One-Pot Synthesis of Renewable Phthalic Anhydride from 5-Hydroxymethfurfural by using MoO3 /Cu(NO3 )2 as Catalyst.

Herein, a synthetic pathway to renewable phthalic anhydride (PA) from 5-hydroxymethfurfural (HMF) in one pot is reported. The commonly available catalysts MoO3 and Cu(NO3 )2 play a crucial role in integrating the multiple steps of the reaction, namely decarbonylation of HMF to active furyl intermediate (AFI), oxidation of HMF to maleic anhydride (MA), Diels-Alder cycloaddition of AFI and MA, and subsequent dehydration, in one pot. Under mild reaction conditions, a 63.2 % yield of PA is obtained from HMF. Compared with the currently reported route to renewable PA based on the Diels-Alder cycloaddition of biomass-derived MA and furan, this convenient one-pot synthesis represents a great improvement in efficiency

Synthesis of renewable monomer 2, 5-bishydroxymethylfuran from highly concentrated 5-hydroxymethylfurfural in deep eutectic solvents

Abstract(#br)2, 5-Bishydroxymethylfuran (BHMF) has been currently emerged as a promising biomass-derived monomer. It is highly desirable to proceed a chemical process at a high substrate concentration, by which a facile and cost-effective separation of products can be expected. Herein, we report for the first time on the hydrogenation of highly concentrated 5-hydroxymethylfurfural (HMF) in deep eutectic solvents (DESs), giving a near quantitative selectivity towards BHMF in ChCl-glycerol DES at 25°C in 3h using NaBH 4 as the H-donor. DES is hailed as a new class of green solvent, in which HMF/BHMF could be stabilized by the strong hydrogen-bond interaction, and allowed the selective hydrogenation of HMF at high concentration up to 40wt%. Notably, the resulting BHMF could be facilely separated by extraction with ethyl acetate, and then high purity of BHMF with a desirable isolated yield around 80% was obtained after removing of ethyl acetate. Additionally, the reaction efficiency of HMF hydrogenation in DESs was verified to be strongly associated with the viscosity of DESs and the p K a value of hydrogen-bonding donor

Insights into the active sites and catalytic mechanism of oxidative esterification of 5-hydroxymethylfurfural by metal-organic frameworks-derived N-doped carbon

Abstract(#br)Directly oxidative esterification of Biomass-derived 5-hydroxymethylfurfural (HMF) into dimethyl furan dicarboxylate (DMFDCA) is a promising route for the replacement of petroleum-derived commodity chemical terephthalic acid (TPA) extensively employed in polyester synthesis. Co-based N-doped carbon materials are one of the most promising applied catalysts for oxidative esterification reaction, however, the active sites and reaction pathway of these catalysts have not been clearly clarified, which is crucial to the practical application. Herein, we report that ZIF-67 (a zeolitic imidazolate framework (ZIF)-type cobalt-containing MOF) derived Co@C-N material is a highly effective catalyst for the selective conversion of HMF into DMFDCA in 95% yield. The high activity of the ZIF-67 derived nanocarbon composites Co@C-N can be attributed to the electron transfer between nitrogen-doped carbon shells and Co nanoparticles. The appropriate graphitic N and pyridinic N doping increases the electronic mobility and active sites. Density functional theory (DFT) simulations indicated that oxygen, HMF and methanol molecules are adsorbed and activated on C-N materials. Furthermore, no 2, 5-diformylfuran (DFF) was captured as an intermediate because the oxidative esterification of aldehyde preferentially occurred than the oxidation of hydroxyl group in HMF. We anticipate that these results can drive progress in the bio-based polymers sector and oxidative esterification reaction

Experimental investigation of mechanically laminated straight or curved-and-tapered bamboo-concrete T-beams

