How Thermal Effect Regulates Cyclic Voltammetry of Supercapacitors

Cyclic voltammetry (CV) is a powerful technique for characterizing electrochemical properties of electrochemical devices. During charging-discharging cycles, thermal effect has profound impact on its performance, but existing theoretical models cannot clarify such intrinsic mechanism and often give poor prediction. Herein, we propose an interfacial model for the electro-thermal coupling, based on fundamentals in non-equilibrium statistical mechanics. By incorporating molecular interactions, our model shows a quantitative agreement with experimental measurements. The integral capacitance shows a first enhanced then decayed trend against the applied heat bath temperature. Such a relation is attributed to the competition between electrical attraction and Born repulsion via dielectric inhomogeneity, which is rarely understood in previous models. In addition, as evidenced in recent experimental CV tests, our model predicts the non-monotonic dependence of the capacitance on the bulk electrolyte density, further demonstrating its high accuracy. This work demonstrates a potential pathway towards next-generation thermal regulation of electrochemical devices

Transcriptome, microRNA, and degradome analyses of the gene expression of Paulownia with phytoplamsa

Primers of P. tomentosa miRNAs for qRT-PCR analysis. (DOCX 20.7 kb

Forest Trees for Biochar and Carbon Sequestration: Production and Benefits

Many tree species worldwide are suitable for making biochar (BC), with planted eucalypts in particular being very productive and extensive. Above- and below-ground carbon sequestration by Eucalyptus plantations depends on plantation management options. An intensively managed cultivar could sequester over 100 mt of C/ha at a cost of $21–40/mt. BC production systems ranging in size from small mobile units to large centralized facilities and many kiln technologies influence the quality and price of the BC produced as well as the ability to control emissions. While BC from wood has many applications, its use as a soil amendment in forest plantations is appealing as a long-term sequestration strategy and opportunity to grow more robust trees and increase survival rates. Research in Florida USA and elsewhere addresses responses of forest and agronomic crops to wood BC soil amendments with and without other fertilizers. In combination with the carbon sequestered through tree growth, sequestration of 2.5 mt/ha of wood BC as a soil amendment in Eucalyptus plantations has estimated costs ranging from$3.30–5.49/ton of C

Composted Sewage Sludge Application Reduces Mineral Fertilization Requirements and Improves Soil Fertility in Sugarcane Seedling Nurseries

Sugarcane demands large amounts of nutrients to reach a high level of productivity. Nutrients are generally supplied by mineral fertilizers, but their high costs and negative environmental impacts have generated interest in greater use of organic nutrient sources such as composted sewage sludge (CSS). In this study, we evaluated changes in soil chemical properties after the application of CSS or CSS/mineral fertilizer (MF) combinations to soil containing sugarcane seedlings under nursery conditions. Treatments included: T1: conventional mineral fertilization (MF) without application of CSS, T2: 100% of the recommended MF (06–30–24); T3: application of 2.5 Mg−1 CSS; T4: 5.0 Mg−1 CSS, T5: 7.5 Mg−1 CSS, T6: 2.5 Mg−1 CSS and 50% MF, T7: 5.0 Mg−1 CSS and 50% MF, T8: 7.5 Mg−1 CSS and 50% MF, T9: 2.5 Mg−1 CSS and 100% MF, T10: 5.0 Mg−1 CSS and 100% MF, T11: 7.5 Mg−1 CSS and 100% MF. Soil chemical properties were evaluated from the soil surface (0.0–0.25 m) and subsurface (0.25–0.50 m) horizons. The results showed that the increase in CSS application did not affect soil organic matter content at either depth, while Zn concentrations increased in the soil subsurface horizon. The application of CSS at 5.0 Mg ha−1 with or without 50% MF resulted in the highest pH values, sum of bases, cation-exchange capacity, P, K, Ca, Mg, Cu, and Zn in surface horizons. The use of CSS as an organic fertilizer in sugarcane nurseries improves soil fertility, reduces mineral fertilizer requirements, and, thus, facilitates the sustainable disposal of sewage sludge