Efficient Inverted ITO-Free Organic Solar Cells Based on Transparent Silver Electrode with Aqueous Solution-Processed ZnO Interlayer

Efficient inverted organic solar cells (OSCs) with the MoO3 (2 nm)/Ag (12 nm) transparent cathode and an aqueous solution ZnO electron extraction layer processed at low temperature are investigated in this work. The blend of low bandgap poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7) and [6,6]-phenyl-C71-butyric acid methylester (PC71BM) is employed as the photoactive layer here. A power conversion efficiency (PCE) of 5.55% is achieved for such indium tin oxide- (ITO-) free OSCs under AM 1.5G simulated illumination, comparable to that of ITO-based reference OSCs (PCE of 6.11%). It is found that this ZnO interlayer not only slightly enhances the transparency of MoO3/Ag cathode but also obtains a lower root-mean-square (RMS) roughness on the MoO3/Ag surface. Meanwhile, ITO-free OSCs also show a good stability. The PCE of the devices still remains above 85% of the original values after 30 days, which is slightly superior to ITO-based reference OSCs where the 16% degradation in PCE is observed after 30 days. It may be instructive for further research of OSCs based on metal thin film electrodes

ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes

ITO-free semitransparent organic solar cells (OSCs) based on MoO3/Ag anodes with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester films as the active layer are investigated in this work. To obtain the optimal transparent (MoO3)/Ag anode, ITO-free reference OSCs are firstly fabricated. The power conversion efficiency (PCE) of 2.71% is obtained for OSCs based on the optimal MoO3 (2 nm)/Ag (9 nm) anode, comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are investigated. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% and 0.67% is obtained for illumination from the anode and cathode side, respectively, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) (Sol. Energy Mater. Sol. Cells, 95, pp. 877–880, 2011). The transparency and PCE of ITO-free semitransparent OSCs can be further improved by introducing a light couple layer. The developed method is compatible with various substrates, which is instructive for further research of ITO-free semitransparent OSCs

The Prediction of Evacuation Efficiency on Metro Platforms Based on Passengers’ Decision-Making Capability

In the research, decision-making capabilities are explored in relation to the prediction of evacuation efficiency to improve forecast accuracy on metro platforms. For this purpose, this study reviewed theories related to evacuation behaviours utilising the anomaly-seeking approach and the paradigm of relationship development. The conceptual framework of decision-making capability and evacuation behaviours was explored based on risk perception, level of emergency knowledge, survivability and emotion, and their relationship with the partial least squares equation was constructed. A predictive model of evacuation efficiency and its differential equations incorporating this relationship were also proposed based on the epidemic model. By developing and testing the conceptual framework and model, theoretical support is provided for evacuation behaviour, while assisting emergency management in developing plans and measures to respond to emergencies on metro platforms. This study realises the possibility of predicting evacuation efficiency from a decision-making capability perspective

Analysis of the Drivers of Highway Construction Companies Adopting Smart Construction Technology

In this study, we aimed to identify the influencing factors that drive highway construction companies to adopt smart construction technologies. Using expert interviews and expert scoring, we collected interview data from 25 experts in the field and we proposed the TOSE framework based on the TOE framework, identifying four dimensions and fourteen influencing factors. We analyzed the results using the Fuzzy DEMATEL-ISM method, and we then summarized the findings according to the evaluation criteria to determine the validity of the fourteen hypotheses and the extent to which they drive highway construction companies to adopt smart construction technologies. The findings of this paper are of high value to decision makers and participants in highway construction companies, as well as to other companies in the construction industry, in their decision to adopt smart construction technologies

Failure Mechanism and Residual Stress Analysis of Crystal Materials for the Thermal Battery

This paper investigates the thermal battery as a research topic. We conducted an in-depth analysis of various thermal battery aspects, such as the cathode material CoS2 and electrolyte material morphology, crystal type, and interface state changes before and after service. The aim was to explore the core reaction and main failure mechanisms of the thermal battery. Prior to the reaction, the thermal battery cathode and electrolyte material consisted of pure-phase CoS2 and a composition of MgO-LiF/LiBr/LiCl. After service, the cathode and electrolyte of the single thermal battery exhibited significant morphological alterations caused by the presence of a molten state. The cathode transformed from CoS2 to Co3S4 and Co9S8 together with the presence of a marginal quantity of Co monomers visible throughout the discharge process, which was confirmed by means of XRD and XPS analyses. After the reaction, the electrolyte material was primarily made up of LiF, LiBr, and LiCl while the crystal components remained largely unaltered, albeit with apparent morphological variations. As was deduced from the thermodynamic analysis, the cathode material’s decomposition temperature stood at 655 °C, exceeding the working temperature of the thermal battery (500 °C) by a considerable margin, which is indicative of outstanding thermal durability within the thermal battery’s operational temperature range. Furthermore, the discharge reaction of the positive electrode was incomplete, resulting in reduced CoS2 residue in the thermal battery monomer after service. The reaction yielded a combination of Co3S4, Co9S8, and small amounts of Co monomers, indicating possible inconsistencies in the phase composition of the pole piece during the reaction process. In this study, we examine the distribution of residual stress in the thermal battery under various operating conditions. The simulation results indicate that exposure to a 70 °C environment for 2 h causes the maximum residual stress of the battery, which had an initial temperature of 25 °C, to reach 0.26 GPa. The thermal battery subjected to an initial temperature of 25 °C exhibited a maximum residual stress of 0.42 GPa subsequent to a 2-hour exposure to a temperature of −50 °C

