Thorium-doping induced superconductivity up to 56 K in Gd1-xThxFeAsO

Following the discovery of superconductivity in an iron-based arsenide LaO1-xFxFeAs with a superconducting transition temperature (Tc) of 26 K[1], Tc was pushed up surprisingly to above 40 K by either applying pressure[2] or replacing La with Sm[3], Ce[4], Nd[5] and Pr[6]. The maximum Tc has climbed to 55 K, observed in SmO1-xFxFeAs[7, 8] and SmFeAsO1-x[9]. The value of Tc was found to increase with decreasing lattice parameters in LnFeAsO1-xFx (Ln stands for the lanthanide elements) at an apparently optimal doping level. However, the F- doping in GdFeAsO is particularly difficult[10,11] due to the lattice mismatch between the Gd2O2 layers and Fe2As2 layers. Here we report observation of superconductivity with Tc as high as 56 K by the Th4+ substitution for Gd3+ in GdFeAsO. The incorporation of relatively large Th4+ ions relaxes the lattice mismatch, hence induces the high temperature superconductivity.Comment: 4 pages, 3 figure

Possibility of Unconventional Pairing Due to Coulomb Interaction in Fe-Based Pnictide Superconductors: Perturbative Analysis of Multi-Band Hubbard Models

Possibility of unconventional pairing due to Coulomb interaction in iron-pnictide superconductors is studied by applying a perturbative approach to realistic 2- and 5-band Hubbard models. The linearized Eliashberg equation is solved by expanding the effective pairing interaction perturbatively up to third order in the on-site Coulomb integrals. The numerical results for the 5-band model suggest that the eigenvalues of the Eliashberg equation are sufficiently large to explain the actual high Tc for realistic values of Coulomb interaction and the most probable pairing state is spin-singlet s-wave without any nodes just on the Fermi surfaces, although the superconducting order parameter changes its sign between the small Fermi pockets. On the other hand the 2-band model is quite insufficient to explain the actual high Tc.Comment: 2 pages, 3 figures. Proceedings of the Intl. Symposium on Fe-Oxypnictide Superconductors (Tokyo, 28-29th June 2008

Theory of the Magnetic Moment in Iron Pnictides

We show that the combined effects of spin-orbit, monoclinic distortion, and p-d hybridization in tetrahedrally coordinated Fe in LaOFeAs invalidates the naive Hund's rule filling of the Fe d-levels. The two highest occupied levels have one electron each but as a result of the p-d hybridization have very different on-site repulsions. As a result, electrons in the upper level are more itinerant while those in the lower level are more localized. It is the xy-projection of the spin in the lower level that orders antiferromagnetically as the z-components of the spins in the two levels is shown to be vanishingly small in the ground state. The resulting magnetic moment is highly anisotropic with an in-plane value of $0.25-0.35\mu_B$ per Fe and a z-projection of $0.06\mu_B$, both of which are in agreement with experiment. As a consequence, we arrive the minimal model that describes the electronic properties of LaOFeAs.Comment: Published Versio

Competition between the BCS superconductivity and ferromagnetic spin fluctuations in MgCNi3_3

The low temperature specific heat of the superconductor MgCNi$_3$ and a non-superconductor MgC$_{0.85}$Ni$_3$ is investigated in detail. An additional contribution is observed from the data of MgCNi$_3$ but absent in MgC$_{0.85}$Ni$_3$, which is demonstrated to be insensitive to the applied magnetic field even up to 12 Tesla. A detailed discussion on its origin is then presented. By subtracting this additional contribution, the zero field specific heat of MgCNi$_3$ can be well described by the BCS theory with the gap ratio ($\Delta/k_BT_c$) determined by the previous tunneling measurements. The conventional s-wave pairing state is further proved by the magnetic field dependence of the specific heat at low temperatures and the behavior of the upper critical field.Comment: To appear in Physical Review B, 6 pages, 7 figure

Evidence for s-wave pairing from measurement on lower critical field in MgCNi3MgCNi_3

Magnetization measurements in the low field region have been carefully performed on a well-shaped cylindrical and an ellipsoidal sample of superconductor $MgCNi_3$. Data from both samples show almost the same results. The lower critical field $H_{c1}$ and the London penetration depth $\lambda$ are thus derived. It is found that the result of normalized superfluid density $\lambda^2(0)/\lambda^2(T)$ of $MgCNi_3$ can be well described by BCS prediction with the expectation for an isotropic s-wave superconductivity.Comment: To appear in Phys. Rev.

Wilson Fermions on a Randomly Triangulated Manifold

A general method of constructing the Dirac operator for a randomly triangulated manifold is proposed. The fermion field and the spin connection live, respectively, on the nodes and on the links of the corresponding dual graph. The construction is carried out explicitly in 2-d, on an arbitrary orientable manifold without boundary. It can be easily converted into a computer code. The equivalence, on a sphere, of Majorana fermions and Ising spins in 2-d is rederived. The method can, in principle, be extended to higher dimensions.Comment: 18 pages, latex, 6 eps figures, fig2 corrected, Comment added in the conclusion sectio

Multiple Superconducting Gaps, Anisotropic Spin Fluctuations and Spin-Orbit Coupling in Iron-Pnictides

This article reviews the NMR and NQR studies on iron-based high-temperature superconductors by the IOP/Okayama group. It was found that the electron pairs in the superconducting state are in the spin-singlet state with multiple fully-opened energy gaps. The antiferromagnetic spin fluctuations in the normal state are found to be closely correlated with the superconductivity. Also the antiferromagnetic spin fluctuations are anisotropic in the spin space, which is different from the case in copper oxide superconductors. This anisotropy originates from the spin-orbit coupling and is an important reflection of the multiple-bands nature of this new class of superconductors.Comment: 20 pages, 16 figure