Impact production of NO and reduced species

It has recently been suggested that a reported spike in seawater (87)Sr/(86)Sr at the K-T boundary is the signature of an impact-generated acid deluge. However, the amount of acid required is implausibly large. Some about 3 x 10 to the 15th power moles of Sr must be weathered from silicates to produce the inferred Sr spike. The amount of acid required is at least 100 and probably 1000 times greater. Production of 3 x 10 to the 18th power moles of NO is clearly untenable. The atmosphere presently contains only 1.4 x 10 to the 20th power moles of N-sub 2 and 3.8 x 10 to the 19th power moles of O sub 2 If the entire atmosphere were shocked to 2000 K and cooled within a second, the total NO produced would be about 3 x 10 to the 18th power moles. This is obviously unrealistic. A (still to short) cooling time of 10th to the 3rd power sec reduces NO production by an order of magnitude. In passing, we note that if the entire atmosphere had in fact been shocked to 2000 K, acid rain would have been the least of a dinosaur's problems. Acid rain as a mechanism poses poses other difficulties. Recently deposited carbonates would have been most susceptable to acid attack. The researchers' preferred explanation is simply increased continental erosion following ecological trauma, coupled with enchanced levels of CO-sub 2

The Tethered Moon

Cosmic collisions between terrestrial planets resemble somewhat the life cycle of the phoenix: worlds collide, are consumed in flame, and after the debris has cleared, shiny new worlds emerge aglow with possibilities. And glow they do, for they are molten. How brightly they glow, and for how long, is determined by their atmospheres and their moons. A reasonable initial condition on Earth after the Moon-forming impact is that it begins as a hot global magma ocean. We therefore begin our study with the mantle as a liquid ocean with a surface temperature on the order of 3000-4000 K at a time some 100-1000 years after the impact, by which point we can hope that early transients have settled down

Warming Early Mars by Impact Degassing of Reduced Greenhouse Gases

Reducing greenhouse gases are once again the latest trend in finding solutions to the early Mars climate dilemma. In its current form collision induced absorptions (CIA) involving H2 and/or CH4 provide enough extra greenhouse power in a predominately CO2 atmosphere to raise global mean surface temperatures to the melting point of water provided the atmosphere is thick enough and the reduced gases are abundant enough. Surface pressures must be at least 500 mb and H2 and/or CH4 concentrations must be at or above the several percent level for CIA to be effective. Atmospheres with 1-2 bars of CO2 and 2- 10% H2 can sustain surface environments favorable for liquid water. Smaller concentrations of H2 are sufficient if CH4 is also present. If thick CO2 atmospheres with percent level concentrations of reduced gases are the solution to the faint young Sun paradox for Mars, then plausible mechanisms must be found to generate and sustain the gases. Possible sources of reducing gases include volcanic outgassing, serpentinization, and impact delivery; sinks include photolyis, oxidation, and escape to space. The viability of the reduced greenhouse hypothesis depends, therefore, on the strength of these sources and sinks. In this paper we focus on impact delivered reduced gases

Ks-band detection of thermal emission and color constraints to CoRoT-1b: A low-albedo planet with inefficient atmospheric energy redistribution and a temperature inversion

We report the detection in Ks-band of the secondary eclipse of the hot Jupiter CoRoT-1b, from time series photometry with the ARC 3.5-m telescope at Apache Point Observatory. The eclipse shows a depth of 0.336+/-0.042 percent and is centered at phase 0.5022 (+0.0023,-0.0027), consistent with a zero eccentricity orbit ecos{\omega} = 0.0035 (+0.0036,-0.0042). We perform the first optical to near-infrared multi-band photometric analysis of an exoplanet's atmosphere and constrain the reflected and thermal emissions by combining our result with the recent 0.6, 0.71, and 2.09 micron secondary eclipse detections by Snellen et al. (2009), Gillon et al. (2009), and Alonso et al. (2009a). Comparing the multi-wavelength detections to state-of-the-art radiative-convective chemical-equilibrium atmosphere models, we find the near-infrared fluxes difficult to reproduce. The closest blackbody-based and physical models provide the following atmosphere parameters: a temperature T = 2454 (+84,-170) K, a very low Bond albedo A_B = 0.000 (+0.087,-0.000), and an energy redistribution parameter P_n = 0.1, indicating a small but nonzero amount of heat transfer from the day- to night-side. The best physical model suggests a thermal inversion layer with an extra optical absorber of opacity kappa_e =0.05cm^2g^-1, placed near the 0.1-bar atmospheric pressure level. This inversion layer is located ten times deeper in the atmosphere than the absorbers used in models to fit mid-infrared Spitzer detections of other irradiated hot Jupiters.Comment: accepted for publication on Ap