1,160 research outputs found
Synthesis, structures and reduction chemistry of monophthalocyanine scandium hydroxides
The preparation and structural characterization of a pair of scanditun(III) phthalocyanine hydroxide complexes were achieved by reaction of PcScCl with alkali metal alkoxides, likely via hydrolysis of soluble PcSc-alkoxide intermediates. A Sc2Li2 (mu(3)-OH)(4) cubane supported by two distorted Pc rings of the form (PcSc)(2)(mu(3)-OH)(4)Li-2 (THF)(DME) was isolated from the reaction of PcScCl with (LiOPr)-Pr-i, while a simpler alkali-metal-free [Pc2Sc2(mu(2)-OH)(2)(THE)] was obtained from addition of (NaOBu)-Bu-i; both structures are reminiscent of bent metallocenes, with dihedral angles between the two Pc rings of 50.8 and 37.7 degrees respectively. A soluble PcScOH material can also be obtained directly via hydrolysis of insoluble PcScCl in approximately 95:5 THF:water. Reduction of the Pc ring of PcScCl using KC8 is reversible and generates Pc3- and Pc4--containing materials that were characterized via UV-vis spectroscopy and, where appropriate EPR and H-1 NMR spectroscopy; analogous reductions of the PcScOH-based species were irreversible. Exposure of the air-sensitive, reduced PcScCl-based species to ambient atmosphere generated PcScOH materials analogous to the direct hydrolysis route
Identity of the imaginary-time and real-time thermal propagators for scalar bound states in a one-generation Nambu-Jona-Lasinio model
By rigorous reanalysis of the results, we have proven that the propagators at
finite temperature for scalar bound states in one-generation fermion condensate
scheme of electroweak symmetry breaking are in fact identical in the
imaginary-time and the real-time formalism. This dismisses the doubt about
possible discrepancy between the two formalisms in this problem. Identity of
the derived thermal transformation matrices of the real-time matrix propagators
for scalar bound states without and with chemical potential and the ones for
corresponding elementary scalar particles shows similarity of thermodynamic
property between the two types of particles. Only one former inference is
modified, i.e. when the two flavors of fermions have unequal nonzero masses,
the amplitude of the composite Higgs particle will decay instead grow in time.Comment: 5 pages, revtex4, no figure
One Dimensional Chain with Long Range Hopping
The one-dimensional (1D) tight binding model with random nearest neighbor
hopping is known to have a singularity of the density of states and of the
localization length at the band center. We study numerically the effects of
random long range (power-law) hopping with an ensemble averaged magnitude
\expectation{|t_{ij}|} \propto |i-j|^{-\sigma} in the 1D chain, while
maintaining the particle-hole symmetry present in the nearest neighbor model.
We find, in agreement with results of position space renormalization group
techniques applied to the random XY spin chain with power-law interactions,
that there is a change of behavior when the power-law exponent becomes
smaller than 2
Magnetic enhancement of CoZnFeO spinel oxide by mechanical milling
We report the magnetic properties of mechanically milled
CoZnFeO spinel oxide. After 24 hours milling of the
bulk sample, the XRD spectra show nanostructure with average particle size
20 nm. The as milled sample shows an enhancement in magnetization and
ordering temperature compared to the bulk sample. If the as milled sample is
annealed at different temperatures for the same duration, recrystallization
process occurs and approaches to the bulk structure on increasing the annealing
temperatures. The magnetization of the annealed samples first increases and
then decreases. At higher annealing temperature ( 1000C) the system
shows two coexisting magnetic phases {\it i.e.}, spin glass state and
ferrimagnetic state, similar to the as prepared bulk sample. The room
temperature M\"{o}ssbauer spectra of the as milled sample, annealed at
300C for different durations (upto 575 hours), suggest that the observed
change in magnetic behaviour is strongly related with cations redistribution
between tetrahedral (A) and octahedral (O) sites in the spinel structure. Apart
from the cation redistribution, we suggest that the enhancement of
magnetization and ordering temperature is related with the reduction of B site
spin canting and increase of strain induced anisotropic energy during
mechanical milling.Comment: 14 pages LaTeX, 10 ps figure
Schwinger-Dyson approach to non-equilibrium classical field theory
In this paper we discuss a Schwinger-Dyson [SD] approach for determining the
time evolution of the unequal time correlation functions of a non-equilibrium
classical field theory, where the classical system is described by an initial
density matrix at time . We focus on field theory in 1+1
space time dimensions where we can perform exact numerical simulations by
sampling an ensemble of initial conditions specified by the initial density
matrix. We discuss two approaches. The first, the bare vertex approximation
[BVA], is based on ignoring vertex corrections to the SD equations in the
auxiliary field formalism relevant for 1/N expansions. The second approximation
