Dynamics of self-propelled colloids and their application as active matter

Colloïden bewegen in suspensie door Browniaanse beweging. Echter, deze vorm van bewegen is willekeurig. Dit in tegenstelling tot bijvoorbeeld zwemmende bacteriën,die even groot zijn, maar die het vermogen hebben om zich in een bepaalde richting te bewegen door chemicaliën om te zetten in mechanische beweging. In dit proefschrift zijn levenloze colloïdale deeltjes uitgerust met katalytisch materiaal om zelfvoortstuwende microzwemmers te vormen. Het eerste deel van het proefschrift geeft achtergrondinformatie over fabricage en zelfaandrijving van deze "actieve" colloïden en hun gebruik als modelsystemen om het zwemmen en de opkomst van collectieve fenomenen bestuderen. Om gerichte zelfvoortstuwing te bereiken, zou het colloïdale deeltje typisch moeten bestaan uit verschillende materialen, of een anisotrope vorm. Het bevat een materiaal dat een externe energiebron zoals chemische brandstof of licht kan omzetten in beweging. Dit proefschrift bestudeert de beweging van zelfvoortstuwende colloïden in complexe omgevingen. We ontwikkelden een serie van toepassingen van deze actieve colloïden en onderzochten hoe zelfaandrijvende colloïden kunnen worden gebruikt om de functie van nanosensors te verbeteren. Alhoewel een aanzienlijke hoeveelheid van theoretisch en experimenteel onderzoek zich heeft gericht op het begrijpen van de dynamiek van dergelijke colloïden, realistische toepassingen om actieve materialen te realiseren is grotendeels achterwege gebleven. Dit proefschrift laat zien hoe we eindelijk een dichte bulk suspensie van zelfrijdende chemisch actieve colloïden kunnen vormen die aan de basis voor nieuwe 'actieve materialen'

Surface roughness-induced speed increase for active Janus micromotors

We demonstrate a simple physical fabrication method to control surface roughness of Janus micromotors and fabricate self-propelled active Janus microparticles with rough catalytic platinum surfaces that show a four-fold increase in their propulsion speed compared to conventional Janus particles coated with a smooth Pt layer.Postprint (published version

Strategies to control invasion of Sailfin Armoured Catfish, Pterygoplichthys spp. in wastewater-fed aquaculture bheries of East Kolkata Wetland, India with suggestion of a modified barrier based on the biological and behavioural characteristics

Sailfin armoured catfish (Pterygoplichthys spp.), an alien invasive species of family Loricariidae has invaded extensively in wastewater-fed large aquaculture ponds (locally called ‘bheries’) of East Kolkata Wetlands (EKW), West Bengal, India. As there is no viable controlling method at present, commonly these fishes are removed by different physical methods and discarded. In the present study, we investigated the effectiveness and suitability of different in-practice Pterygoplichthys spp. control methods, based on on-field sampling, biological and behavioural study of the fish and also response analysis of the stakeholder’s of EKW. The results indicate that in-practice eradication efforts, like ‘repeated seine netting’ with or without removal of Eichhornia sheath of the pond periphery and ‘dewatering of pond’ aiming to reduce or eradicate Pterygoplichthys spp., are not fully effective, because of the capture avoidance ability and burrowing habit of these fishes. We found deep and branching burrows of Pterygoplichthys spp. in aquaculture ponds of EKW, with maximum burrow depth of 58 cm, and water in that burrows even after 12 days of dewatering. Hence, it is suggested stakeholders to keep dewatered pond exposed to sunlight for at least four weeks or above to ensure complete water-out from the burrows in which Pterygoplichthys spp. take shelter or lay their eggs. ‘Multilayer bamboo fencing’ or ‘combination of bamboo fencing and net barrier’ use by the stakeholders of EKW to prevent intrusion or re-intrusion of Pterygoplichthys spp. were found only partially effective, because of the capability of these fishes to damage net-blocking through their hard dorsal and pectoral spines or entry through the holes dug across the barrier in beneath or banks of the sewage intake channel. Based on learning on the biological and behavioural characteristics of Pterygoplichthys spp., we then suggested a modified version of barrier to the stakeholder’s of EKW, incorporating a sewage feeder pipeline, a concrete collection chamber with size separation arrangement made of hard materials like wire mesh and a dam of specific dimensions across the channel, for effective prevention of intrusion of these fishes in their aquaculture bheries

Chemical Nanomotors at the Gram Scale Form a Dense Active Optorheological Medium

The rheological properties of a colloidal suspension are a function of the concentration of the colloids and their interactions. While suspensions of passive colloids are well studied and have been shown to form crystals, gels, and glasses, examples of energy-consuming active colloidal suspensions are still largely unexplored. Active suspensions of biological matter, such as motile bacteria or dense mixtures of active actin-motor-protein mixtures have, respectively, reveals superfluid-like and gel-like states. Attractive inanimate systems for active matter are chemically self-propelled particles. It has so far been challenging to use these swimming particles at high enough densities to affect the bulk material properties of the suspension. Here, it is shown that light-triggered asymmetric titanium dioxide that self-propel, can be obtained in large quantities, and self-organize to make a gram-scale active medium. The suspension shows an activity-dependent tenfold reversible change in its bulk viscosity

Functional consequences of extended high frequency hearing impairmenEvidence from the speech, spatial, and qualities of hearing scale

Hearing loss in the extended high frequencies, despite a normal audiogram, could affect speech-in-noise recognition. However, it is not known if extended high frequency (EHF) hearing loss is associated with everyday listening and communication deficits. The present study aimed to determine the functional effects of impaired EHF hearing among adults using the Speech, Spatial, and Qualities of Hearing Scale (SSQ). A secondary objective was to evaluate the relationship between objective (speech-in-noise recognition) and subjective (SSQ) measures of hearing function. Listeners with EHF hearing loss provided lower SSQ ratings compared with their EHF-normal counterparts. The lower ratings could not be attributed to the age or standard audiogram of the listeners. Ratings from more than 50% of EHF-impaired listeners were below the 2 SD cutoff point obtained from EHF-normal listeners. The mean speech recognition threshold was poorer for EHF-impaired listeners, and a poorer speech recognition threshold was associated with lower SSQ ratings, i.e., poorer self-reported hearing ability. For some listeners, EHF hearing loss could be the missing link between self-reported hearing difficulty in the presence of a normal audiogram. These findings provide evidence for the functional deficits associated with EHF hearing loss and invoke the need for future investigations into the management of EHF loss

Active colloidal propulsion over a crystalline surface

Westudy both experimentally and theoretically the dynamics of chemically self-propelled Janus colloids moving atop a two-dimensional crystalline surface. The surface is a hexagonally close-packed monolayer of colloidal particles of the same size as the mobile one. The dynamics of the self-propelled colloid reflects the competition between hindered diffusion due to the periodic surface and enhanced diffusion due to active motion. Which contribution dominates depends on the propulsion strength, which can be systematically tuned by changing the concentration of a chemical fuel. The mean-square displacements (MSDs) obtained from the experiment exhibit enhanced diffusion at long lag times. Our experimental data are consistent with a Langevin model for the effectively two-dimensional translational motion of an active Brownian particle in a periodic potential, combining the confining effects of gravity and the crystalline surface with the free rotational diffusion of the colloid. Approximate analytical predictions are made for the MSD describing the crossover from free Brownian motion at short times to active diffusion at long times. The results are in semi-quantitative agreement with numerical results of a refined Langevin model that treats translational and rotational degrees of freedom on the same footing