Induced Growth of Asymmetric Nanocantilever Arrays on Polar Surfaces

©2003 The American Physical Society. The electronic version of this article is the complete one and can be found online at: http://link.aps.org/doi/10.1103/PhysRevLett.91.185502DOI: 10.1103/PhysRevLett.91.185502We report that the Zn-terminated ZnO (0001) polar surface is chemically active and the oxygenterminated (0001) polar surface is inert in the growth of nanocantilever arrays. Longer and wider "comblike" nanocantilever arrays are grown from the (0001)-Zn surface, which is suggested to be a self-catalyzed process due to the enrichment of Zn at the growth front. The chemically inactive (0001)-O surface typically does not initiate any growth, but controlling experimental conditions could lead to the growth of shorter and narrower nanocantilevers from the intersections between (0001)-O with (0110) surfaces

Beyond Wigner's isobaric multiplet mass equation: Effect of charge-symmetry-breaking interaction and Coulomb polarization

The quadratic form of the isobaric multiplet mass equation (IMME), which was originally suggested by Wigner and has been generally regarded as valid, is seriously questioned by recent high-precision nuclear mass measurements. The usual resolution to this problem is to add empirically the cubic and quartic $T_z$-terms to characterize the deviations from the IMME, but finding the origin of these terms remains an unsolved difficulty. Based on a strategy beyond the Wigner's first-order perturbation, we derive explicitly the cubic and quartic $T_z$-terms. These terms are shown to be generated by the effective charge-symmetry breaking and charge-independent breaking interactions in nuclear medium combined with the Coulomb polarization effect. Calculations for the $sd$- and lower $fp$-shells explore a systematical emergence of the cubic $T_z$-term, suggesting a general deviation from the original IMME. Intriguingly, the magnitude of the deviation exhibits an oscillation-like behavior with mass number, modulated by the shell effect.Comment: 13 pages, 4 figure

Correlation effects in the ground state charge density of Mott-insulating NiO: a comparison of ab-initio calculations and high-energy electron diffraction measurements

Accurate high-energy electron diffraction measurements of structure factors of NiO have been carried out to investigate how strong correlations in the Ni 3d shell affect electron charge density in the interior area of nickel ions and whether the new ab-initio approaches to the electronic structure of strongly correlated metal oxides are in accord with experimental observations. The generalized gradient approximation (GGA) and the local spin density approximation corrected by the Hubbard U term (LSDA+U) are found to provide the closest match to experimental measurements. The comparison of calculated and observed electron charge densities shows that correlations in the Ni 3d shell suppress covalent bonding between the oxygen and nickel sublattices.Comment: 6 pages, LaTeX and 5 figures in the postscript forma