203 research outputs found
X-ray Absorption Fine Structure in Embedded Atoms
Oscillatory structure is found in the atomic background absorption in
x-ray-absorption fine structure (XAFS). This atomic-XAFS or AXAFS arises from
scattering within an embedded atom, and is analogous to the Ramsauer-Townsend
effect. Calculations and measurements confirm the existence of AXAFS and show
that it can dominate contributions such as multi-electron excitations. The
structure is sensitive to chemical effects and thus provides a new probe of
bonding and exchange effects on the scattering potential.Comment: 4 pages plus 2 postscript figures, REVTEX 3.
Pd/Cu Site Interchange and Non-Fermi-Liquid Behavior in UCu_4Pd
X-ray-absorption fine-structure measurements of the local structure in
UCu_4Pd are described which indicate a probable lattice-disorder origin for
non-Fermi-liquid behavior in this material. Short Pd-Cu distances are observed,
consistent with 24 +/- 3% of the Pd atoms occupying nominally Cu sites. A
"Kondo disorder" model, based on the effect on the local Kondo temperature T_K
of this interchange and some additional bond-length disorder, agrees
quantitatively with previous experimental susceptibility data, and therefore
also with specific heat and magnetic resonance experiments.Comment: 4 pages, 3 PostScript figures, to be published in PR
Local lattice disorder in the geometrically-frustrated spin glass pyrochlore Y2Mo2O7
The geometrically-frustrated spin glass Y2Mo2O7 has been considered widely to
be crystallographically ordered with a unique nearest neighbor magnetic
exchange interaction, J. To test this assertion, we present x-ray-absorption
fine-structure results for the Mo and Y K edges as a function of temperature
and compare them to results from a well-ordered pyrochlore, Tl2Mn2O7. We find
that the Mo-Mo pair distances are significantly disordered at approximately
right angles to the Y-Mo pairs. These results strongly suggest that lattice
disorder nucleates the spin-glass phase in this material.Comment: 9 pages, 2 Postscript figures, Phys. Rev. B: Rapid, in pres
Effect of [OH-] linkages on luminescent properties of ZnO nanoparticles
Optical properties of ZnO nanoparticles prepared from a simple chemical
method using sodium zincate bath show strong white light emission. X-ray
absorption fine structure studies reveal a completely different local
environment around Zn in these ZnO nanoparticles. The observed luminescence
properties and local structural changes have been explained on the basis of a
linkage between Zn and OH- ions in the surface layers of ZnO nanoparticles.Comment: J. Phys. Chem. C. (2011) (in print
Local structure study about Co in YBa(CuCo)O thin films using polarized XAFS
We have studied the local structure around Co in
YBa(CuCo)O thin films with three different
concentrations: x=0.07, 0.10, 0.17, and in a
PrBa(CuCo)O thin film of concentration x=0.05
using the X-ray Absorption Fine Structure (XAFS) technique. Data were collected
at the Co -edge with polarizations both parallel and perpendicular to the
film surface. We find that the oxygen neighbors are well ordered and shortened
in comparison with YBCO Cu-O values to 1.80 \AA{} and 1.87 \AA{} in the
-axis and -plane, respectively. A comparison of further neighbors in the
thin film and powder data show that these peaks in the film are suppressed in
amplitude relative to the powder samples, which suggests there is more disorder
and/or distortions of the Co environment present in the thin films.Comment: 14 pages; To be submitted to Phys. Rev.
Spectroscopic and computational insights on catalytic synergy in bimetallic aluminophosphate catalysts
A combined electronic structure computational and X-ray absorption spectroscopy study was used to investigate the nature of the active sites responsible for catalytic synergy in Co-Ti bimetallic nanoporous frameworks. Probing the nature of the molecular species at the atomic level has led to the identification of a unique Co-O-Ti bond, which serves as the loci for the superior performance of the bimetallic catalyst, when compared with its analogous monometallic counterpart. The structural and spectroscopic features associated with this active site have been characterized and contrasted, with a view to affording structure property relationships, in the wider context of designing sustainable catalytic oxidations with porous solids
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