is a related approximation made to the SD equations of the original formulation
in terms of alone. We compare these SD approximations as well as a
Hartree approximation with exact numerical simulations. We find that both
approximations based on the SD equations yield good agreement with exact
numerical simulations and cure the late time oscillation problem of the Hartree
approximation. We also discuss the relationship between the quantum and
classical SD equations.Comment: 36 pages, 5 figure
Adiabatic quantum pump in the presence of external ac voltages
We investigate a quantum pump which in addition to its dynamic pump
parameters is subject to oscillating external potentials applied to the
contacts of the sample. Of interest is the rectification of the ac currents
flowing through the mesoscopic scatterer and their interplay with the quantum
pump effect. We calculate the adiabatic dc current arising under the
simultaneous action of both the quantum pump effect and classical
rectification. In addition to two known terms we find a third novel
contribution which arises from the interference of the ac currents generated by
the external potentials and the ac currents generated by the pump. The
interference contribution renormalizes both the quantum pump effect and the ac
rectification effect. Analysis of this interference effect requires a
calculation of the Floquet scattering matrix beyond the adiabatic approximation
based on the frozen scattering matrix alone. The results permit us to find the
instantaneous current. In addition to the current generated by the oscillating
potentials, and the ac current due to the variation of the charge of the frozen
scatterer, there is a third contribution which represents the ac currents
generated by an oscillating scatterer. We argue that the resulting pump effect
can be viewed as a quantum rectification of the instantaneous ac currents
generated by the oscillating scatterer. These instantaneous currents are an
intrinsic property of a nonstationary scattering process.Comment: 11 pages, 1 figur
Photon-assisted tunneling in a Fe8 Single-Molecule Magnet
The low temperature spin dynamics of a Fe8 Single-Molecule Magnet was studied
under circularly polarized electromagnetic radiation allowing us to establish
clearly photon-assisted tunneling. This effect, while linear at low power,
becomes highly non-linear above a relatively low power threshold. This
non-linearity is attributed to the nature of the coupling of the sample to the
thermostat.These results are of great importance if such systems are to be used
as quantum computers.Comment: 4 pages, 4 figure
Noise-assisted classical adiabatic pumping in a symmetric periodic potential
We consider a classical overdamped Brownian particle moving in a symmetric
periodic potential. We show that a net particle flow can be produced by
adiabatically changing two external periodic potentials with a spatial and a
temporal phase difference. The classical pumped current is found to be
independent of the friction and to vanish both in the limit of low and high
temperature. Below a critical temperature, adiabatic pumping appears to be more
efficient than transport due to a constant external force.Comment: six pages, 3 figure
Renormalized kinetic theory of classical fluids in and out of equilibrium
We present a theory for the construction of renormalized kinetic equations to
describe the dynamics of classical systems of particles in or out of
equilibrium. A closed, self-consistent set of evolution equations is derived
for the single-particle phase-space distribution function , the correlation
function , the retarded and advanced density response
functions to an external potential , and
the associated memory functions . The basis of the theory is an
effective action functional of external potentials that
contains all information about the dynamical properties of the system. In
particular, its functional derivatives generate successively the
single-particle phase-space density and all the correlation and density
response functions, which are coupled through an infinite hierarchy of
evolution equations. Traditional renormalization techniques are then used to
perform the closure of the hierarchy through memory functions. The latter
satisfy functional equations that can be used to devise systematic
approximations. The present formulation can be equally regarded as (i) a
generalization to dynamical problems of the density functional theory of fluids
in equilibrium and (ii) as the classical mechanical counterpart of the theory
of non-equilibrium Green's functions in quantum field theory. It unifies and
encompasses previous results for classical Hamiltonian systems with any initial
conditions. For equilibrium states, the theory reduces to the equilibrium
memory function approach. For non-equilibrium fluids, popular closures (e.g.
Landau, Boltzmann, Lenard-Balescu) are simply recovered and we discuss the
correspondence with the seminal approaches of Martin-Siggia-Rose and of
Rose.and we discuss the correspondence with the seminal approaches of
Martin-Siggia-Rose and of Rose.Comment: 63 pages, 10 figure
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