This study echoes the rising demand for bio-based material in concrete composite structures in the race to accelerate carbon neutrality in construction. Noticing that most previous studies are focused on straight timber or engineered bamboo-to-concrete composite beams, this study developed straight or curved-and-tapered mechanically laminated bamboo-concrete (LBC) T-beams. Six layers of 26mm thick laminated bamboo panels were glue laminated together to form the bamboo beams. The curved bamboo beams have three different rises of arch: 50mm, 100mm and 150mm. All specimen beams were tested by four-point bending tests to evaluate their structural performances of the curved and straight LBC T-beams. To monitor the flange-to-web interface shear transfer, a novel interface shear slip calibration method that captures the longitudinal after-slip strain redistribution was developed and validated by strain gauge measurements. This study also highlights the interlayer shear bonding strength of laminated bamboo as the thresholding parameter that determines the composite beams' overall flexural strength, evidenced by detailed failure mode analysis. The proposed interface shear slip calibration method can be extended to the other types of shear connectors such as screws, nails, shear plates and notched connections

Insect-Specific microRNA Involved in the Development of the Silkworm Bombyx mori

MicroRNAs (miRNAs) are endogenous non-coding genes that participate in post-transcription regulation by either degrading mRNA or blocking its translation. It is considered to be very important in regulating insect development and metamorphosis. We conducted a large-scale screening for miRNA genes in the silkworm Bombyx mori using sequence-by-synthesis (SBS) deep sequencing of mixed RNAs from egg, larval, pupal, and adult stages. Of 2,227,930 SBS tags, 1,144,485 ranged from 17 to 25 nt, corresponding to 256,604 unique tags. Among these non-redundant tags, 95,184 were matched to the silkworm genome. We identified 3,750 miRNA candidate genes using a computational pipeline combining RNAfold and TripletSVM algorithms. We confirmed 354 miRNA genes using miRNA microarrays and then performed expression profile analysis on these miRNAs for all developmental stages. While 106 miRNAs were expressed in all stages, 248 miRNAs were egg- and pupa-specific, suggesting that insect miRNAs play a significant role in embryogenesis and metamorphosis. We selected eight miRNAs for quantitative RT-PCR analysis; six of these were consistent with our microarray results. In addition, we searched for orthologous miRNA genes in mammals, a nematode, and other insects and found that most silkworm miRNAs are conserved in insects, whereas only a small number of silkworm miRNAs has orthologs in mammals and the nematode. These results suggest that there are many miRNAs unique to insects

Overall and cause-specific mortality rates among men and women with high exposure to indoor air pollution from the use of smoky and smokeless coal: a cohort study in Xuanwei, China

OBJECTIVES: Never-smoking women in Xuanwei (XW), China, have some of the highest lung cancer rates in the country. This has been attributed to the combustion of smoky coal used for indoor cooking and heating. The aim of this study was to evaluate the spectrum of cause-specific mortality in this unique population, including among those who use smokeless coal, considered 'cleaner' coal in XW, as this has not been well-characterised. DESIGN: Cohort study. SETTING: XW, a rural region of China where residents routinely burn coal for indoor cooking and heating. PARTICIPANTS: Age-adjusted, cause-specific mortality rates between 1976 and 2011 were calculated and compared among lifetime smoky and smokeless coal users in a cohort of 42 420 men and women from XW. Mortality rates for XW women were compared with those for a cohort of predominately never-smoking women in Shanghai. RESULTS: Mortality in smoky coal users was driven by cancer (41%), with lung cancer accounting for 88% of cancer deaths. In contrast, cardiovascular disease (CVD) accounted for 32% of deaths among smokeless coal users, with 7% of deaths from cancer. Total cancer mortality was four times higher among smoky coal users relative to smokeless coal users, particularly for lung cancer (standardised rate ratio (SRR)=17.6). Smokeless coal users had higher mortality rates of CVD (SRR=2.9) and pneumonia (SRR=2.5) compared with smoky coal users. These patterns were similar in men and women, even though XW women rarely smoked cigarettes. Women in XW, regardless of coal type used, had over a threefold higher rate of overall mortality, and most cause-specific outcomes were elevated compared with women in Shanghai. CONCLUSIONS: Cause-specific mortality burden differs in XW based on the lifetime use of different coal types. These observations provide evidence that eliminating all coal use for indoor cooking and heating is an important next step in improving public health particularly in developing countries

