Astronomical calibration of the geological timescale: closing the middle Eocene gap

To explore cause and consequences of past climate change, very accurate age models such as those provided by the astronomical timescale (ATS) are needed. Beyond 40 million years the accuracy of the ATS critically depends on the correctness of orbital models and radioisotopic dating techniques. Discrepancies in the age dating of sedimentary successions and the lack of suitable records spanning the middle Eocene have prevented development of a continuous astronomically calibrated geological timescale for the entire Cenozoic Era. We now solve this problem by constructing an independent astrochronological stratigraphy based on Earth's stable 405 kyr eccentricity cycle between 41 and 48 million years ago (Ma) with new data from deep-sea sedimentary sequences in the South Atlantic Ocean. This new link completes the Paleogene astronomical timescale and confirms the intercalibration of radioisotopic and astronomical dating methods back through the Paleocene–Eocene Thermal Maximum (PETM, 55.930 Ma) and the Cretaceous–Paleogene boundary (66.022 Ma). Coupling of the Paleogene 405 kyr cyclostratigraphic frameworks across the middle Eocene further paves the way for extending the ATS into the Mesozoic

The Geological Record of Ocean Acidification

Ocean acidification may have severe consequences for marine ecosystems; however, assessing its future impact is difficult because laboratory experiments and field observations are limited by their reduced ecologic complexity and sample period, respectively. In contrast, the geological record contains long-term evidence for a variety of global environmental perturbations, including ocean acidification plus their associated biotic responses. We review events exhibiting evidence for elevated atmospheric CO2, global warming, and ocean acidification over the past ~300 million years of Earth's history, some with contemporaneous extinction or evolutionary turnover among marine calcifiers. Although similarities exist, no past event perfectly parallels future projections in terms of disrupting the balance of ocean carbonate chemistry—a consequence of the unprecedented rapidity of CO2 release currently taking place

The climatic consequences of a rare orbital anomaly at the Oligocene/Miocene boundary (23Ma)

The late Oligocene to early Miocene (20-26Ma) is characterized by a complex climate history that includes a stepped transition toward a cooler climate, intermittent partial glaciations of Antarctica, and a transient glaciation, Mi-1, at the Oligocene/Miocene (O/M) boundary. The Mi-1 event is characterized by an anomalous positive oxygen isotope excursion, the magnitude of which suggests the brief appearance of a full-scale ice-sheet on east Antarctica coupled with a few degrees of deep sea cooling. A recent breakthrough in extending the astronomical calibration back to ~30 Ma has provided a unique opportunity to compare the climatic events of the O/M transition relative to Earth’s orbital variations. Here, we present an uninterrupted 5.5 My long high-fidelity chronology of late Oligocene-early Miocene climate and ocean carbon chemistry that is based on a composite in the western equatorial Atlantic. This unique isotope record provides a rare window into how the climate system responded to orbital forcing uncer boundary conditions significantly different from those of the recent past. Time-series analyses reveal climate variance concentrated at all Milankovitch frequencies, but with unusually strong power at the primary eccentricity band periods of 406, 125, and 95-ky. These cycles, which represent in part glacial advances and retreats of Antarctic ice-sheets, show significantly enhanced variability over a 1.6 my period (21.4-23.0 Ma) of suspected low greenhouse gas levels as inferred from the carbon isotope record. Perhaps the most unexpected finding is that of a rare orbital congruence between eccentricity and obliquity that precisely corresponds with the Mi-1 glaciation. This orbital anomaly involves ~four consecutive cycles of low amplitude variance in obliquity (a node) during a period of low eccentricity. The net result is an extended period (~200ky) of low seasonality orbits, which allows for a step-like expansion of an Antarctic ice-sheet

Astronomical calibration of the late Oligocene through early Miocene geomagnetic polarity time scale (abstract of paper presented at AGU Fall Meeting, San Francisco, 8-12 Dec 2003)

