Graphene heterostructures for spin and charge transport

A single atom thick layer of graphite is known as graphene. Despite its simplicity, graphene has made a major impact in research after being demonstrated to exist in 2004. Not only is it easy to make, using graphite, tape and a substrate, it also has remarkable electronic properties. But because graphene is basically a large surface, it is easily influenced by external factors. To improve the electronic quality of a graphene layer, it can be shielded from the environment using a thin layer of hexagonal boron nitride (h-BN). Stacking graphene and h-BN is however not trivial. Here we developed two methods to create such heterostructures. A straightforward way is to first deposit graphene on a sacrificial polymer layer and then release it on a h-BN crystal. A cleaner approach is by picking up crystal flakes one by one using a polymer coated stamp and depositing the resulting stack on a substrate. Using these methods, we create high quality graphene heterostructures, as is demonstrated by increased electron mobilities.Furthermore, we investigate graphene spin transport in heterostructure devices. Here the electron spin is used instead of charge to carry information. Graphene shows great potential due to its ability to carry spin information over record distances at room temperature. We find that in heterostructures spins can travel even further. Additionally, we exposed few layer graphene to irradiation and observe that spin transport properties are surprisingly robust despite the damage, further demonstrating the potential of graphene for spintronic applications

24 \textmu m length spin relaxation length in boron nitride encapsulated bilayer graphene

We have performed spin and charge transport measurements in dual gated high mobility bilayer graphene encapsulated in hexagonal boron nitride. Our results show spin relaxation lengths $\lambda_s$ up to 13~\textmu m at room temperature with relaxation times $\tau_s$ of 2.5~ns. At 4~K, the diffusion coefficient rises up to 0.52~m$^2$/s, a value 5 times higher than the best achieved for graphene spin valves up to date. As a consequence, $\lambda_s$ rises up to 24~\textmu m with $\tau_s$ as high as 2.9~ns. We characterized 3 different samples and observed that the spin relaxation times increase with the device length. We explain our results using a model that accounts for the spin relaxation induced by the non-encapsulated outer regions.Comment: 5 pages and 4 figure

A laboratory comparison of the interactions between three plastic mulch types and 38 active substances found in pesticides

Background: In semi-arid regions, the use of plastic mulch and pesticides in conventional agriculture is nearly ubiquitous. Although the sorption of pesticides on Low Density Polyethylene (LDPE) has been previously studied, no data are available for other plastics such as Pro-oxidant Additive Containing (PAC) plastics or “biodegradable” (Bio) plastics. The aim of this research was to measure the sorption pattern of active substances from pesticides on LDPE, PAC and Bio plastic mulches and to compare the decay of the active substances in the presence and absence of plastic debris. Methods: For this purpose, 38 active substances from 17 insecticides, 15 fungicides and six herbicides commonly applied with plastic mulching in South-east Spain were incubated with a 3 × 3 cm2 piece of plastic mulch (LDPE, PAC and Bio). The incubation was done in a solution of 10% acetonitrile and 90% distilled water at 35 _C for 15 days in the dark. The Quick Easy Cheap Effective Rugged Safe approach was adapted to extract the pesticides. Results: The sorption behavior depended on both the pesticide and the plastic mulch type. On average, the sorption percentage was ~23% on LDPE and PAC and ~50% on Bio. The decay of active substances in the presence of plastic was ~30% lesser than the decay of active substances in solution alone. This study is the first attempt at assessing the behavior of a diversity of plastic mulches and pesticides to further define research needs.This work was supported by the European Commission Horizon 2020 project Diverfarming (grant agreement 728003). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript

Targeting estrogen signaling and biosynthesis for aged skin repair

Non-healing skin wounds are disproportionally prevalent in older adults. Current treatments do not account for the particularities of aged skin and result in inadequate outcomes. Overall, healing chronic wounds in the elderly remains a major unmet clinical need. Estrogens play a critical role in reproduction but also have important actions in non-reproductive organs. Estrogen biosynthesis and signaling pathways are locally activated during physiological wound healing, processes that are inhibited in elderly estrogen-deprived skin. Estrogen deprivation has been shown to be a critical mediator of impaired wound healing in both postmenopausal women and aged men, and topical estrogen application reverses age-associated delayed wound healing in both elderly men and women. These data indicate that adequate estrogen biosynthesis and properly regulated estrogen signaling pathways are essential for normal wound healing and can be targeted to optimize tissue repair in the elderly. However, due to fundamental questions regarding how to safely restore estrogen signaling locally in skin wounds, there are currently no therapeutic strategies addressing estrogen deficiency in elderly chronic wounds. This review discusses established and recent literature in this area and proposes the hypothesis that estrogen plays a pleiotropic role in skin aging and that targeting estrogen signaling and biosynthesis could promote skin repair in older adults

