Local fluctuations of vibrational polaritons monitored by two-dimensional infrared spectroscopy

We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due to intermolecule coherence. To further resolve such process, we develop a two-dimensional infrared spectroscopy (2D-IR) for molecules interacting with cavity modes. The cooperative feature in correspondence to the spectroscopic signal is specified. The results reveal the dark states by the cross peaks apart from the ones for polaritons, as a result of the breakdown of cooperativity between molecules. We further show that the breakdown of cooperativity profoundly connects to the localization of the vibrational excitations whereas the polariton modes are extended wave over several molecules. Besides, our work offers new physical insight for understanding the recent 2D-IR experiments where the interaction between dark modes and bright polaritons was evident.Comment: 11 pages, 6 figure

Cooperative Wave Mixing in Atoms and Solids

Enhancing optical signal is a subject of long term interest with many applications, such as trace chemical detection in the lab and standoff detection in the atmosphere. It is well known that optical properties of multi-level atomic and molecular system can be controlled and manipulated efficiently using quantum coherence and interference resulting an enhancement in optical signals. In this dissertation we investigate methods both with/without utilizing coherence of atomic and molecular systems to enhance optical signals. We use resonant Raman scattering and surface-enhanced Raman scattering which do not rely on molecular coherence to boost Raman signal from molecules, several orders of magnitude enhancement has been achieved. When coherence is introduced into atomic systems, cooperative emission is produced as a result of coherence. The emission is named Superfluorescence (SF) or superradiance (SR) depending on the initial coherence of the prepared systems. We study the properties of SF, yoked SF (YSF) and SR, the transition from YSF to SR and quantum beat exhibits in YSF/SR signal. More than thirty folds of pulse energy is obtained from SR compare to that of YSF. Possible applications of these results are also discussed

Ultralow-power local laser control of the dimer density in alkali-metal vapors through photodesorption

Ultralow-power diode-laser radiation is employed to induce photodesorption of cesium from a partially transparent thin-film cesium adsorbate on a solid surface. Using resonant Raman spectroscopy, we demonstrate that this photodesorption process enables an accurate local optical control of the density of dimer molecules in alkali-metal vapors.Comment: 4 pages, 4 figure

Laser spectroscopic technique for direct identification of a single virus I: FASTER CARS

From the famous 1918 H1N1 influenza to the present COVID-19 pandemic, the need for improved viral detection techniques is all too apparent. The aim of the present paper is to show that identification of individual virus particles in clinical sample materials quickly and reliably is near at hand. First of all, our team has developed techniques for identification of virions based on a modular atomic force microscopy (AFM). Furthermore, femtosecond adaptive spectroscopic techniques with enhanced resolution via coherent anti-Stokes Raman scattering (FASTER CARS) using tip-enhanced techniques markedly improves the sensitivity [M. O. Scully, et al, Proc. Natl. Acad. Sci. U.S.A. 99, 10994-11001 (2002)]

Laser Spectroscopic Technique for Direct Identification of a Single Virus I: FASTER CARS

From the famous 1918 H1N1 influenza to the present COVID-19 pandemic, the need for improved virial detection techniques is all too apparent. The aim of the present paper is to show that identification of individual virus particles in clinical sample materials quickly and reliably is near at hand. First of all, our team has developed techniques for identification of virions based on a modular atomic force microscopy (AFM). Furthermore, Femtosecond Adaptive Spectroscopic Techniques with Enhanced Resolution via Coherent Anti-Stokes Raman Scattering (FASTER CARS) [1] using tip-enhanced techniques markedly improves the sensitivity.Comment: 16 pages, 3 figure

Innovations in Surface Modification Techniques: Advancing Hydrophilic \textit{LiYF4_{4}:Yb, Er, Tm} Upconversion Nanoparticles and Their Applications

The development and application of upconversion nanoparticles (UCNPs) have garnered significant attention due to their unique optical properties and potential uses in bioimaging, drug delivery, and solar cells. However, the hydrophobic nature of UCNPs presents challenges in their synthesis and application, particularly in aqueous environments. We provide an overview of UCNPs, their synthesis challenges, and the importance of surface modification. Furthermore, we discuss the properties of \textit{LiYF_{4}:Yb, Er, Tm} UCNPs synthesized using novel 2,2-[ethylenebis(oxy)] bisacetic acid (EBAA) method and their versatile applications. Notably, the first Dynamic Light Scattering measurement on 05/22/2022 showed a size of 11.39 nm, and after 348 days on 04/05/2023, the same batch maintained a size of 13.8 nm, indicating excellent stability and no particle agglomeration over this extended period. This remarkable stability underscores the potential of UCNPs synthesized with the EBAA method for long-term applications. Finally, we compare the EBAA method with other surface modification techniques, exploring challenges and future perspectives for the use of hydrophilic UCNPs in various applications. This review aims to emphasize the significance of the EBAA method in advancing the field of upconversion nanoparticles and broadening their potential integration into diverse applications.Comment: 21 Pages, 1 table, 13 figure

The Warming Effect of Urbanization in the Urban Agglomeration Area Accelerates Vegetation Growth on the Urban–Rural Gradient

Urbanization has changed the environmental conditions of vegetation growth, such as the heat island effect, which has an indirect impact on vegetation growth. However, the extent to which the direct and indirect effects of the thermal environment changes caused by urbanization on vegetation growth are unclear. In this study, taking the example of the Guangdong–Hong Kong–Macao Greater Bay Area, a fast-growing national urban agglomeration in China, the relationship between vegetation growth and warming conditions during the period from 2001 to 2020 were explored by the net primary productivity (NPP) and land surface temperature (LST), based on the vegetation growth theory, in urban environments. The results show that there is a significant exponential relationship between the warming and the growth of large-scale vegetation. This relationship is mainly attributable to thermal environmental factors, since their multi-year average contribution rate on the interannual scale is 95.02%. The contribution rate varies on the seasonal scale, according to which the contribution rate is the largest in autumn and the smallest in winter. This research is of great significance for predicting the potential response of vegetation growth to future climate warming and improving vegetation growth in urban areas