Understanding the nucleation mechanisms of Carbon Nanotubes in catalytic Chemical Vapor Deposition

The nucleation of carbon caps on small nickel clusters is studied using a tight binding model coupled to grand canonical Monte Carlo simulations. It takes place in a well defined carbon chemical potential range, when a critical concentration of surface carbon atoms is reached. The solubility of carbon in the outermost Ni layers, that depends on the initial, crystalline or disordered, state of the catalyst and on the thermodynamic conditions, is therefore a key quantity to control the nucleation

Time-dependent Fr\"ohlich transformation approach for two-atom entanglement generated by successive passage through a cavity

Time-dependent Fr\"ohlich transformations can be used to derive an effective Hamiltonian for a class of quantum systems with time-dependent perturbations. We use such a transformation for a system with time-dependent atom-photon coupling induced by the classical motion of two atoms in an inhomogeneous electromagnetic field. We calculate the entanglement between the two atoms resulting from their motion through a cavity as a function of their initial position difference and velocity.Comment: 7 pages, 3 figure