayesian Updating in a Social Learning Experiment

In our laboratory experiment, subjects, in sequence, have to predict the value of a good. The second subject in the sequence makes his prediction twice: first (“first belief”), after he observes his predecessor’s prediction; second (“posterior belief”), after he observes his private signal. We find that the second subjects weigh their signal as a Bayesian agent would do when the signal confirms their first belief; they overweight the signal when it contradicts their first belief. This way of updating, incompatible with Bayesianism, can be explained by the Likelihood Ratio Test Updating (LRTU) model, a generalization of the Maximum Likelihood Updating rule. It is at odds with another family of updating, the Full Bayesian Updating. In another experiment, we directly test the LRTU model and find support for it

Design, synthesis and biological activity of selective hCAs inhibitors based on 2-(benzylsulfinyl)benzoic acid scaffold

A large library of derivatives based on the scaffold of 2-(benzylsulfinyl)benzoic acid were synthesised and tested as atypical inhibitors against four different isoforms of human carbonic anhydrase (hCA I, II, IX and XII, EC 4.2.1.1). The exploration of the chemical space around the main functional groups led to the discovery of selective hCA IX inhibitors in the micromolar/nanomolar range, thus establishing robust structure-activity relationships within this versatile scaffold. HPLC separation of some selected chiral compounds and biological evaluation of the corresponding enantiomers was performed along with molecular modelling studies on the most active derivatives