At Ocean Drilling Program Site 1090 (subantarctic South Atlantic) benthic foraminiferal stable isotope data (from Cibicidoides and Oridorsalis) span the late Oligocene through the early Miocene (24-16 Ma) at a temporal resolution of 5 kyr. In the same time interval, a magnetic polarity stratigraphy can be unequivocally correlated to the geomagnetic polarity timescale (GPTS), thereby providing direct correlation of the isotope record to the GPTS. In an initial age model we use the newly derived age of the Oligocene/Miocene boundary of 23.0 Ma (Shackleton et al., 2000) revised to the new astronomical calculation of Laskar (2001) to recalculate the spline ages of Cande and Kent (1995). We then tune the site 1090 oxygen isotope record to obliquity, assuming a 7.2 kyr phase lag, using the new astronomic solution of Laskar (2001). In this manner we are able to refine the ages of polarity chrons C7n through C5Cn.1n. The new age model is consistent, within one obliquity cycle, with previously tuned ages for polarity chrons C7n to C6Bn from Shackleton et al. (2000), rescaled to the new astronomical solution of Laskar (2001). For early Miocene polarity chrons C6AAr through C5Cn, our obliquity-scale age model is the first to allow a direct calibration to the GPTS. The new ages are also close to, within one obliquity cycle, to those obtained by rescaling the Cande and Kent (1995) interpolation using the new age of the O/M boundary (23.0 Ma), and the same middle Miocene control point (14.8 Ma) used by Cande and Kent (1992). Thus we have confidence in the orbitally tuned age model and the refined GPTS calibration for the late Oligocene through early Miocene

Two-stepping into the icehouse: East Antarctic weathering during progressive ice-sheet expansion at the Eocene-Oligocene transition

In conjunction with increasing benthic foraminiferal ?18O values at the Eocene–Oligocene transition (EOT; ca. 34 Ma), coarse-grained ice-rafted debris (IRD; >425 ?m) appears abruptly alongside fossil fish teeth with continentally derived neodymium (Nd) isotope ratios (?Nd) in Kerguelen Plateau (Southern Ocean) sediments. Increased Antarctic weathering flux, as inferred from two steps to less radiogenic ?Nd values, coincides with two steps in benthic foraminiferal ?18O values. These results indicate that two distinct surges of weathering were generated by East Antarctic ice growth during the EOT. Weathering by ice sheets during a precursor glaciation at 33.9 Ma did not produce significant IRD accumulation during the first ?Nd shift. Glacial weathering was sustained during a terrace interval between the two steps, probably by small high-elevation ice sheets. A large increase in weathering signals the rapid coalescence of small ice sheets into an ice sheet of continental proportions ca. 33.7 Ma. Rapid ice sheet expansion resulted in a suppression of weathering due to less exposed area and colder conditions. Parallel changes in Antarctic weathering flux and deep-sea carbonate accumulation suggest that ice-sheet expansion during the EOT had a direct impact on the global carbon cycle; possible mechanisms include associated changes in silicate weathering on the East Antarctic craton and enhanced fertilization of Southern Ocean waters, both of which warrant further investigation

Carbon emissions and acidification

Avoiding environmental damage from ocean acidification requires reductions in carbon dioxide emissions regardless of climate change

Climate response to orbital forcing across the Oligocene-Miocene boundary

Spectral analyses of an uninterrupted 5.5-million-year (My)-long chronology of late Oligocene-early Miocene climate and ocean carbon chemistry from two deep-sea cores recovered in the western equatorial Atlantic reveal variance concentrated at all Milankovitch frequencies. Exceptional spectral power in climate is recorded at the 406-thousand-year (ky) period eccentricity band over a 3.4-million-year period [20 to 23.4 My ago (Ma)] as well as in the 125- and 95-ky bands over a 1.3-million-year period (21.7 to 23.0 Ma) of suspected low greenhouse gas levels. Moreover, a major transient glaciation at the epoch boundary (~23 Ma), Mi-1, corresponds with a rare orbital congruence involving obliquity and eccentricity. The anomaly, which consists of low-amplitude variance in obliquity (a node) and a minimum in eccentricity, results in an extended period (~200 ky) of low seasonality orbits favorable to ice-sheet expansion on Antarctic