123 research outputs found

    Graphene zigzag ribbons, square lattice models and quantum spin chains

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    We present an extended study of finite-width zigzag graphene ribbons (ZGRs) based on a tight-binding model with hard-wall boundary conditions. We provide an exact analytic solution that clarifies the origin of the predicted width dependence on the conductance through junctions of ribbons with different widths. An analysis of the obtained solutions suggests a new description of ZGRs in terms of coupled chains. We pursue these ideas further by introducing a mapping between the ZGR model and the Hamiltonian for N-coupled quantum chains as described in terms of 2N Majorana fermions. The proposed mapping preserves the dependence of ribbon properties on its width thus rendering metallic ribbons for N odd and zero-gap semiconductor ribbons for N even. Furthermore, it reveals a close connection between the low-energy properties of the ZGR model and a continuous family of square lattice model Hamiltonians with similar width-dependent properties that includes the π\pi-flux and the trivial square lattice models. As a further extension, we show that this new description makes it possible to identify various aspects of the physics of graphene ribbons with those predicted by models of quantum spin chains (QSCs)

    Landau level mixing by full spin-orbit interactions

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    We study a two-dimensional electron gas in a perpendicular magnetic field in the presence of both Rashba and Dresselhaus spin-orbit interactions. Using a Bogoliubov transformation we are able to write an approximate formula for the Landau levels, thanks to the simpler form of the resulting Hamiltonian. The exact numerical calculation of the energy levels, is also made simpler by our formulation. The approximate formula and the exact numerical results show excellent agreement for typical semiconductors, especially at high magnetic fields. We also show how effective Zeeman coupling is modified by spin-orbit interactions.Comment: 5 pages, 5 figure

    Fine and ultrafine particle number and size measurements from industrial combustion processes : primary emissions field data

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    This study is to our knowledge the first to present the results of on-line measurements of residual nanoparticle numbers downstream of the flue gas treatment systems of a wide variety of medium- and large-scale industrial installations. Where available, a semi-quantitative elemental composition of the sampled particles is carried out using a Scanning Electron Microscope coupled with an Energy Dispersive Spectrometer (SEM-EDS). The semi-quantitative elemental composition as a function of the particle size is presented. EU's Best Available Technology documents (BAT) show removal efficiencies of Electrostatic Precipitator (ESP) and bag filter dedusting systems exceeding 99% when expressed in terms of weight. Their efficiency decreases slightly for particles smaller than 1 mu m but when expressed in terms of weight, still exceeds 99% for bag filters and 96% for ESP. This study reveals that in terms of particle numbers, residual nanoparticles (NP) leaving the dedusting systems dominate by several orders of magnitude. In terms of weight, all installations respect their emission limit values and the contribution of NP to weight concentrations is negligible, despite their dominance in terms of numbers. Current World Health Organisation regulations are expressed in terms of PM2.5 wt concentrations and therefore do not reflect the presence or absence of a high number of NP. This study suggests that research is needed on possible additional guidelines related to NP given their possible toxicity and high potential to easily enter the blood stream when inhaled by humans

    Ordered phases of XXZ-symmetric spin-1/2 zigzag ladder

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    Using bosonization approach, we derive an effective low-energy theory for XXZ-symmetric spin-1/2 zigzag ladders and discuss its phase diagram by a variational approach. A spin nematic phase emerges in a wide part of the phase diagram, either critical or massive. Possible crossovers between the spontaneously dimerized and spin nematic phases are discussed, and the topological excitations in all phases identified.Comment: 14 pages, 3 figures. submitted to The European Physical Journal

    Effects of different packaging methods on microbial, [chemical] and sensory properties of Nile tilapia (Oreochromis niloticus Linnaeus, 1758) fillets during refrigerator storage

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    The effect of three different packaging methods including Modified Atmosphere Packaging (MAP), Vacuum Packaging and normal Packaging was investigated on the quality of Nile tilapia fresh fillets stored in the refrigerator's temperature. The packaged samples were examined for 10 days with regard to the changes in chemical (TVN, PV, pH), microbial (total viable count) and sensory evaluations. The results indicated that the samples packed in MAP condition had higher quality than that of other methods at the end of the storage period. In addition, the slower destructive impacts and microbial growth was observed in MAP. The results of present study suggest that packaging tilapia under MAP conditions results in the increase in the durability, storing, and distribution period for fillets