Over-expression of dehydroascorbate reductase enhances oxidative stress tolerance in tobacco

Background: Ascorbic acid (Asc) is one of the most abundant antioxidants and it serves as a major contributor to protect plants against oxidative damage. Plants use two enzymes that participate in the metabolic recycling of Asc. One of these two enzymes is dehydroascorbate reductase (DHAR). It directly regenerates Asc from its oxidized state and thus prevents Asc from being irreversibly hydrolyzed to 2, 3-diketogulonic acid. This study aimed to examine whether over-expression of DHAR leads to an enhanced oxidative stress tolerance in tobacco plants. Results: In this study, we functionally characterized a novel JcDHAR gene from Jatropha curcas and found via quantitative RT-PCR analysis that JcDHAR can be induced with H2O2, salt and PEG stresses. The DHAR activities of transgenic tobacco plants increased from 2.0 to 5.3 fold compared to wild-type plants. As a result, the transgenic plants displayed enhanced tolerance to oxidative stress. Conclusions: Our results indicate that JcDHAR expression can effectively enhance the tolerance to oxidative stress in plants

Effects of growth temperature on the properties of InGaN channel heterostructures grown by pulsed metal organic chemical vapor deposition

Pulsed metal organic chemical vapor deposition (P-MOCVD) is introduced into the growth of high quality InGaN channel heterostructures. The effects of InGaN channel growth temperature on the structural and transport properties of the heterostructures are investigated in detail. High resolution x-ray diffraction (HRXRD) and Photoluminescence (PL) spectra indicate that the quality of InGaN channel strongly depends on the growth temperature. Meanwhile, the atomic force microscopy (AFM) results show that the interface morphology between the InGaN channel and the barrier layer also relies on the growth temperature. Since the variation of material properties of InGaN channel has a significant influence on the electrical properties of InAlN/InGaN heterostructures, the optimal transport properties can be achieved by adjusting the growth temperature. A very high two dimension electron gas (2DEG) density of 1.92 × 1013 cm−2 and Hall electron mobility of 1025 cm2/(V⋅s) at room temperature are obtained at the optimal growth temperature around 740 °C. The excellent transport properties in our work indicate that the heterostructure with InGaN channel is a promising candidate for the microwave power devices, and the results in this paper will be instructive for further study of the InGaN channel heterostructures

Preparation and characterization of paclitaxel palmitate albumin nanoparticles with high loading efficacy: an in vitro and in vivo anti-tumor study in mouse models

Background Combination of the prodrug technique with an albumin nano drug-loaded system is a novel promising approach for cancer treatment. However, the long-lasting and far-reaching challenge for the treatment of cancers lies in how to construct the albumin nanometer drug delivery system with lead compounds and their derivatives. Methods In this study, we reported the preparation of injectable albumin nanoparticles (NPs) with a high and quantitative drug loading system based on the NabTM technology of paclitaxel palmitate (PTX-PA). Results Our experimental study on drug tissue distribution in vivo demonstrated that the paclitaxel palmitate albumin nanoparticles (Nab-PTX-PA) remained in the tumor for a longer time post-injection. Compared with saline and paclitaxel albumin nanoparticles (Abraxane®), intravenous injection of Nab-PTX-PA not only reduced the toxicity of the drug in normal organs, and increased the body weight of the animals but maintained sustained release of paclitaxel (PTX) in the tumor, thereby displaying an excellent antitumor activity. Blood routine analysis showed that Nab-PTX-PA had fewer adverse effects or less toxicity to the normal organs, and it inhibited tumor cell proliferation more effectively as compared with commercial paclitaxel albumin nanoparticles. Conclusions This carrier strategy for small molecule drugs is based on naturally evolved interactions between long-chain fatty acids (LCFAs) and Human Serum Albumin (HSA), demonstrated here for PTX. Nab-PTX-PA shows higher antitumor efficacy in vivo in breast cancer models. On the whole, this novel injectable Nab-PTX-PA has great potential as an effective drug delivery system in the treatment of breast cancer