Mathematical model on surface reaction diffusion in the presence of front chemical reaction

The article discusses a mathematical model of solid-phase diffusion over substance surface accompanied a frontal chemical reaction. The purpose of our article is to describe the concentration distribution and surface reacted layer growth. The model is a system parabolic equations, complicated with the presence of mobile front. It takes account of diffusive fluxes redistribution, sublimation from the surface, chemical reaction reversibility. The asymptotic approximation of the obtained nonlinear problem is constructed. Numerical solution was also carried out. Both numerical and analytical solutions conform to each other in a wide range of parameter changes, whereas observed differences are explained. It was obtained that the reaction front at the substrate surface grows as the fourth root of time in the assumed absence of evaporation and reaction reversibility. In the presence of evaporation the logarithmic distribution law ln(t) is obtained. The theoretical possibility of sharp deceleration and stop of reaction product layer growth is obtained. © 2012 Elsevier Ltd. All rights reserved

Spin degrees of freedom and flattening of the spectra of single-particle excitations in strongly correlated Fermi systems

The impact of long-range spin-spin correlations on the structure of a flat portion in single-particle spectra $\xi(p)$, which emerges beyond the point, where the Landau state loses its stability, is studied. We supplement the well-known Nozieres model of a Fermi system with limited scalar long-range forces by a similar long-range spin-dependent term and calculate the spectra versus its strength $g$. It is found that Nozieres results hold as long as $g>0$. However, with $g$ changing its sign, the spontaneous magnetization is shown to arise at any nonzero $g$. The increase of the strength $|g|$ is demonstrated to result in shrinkage of the domain in momentum space, occupied by the flat portion of $\xi(p)$, and, eventually, in its vanishing.Comment: 7 pages, 15 figure

Damping effects and the metal-insulator transition in the two-dimensional electron gas

The damping of single-particle degrees of freedom in strongly correlated two-dimensional Fermi systems is analyzed. Suppression of the scattering amplitude due to the damping effects is shown to play a key role in preserving the validity of the Landau-Migdal quasiparticle picture in a region of a phase transition, associated with the divergence of the quasiparticle effective mass. The results of the analysis are applied to elucidate the behavior of the conductivity $\sigma(T)$ of the two-dimensional dilute electron gas in the density region where it undergoes a metal-insulator transition.Comment: 7 pages, 6 figures. Improved and slightly extended version: new paragraph about Hall effect + new Fig.

Thermal destruction of vessels with liquid upon heating

A new engineering technique of calculating the heating and thermal destruction of vessels containing liquid under extreme thermal loading conditions is offered. The heating of the shell and the internal vessel volume is described on the basis of the thermodynamic approach. The pressure growth in a vessel is a result of gas heating and liquid evaporation. Stresses within the shell and its destruction conditions are determined, which allows predicting the critical time of destruction upon heating. The calculation and experimental data for pressure growth inside the vessel are in good agreement

Mechanisms driving alteration of the Landau state in the vicinity of a second-order phase transition

The rearrangement of the Fermi surface of a homogeneous Fermi system upon approach to a second-order phase transition is studied at zero temperature. The analysis begins with an investigation of solutions of the equation $\epsilon(p)=\mu$, a condition that ordinarily has the Fermi momentum $p_F$ as a single root. The emergence of a bifurcation point in this equation is found to trigger a qualitative alteration of the Landau state, well before the collapse of the collective degree of freedom that is responsible for the second-order transition. The competition between mechanisms that drive rearrangement of the Landau quasiparticle distribution is explored, taking into account the feedback of the rearrangement on the spectrum of critical fluctuations. It is demonstrated that the transformation of the Landau state to a new ground state may be viewed as a first-order phase transition.Comment: 16 pages, 10 figure

Transport properties and the anisotropy of Ba_{1-x}K_xFe_2As_2 single crystals in normal and superconducting states

The transport and superconducting properties of Ba_{1-x}K_xFe_2As_2 single crystals with T_c = 31 K were studied. Both in-plane and out-of plane resistivity was measured by modified Montgomery method. The in-plane resistivity for all studied samples, obtained in the course of the same synthesis, is almost the same, unlike to the out-of plane resistivity, which differ considerably. We have found that the resistivity anisotropy \gamma=\rho_c /\rho_{ab} is almost temperature independent and lies in the range 10-30 for different samples. This, probably, indicates on the extrinsic nature of high out-of-plane resistivity, which may appear due to the presence of the flat defects along Fe-As layers in the samples. This statement is supported by comparatively small effective mass anisotropy, obtained from the upper critical field measurements, and from the observation of the so-called "Friedel transition", which indicates on the existence of some disorder in the samples in c-direction.Comment: 5 pages, 5 figure