The relationship between fatty acids and fish: lesser-known aspects and the need for increasingly efficient analytical techniques

When we associate the word fatty acids with fish, most people identify fish as sources of fatty acids from the omega families. This relationship is always present in the valuation of nutritional quality of fish. However, fatty acids have many other crucial functions in fish. The oldest studies related to fatty acids focused essentially on their role as sources metabolic energy in the form of ATP through β-oxidation. Many studies referred the fatty acid role for migrations, energy production during growth and egg formation, among others. Soon fatty acids quickly began to be studied from the point of view of source of essential nutrients for several physiological processes and integral components of biological membranes. The high content of highly polyunsaturated fatty acids found in fish is related to the fact that they are poikilothermic. In the presence of various temperature scenarios, fish can effectively exploit a wide chemical diversity of membrane fatty acid profiles, to defend their physical properties, such as fluidity. In the last decades, fatty acids have been used as either biomarkers because they are limited to certain taxa and they can be transferred conservatively from primary producers to higher trophic level or stock identifiers because the fatty acid composition of phospholipids in some body tissues have a stable genetics basis. In the last decades multiple techniques have been used for fatty acid analysis. As a rule, before the instrumental analysis, the sample requires 2 previous steps. These comprise extraction of lipids from the matrix and derivatization. The combination of these two stages generates multiple methodologies that are not always standardized. Soon, the analysis of fatty acids tends to reduce and standardize these previous analyses while the instrumental analysis should solve problems related to similar mass spectra of the isomers and coelution between fatty acidsFundação para a Ciência e Tecnologia (FCT) for a PhD scholarship UI/BD/153381/2022.This work was funding by National Funds through FCT - Foundation for Science and Technology under the Project PTDC/BIA-BMA/030517/2017 and the Portuguese Science Foundation through the strategy plan for MED (Mediterranean Institute for Agriculture, Environment and Development), via project UIDB/05183/2020, for MARE (Marine and Environmental Sciences Centre), via project UIDB/04292/2020, UID/50006/2020, and under the project LA/P/0069/2020 granted to the Associate Laboratory ARNET; and for LAQV-REQUIMTE, via project UIDB/50006/2020 and UIDP/50006/202

Comportamento Per Se De Híbridos De Capim-elefante Para Fins Energéticos

The aim of this study was to evaluate the Per se performance of elephant grass hybrids obtained by partial diallel crossing and also their parents for energy purposes through agronomic traits during rainy and dry seasons. The experiment was conducted at Pesagro experimental station, Campos dos Goytacazes, RJ, Brazil, in randomized blocks, with three repetitions. The crosses were made between contrasting parents in a partial diallel scheme with 5 female parents × 5 male parents. The treatments consisted of ten parents, twenty-five hybrid combinations and the control. Three cuts were realized for evaluations (April and October 2013 and April 2014). The characteristics evaluated were: plant height (ALT), in m; stem diameter (SD), in cm; leaf blade width (LB), in cm; number of tillers per linear meter (NP); dry matter percentage (%DM) and dry matter production (DMP), in t.ha-1. Variance analysis were performed and the means were grouped according to Scott-Knott test (P>0.05). It was oberved that the hybrid H4 (Cuban Pinda x Taiwan A-144), H7 (Cameroon - Piracicaba × Três Rios), H8 (Cameroon - Piracicaba × Mercker 86-Mexico), H10 (Cameroon - Piracicaba × Roxo), H13 (P241-86-Piracicaba × Mercker 86-Mexico), H17 (IAC Campinas × Três Rios) and H18 (IAC-86-Campinas × Mercker 86-Mexico) presented high biomass production.71738

Properties and DEFC tests of Nafion Functionalized titanate nanotubes composite membranes prepared by melt extrusion

Nafion based composites are promising materials to improve the performance of direct ethanol fuel cells. In this work, composite membranes of Nafion and titanate nanotubes functionalized with sulfonic acid groups were prepared by melt extrusion and tested in a direct ethanol fuel cell. Far and mid infrared spectroscopies evidenced the formation of ionic bridges between the sulfonic acid groups of both functionalized nanoparticles and the ionomer. Small angle X ray scattering measurements revealed that the melt extrusion method leads to an uniform distribution of the inorganic phase in the ionomer matrix. Such structural analysis indicated that the improved the proton conduction properties of the composites, even with the addition of a high concentration of functionalized nanoparticles, are an outcome of the synergistic ionic network due to the hydrid organic inorganic proton conducting phases. However, an improvement of the fuel cell performance is observed for 2.5 wt of functionalized titanate nanotubes, which is a result of the lower ethanol crossover and the plasticizing effect of the aliphatic segments of the organic moieties grafted at the surface of the titanate nanoparticle

Practical Science and Environmental Education Workshop in Manaus, Brazil

It is an unequivocal fact that Amazonian tropical forest is the largest remaining primary forest in the world. The ecosystem in the region is e tremely comple with high biodiversity (Peres et al. 2010). Conservation and protection of the dynamic forest and river regions is e tremely important not only for the natural environments, but also for the economy and social dependence of benefits from such abundant natural environments. Important natural parameters that affect status of the natural environments include light (natural sunlight), soil, and water, which abundantly e ist in the Amazon region. Solar energy is the primary energy source for the majority of living organisms in both terrestrial and aquatic ecosystems, and drives the diurnal and seasonal cycles of biogeochemical processes (Monteith & Unsworth 2013). In particular, in situ light data remains one of the most underappreciated data measurements although having a significant impact on the physical, chemical and biological processes in the ecosystem (Johnsen 2012). Soil provides the fundamental basis for all terrestrial living organisms including the Amazonian forests as well as life-sustaining infrastructure for human society. Water is the most essential single entity to constitute all organisms from a single cell to the earth. Understanding of importance and roles of each factor and interaction of such comple dynamics in the natural environments can serve as fundamental platform for natural scientists, particularly for young scientists such as university students. The objective of this workshop was to provide hand- on scientific and environmental education for university students in Manaus, Amazonas, Brazil through practical field measurements using the three most important parameters in the natural ecosystem composed of natural sunlight, soil, and water. The workshop was divided into a series of lectures, in situ field sampling, and data processing, analysis and interpretation with the ultimate goal of empowering the undergraduate students with research-centered environmental education and e perience of developing international collaboration.departmental bulletin pape

Entropy-corrected new agegraphic dark energy in Horava-Lifshitz cosmology

We study the entropy-corrected version of the new agegraphic dark energy (NADE) model and dark matter in a spatially non-flat Universe and in the framework of Ho\v{r}ava-Lifshitz cosmology. For the two cases containing noninteracting and interacting entropy-corrected NADE (ECNADE) models, we derive the exact differential equation that determines the evolution of the ECNADE density parameter. Also the deceleration parameter is obtained. Furthermore, using a parametrization of the equation of state parameter of the ECNADE model as $\omega_{\Lambda}(z)=\omega_0+\omega_1 z$, we obtain both $\omega_0$ and $\omega_1$. We find that in the presence of interaction, the equation of state parameter $\omega_0$ of this model can cross the phantom divide line which is compatible with the observation.Comment: 20 pages, 2 figures, to appear in 'Astrophysics and Space Science