Guava Detection and Pose Estimation Using a Low-Cost RGB-D Sensor in the Field

Fruit detection in real outdoor conditions is necessary for automatic guava harvesting, and the branch-dependent pose of fruits is also crucial to guide a robot to approach and detach the target fruit without colliding with its mother branch. To conduct automatic, collision-free picking, this study investigates a fruit detection and pose estimation method by using a low-cost red⁻green⁻blue⁻depth (RGB-D) sensor. A state-of-the-art fully convolutional network is first deployed to segment the RGB image to output a fruit and branch binary map. Based on the fruit binary map and RGB-D depth image, Euclidean clustering is then applied to group the point cloud into a set of individual fruits. Next, a multiple three-dimensional (3D) line-segments detection method is developed to reconstruct the segmented branches. Finally, the 3D pose of the fruit is estimated using its center position and nearest branch information. A dataset was acquired in an outdoor orchard to evaluate the performance of the proposed method. Quantitative experiments showed that the precision and recall of guava fruit detection were 0.983 and 0.948, respectively; the 3D pose error was 23.43° ± 14.18°; and the execution time per fruit was 0.565 s. The results demonstrate that the developed method can be applied to a guava-harvesting robot

Structural Response of a Prefabricated Utility Tunnel Subject to a Reverse Fault

Prefabricated utility tunnels have drawn much attention in relation to rapid urban development. On this, how to maintain the integrity of an underground lifeline, which is subjected to unexpected fault displacement action, is a concern either from the design or the construction aspect. By applying the commercial software program ABAQUS, this paper presents a systematic numerical simulation of a prefabricated utility tunnel affected by a reverse fault. The critical parameters investigated in this study include fault displacement, burial depth, utility tunnel-soil friction coefficient, and the angle of the utility tunnel crossing the fault plane. Results of the numerical modeling revealed that: (1) both the overall structural deformation and the spliced joints deformation of the prefabricated utility tunnel increase with increasing fault displacement, which greatly reduces the waterproofing ability of the utility tunnel joints; (2) the opening displacement of the joints on the roof of the utility tunnel near the fault plane is positively correlated with burial depth, but the variation is slight; (3) the variations in utility tunnel-soil friction coefficient have little effect on the overall structural deformation and the spliced joints deformation; (4) the opening displacement of the spliced joints of the utility tunnel basically gradually increases with an increase in the crossing angle near the fault plane, which is different than when it is away from the fault plane. The main outcomes obtained from this study can provide reference for the construction of prefabricated utility tunnel in fault active area

Recognition and Matching of Clustered Mature Litchi Fruits Using Binocular Charge-Coupled Device (CCD) Color Cameras

Recognition and matching of litchi fruits are critical steps for litchi harvesting robots to successfully grasp litchi. However, due to the randomness of litchi growth, such as clustered growth with uncertain number of fruits and random occlusion by leaves, branches and other fruits, the recognition and matching of the fruit become a challenge. Therefore, this study firstly defined mature litchi fruit as three clustered categories. Then an approach for recognition and matching of clustered mature litchi fruit was developed based on litchi color images acquired by binocular charge-coupled device (CCD) color cameras. The approach mainly included three steps: (1) calibration of binocular color cameras and litchi image acquisition; (2) segmentation of litchi fruits using four kinds of supervised classifiers, and recognition of the pre-defined categories of clustered litchi fruit using a pixel threshold method; and (3) matching the recognized clustered fruit using a geometric center-based matching method. The experimental results showed that the proposed recognition method could be robust against the influences of varying illumination and occlusion conditions, and precisely recognize clustered litchi fruit. In the tested 432 clustered litchi fruits, the highest and lowest average recognition rates were 94.17% and 92.00% under sunny back-lighting and partial occlusion, and sunny front-lighting and non-occlusion conditions, respectively. From 50 pairs of tested images, the highest and lowest matching success rates were 97.37% and 91.96% under sunny back-lighting and non-occlusion, and sunny front-lighting and partial occlusion conditions, respectively