On isotactic polypropylene annealing: Difference in final properties of neat and β-nucleated polypropylene

The effect of isotactic polypropylene (iPP) molecular weight and thermal treatment on final crystalline structure and mechanical properties were investigated by X-ray scattering, differential scanning calorimetry, tensile testing, and scanning electron microscopy. Neat and β-nucleated isotactic polypropylene were subjected to annealing above melting temperature of β-phase but still below melting temperature of α-phase, which caused both improvement of α crystallites and β to α-recrystallization, in case of nucleated material. As a consequence, the final mechanical properties like tensile strength and stiffness improved significantly. The increase is much more pronounced in the case of β to α-transformed materials with lower molecular weight. This phenomenon can also be attributed to the partial preservation of the specific structure of the amorphous phase present in β-nucleated polypropylene, in addition to the perfection of the crystalline phase. The amorphous phase comprises many interconnecting chains passing through several lamellae whereby providing a long-range effect. © BME-PT.CZ.02.2.69/0.0/0.0/16_027/0008464, IGA/FT/2020/011, IGA/UTB/FT/2021/007; European Commission, ECEuropean UnionEuropean Commission [CZ.02.2.69/0.0/0.0/16_027/0008464, IGA/FT/2020/011, IGA/UTB/FT/2021/007

The competition between self-seeding and specific nucleation in crystallization of long-chain branched polypropylene

The main purpose of this work is to present the effect of long-chain branching and specific α-nucleation on the optical properties, crystallization and supermolecular structure of polypropylene (PP). Commercially available α-nucleating/ clarifying agent 1,3;2,4-bis(3,4-dimethylbenzylidene)sorbitol (Millad 3988) was mixed into linear PP and long-chain branched PP (LCB-PP) in the concentration of 0.2 wt%. For the study of polymorphic composition, crystallinity, and crystallization process under isothermal conditions in the temperature range of 130–150 °C, differential scanning calorimetry and wide-angle X-ray scattering were used. Although the used nucleating/clarifying agent appears to have a slight effect on the optical properties of long-chain branched polypropylene, it does not appear to affect the crystallization kinetics significantly. LCB-PP exhibited self-nucleation, favored over nucleation by a specific nucleating agent.Tomas Bata University in Zlin, TBU, (CZ.02.2.69/0.0/0.0/19_073/0016941)project OP VVV Junior Grants TBU in Zlin [CZ.02.2.69/0.0/0.0/19_073/0016941