Interactions between agricultural mulching plastic debris and pesticides

In semi-arid regions, the use of plastic mulch and pesticides in conventional agriculture is nearly ubiquitous. The use of plastics and pesticides lead both to the release of residues in the soils. The degradation of plastic and pesticide residues in the soil have been previously studied, but not together despite the fact that pesticides may be sorbed to plastics and that the sorption may change the degradation rate. In fact, the sorption of pesticides on Low Density Polyethylene (LDPE) has been previously studied, but no data is available for other plastics such as Pro-oxidant Additive Containing (PAC) plastics or "biodegradable" (Bio) plastics. The aim of this research was to measure the sorption pattern of active substances from 38 pesticides on LDPE, PAC and Bio plastic mulches and to compare the decay of the active substances in the presence and absence of plastic debris. For this purpose, 38 active substances from 17 insecticides, 15 fungicides and 6 herbicides commonly applied with plastic mulching in South-east Spain were incubated at 35°C for 15 days with a 3×3 cm² square of plastic mulch (LDPE, PAC and Bio). The QuEChERS (Quick Easy Cheap Effective Rugged Safe) approach was adapted to extract the pesticides. The sorption behaviour depended on both, the pesticide and the plastic mulch type. On average, the sorption percentage was ~23% on LDPE and PAC, and ~50% on Bio. The decay of active substances in the presence of plastic was, on average, 30% lower than the decay of active substances in solution alone. Therefore, efficacy, transport, degradability and/or eco-toxicity of active substances from pesticides may be affected by sorption on plastics. Additionally the sorption of pesticides on plastic debris may affect the plastic degradability due to the toxicity of pesticides to some soil organisms

Relating Hysteresis and Electrochemistry in Graphene Field Effect Transistors

Hysteresis and commonly observed p-doping of graphene based field effect transistors (FET) was already discussed in reports over last few years. However, the interpretation of experimental works differs; and the mechanism behind the appearance of the hysteresis and the role of charge transfer between graphene and its environment are not clarified yet. We analyze the relation between electrochemical and electronic properties of graphene FET in moist environment extracted from the standard back gate dependence of the graphene resistance. We argue that graphene based FET on a regular SiO2 substrate exhibits behavior that corresponds to electrochemically induced hysteresis in ambient conditions, and can be caused by charge trapping mechanism associated with sensitivity of graphene to the local pH.Comment: 5 pages, 3 figure

Pesticide residues in European agricultural soils – A hidden reality unfolded

Pesticide use is a major foundation of the agricultural intensification observed over the last few decades. As a result, soil contamination by pesticide residues has become an issue of increasing concern due to some pesticides' high soil persistence and toxicity to non-target species. In this study, the distribution of 76 pesticide residues was evaluated in 317 agricultural topsoil samples from across the European Union. The soils were collected in 2015 and originated from 11 EU Member States and 6 main cropping systems. Over 80% of the tested soils contained pesticide residues (25% of samples had 1 residue, 58% of samples had mixtures of two or more residues), in a total of 166 different pesticide combinations. Glyphosate and its metabolite AMPA, DDTs (DDT and its metabolites) and the broad-spectrum fungicides boscalid, epoxiconazole and tebuconazole were the compounds most frequently found in soil samples and the compounds found at the highest concentrations. These compounds occasionally exceeded their predicted environmental concentrations in soil but were below the respective toxic endpoints for standard in-soil organisms. Maximum individual pesticide content assessed in a soil sample was 2.05 mg kg−1 while maximum total pesticide content was 2.87 mg kg−1. This study reveals that the presence of mixtures of pesticide residues in soils are the rule rather than the exception, indicating that environmental risk assessment procedures should be adapted accordingly to minimize related risks to soil life and beyond. This information can be used to implement monitoring programs for pesticide residues in soil and to trigger toxicity assessments of mixtures of pesticide residues on a wider range of soil species in order to perform more comprehensive and accurate risk assessments.</p