    Edge States of Monolayer and Bilayer Graphene Nanoribbons

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    On the basis of tight-binding lattice model, the edge states of monolayer and bilayer graphene nanoribbons (GNRs) with different edge terminations are studied. The effects of edge-hopping modulation, spin-orbital coupling (SOC), and bias voltage on bilayer GNRs are discussed. We observe the following: (i) Some new extra edge states can be created by edge-hopping modulation for monolayer GNRs. (ii) Intralayer Rashba SOC plays a role in depressing the band energy gap EgE_g opened by intrinsic SOC for both monolayer and bilayer GNRs. An almost linear dependent relation, i.e., EgλRE_g\sim \lambda_R, is found. (iii) Although the bias voltage favors a bulk energy gap for bilayer graphene without intrinsic SOC, it tends to reduce the gap induced by intrinsic SOC. (iv) The topological phase of the quantum spin Hall effect can be destroyed completely by interlayer Rashba SOC for bilayer GNRs.Comment: 6 pages, 6 figure

    Zoonotic Bartonella species in Eurasian wolves and other free-ranging wild mammals from Italy

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    Bartonellae are emerging vector-borne pathogens infecting humans, domestic mammals and wildlife. Ninety-seven red foxes (Vulpes vulpes), 8 European badgers (Meles meles), 6 Eurasian wolves (Canis lupus), 6 European hedgehogs (Erinaceus europaeus), 3 beech martens (Martes foina) and 2 roe deer (Capreolus capreolus) from Italian Nature Conservatory Parks were investigated for Bartonella infection. Several Bartonella species (9.84%; 95% CI: 4.55–15.12), including zoonotic ones, were molecularly detected among wolves (83.3%; 95% CI: 51–100.00), foxes (4.12%; 95% CI: 0.17–8.08), hedgehogs (33.33%; 95% CI: 0.00–71.05) and a roe deer. Bartonella rochalimae was the most common Bartonella species (i.e. in 4 foxes and 2 wolves) detected. Candidatus B. merieuxii and B. vinsonii subsp. berkhoffii were identified for the first time in wolves. Furthermore, Bartonella schoenbuchensis was identified in a roe deer and a new clone with phylogenetic proximity to B. clarridgeiae was detected in European hedgehogs. Zoonotic and other Bartonella species were significantly more frequent in Eurasian wolves (p <.0001), than in other free-ranging wild mammals, representing a potential reservoir for infection in humans and domestic animals

    Enhancement of the superconducting transition temperature from the competition between electron-electron correlations and electron-phonon interactions

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    We uncover that the competition between electron-electron correlations and electron-phonon interactions gives rise to unexpectedly huge enhancement of the superconducting transition temperature, several hundreds percent larger (\geq 200 K) than that of the case when only one of the two is taken into account (\sim 30 K). Our renormalization group analysis claims that this mechanism for the enhancement of the critical temperature is not limited on superconductivity but applied to various Fermi surface instabilities, proposing an underlying universal structure, which turns out to be essentially identical to that of a recent study [Phys. Rev. Lett. {\bf 108}, 046601 (2012)] on the enhancement of the Kondo temperature in the presence of Rashba spin-orbit interactions. We also discuss the stability of superconductivity against nonmagnetic randomness

    Quantum coherence enhances electron transfer rates to two equivalent electron acceptors

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    When a molecular electron donor interacts with multiple electron acceptors, quantum coherence can enhance the electron transfer (ET) rate. Here we report photodriven ET rates in a pair of donor–acceptor (D-A) compounds that link one anthracene (An) donor to one or two equivalent 1,4-benzoquinone (BQ) acceptors. Subpicosecond ET from the lowest excited singlet state of An to two BQs is about 2.4 times faster than ET to one BQ at room temperature, but about 5 times faster at cryogenic temperatures. This factor of 2 increase results from a transition from ET to one of two acceptors at room temperature to ET to a superposition state of the two acceptors with correlated system–bath fluctuations at low temperature

    Exome sequencing identifies novel AD-associated genes

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    The genetic component of Alzheimer’s disease (AD) has been mainly assessed using Genome Wide Association Studies (GWAS), which do not capture the risk contributed by rare variants. Here, we compared the gene-based burden of rare damaging variants in exome sequencing data from 32,558 individuals —16,036 AD cases and 16,522 controls— in a two-stage analysis. Next to known genes TREM2, SORL1 and ABCA7, we observed a significant association of rare, predicted damaging variants in ATP8B4 and ABCA1 with AD risk, and a suggestive signal in ADAM10. Next to these genes, the rare variant burden in RIN3, CLU, ZCWPW1 and ACE highlighted these genes as potential driver genes in AD-GWAS loci. Rare damaging variants in these genes, and in particular loss-of-function variants, have a large effect on AD-risk, and they are enriched in early onset AD cases. The newly identified AD-associated genes provide additional evidence for a major role for APP-processing, Aβ-aggregation, lipid metabolism and microglial function in AD
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