Upcycling Steel Slag in Producing Eco-Efficient Iron–calcium Phosphate Cement

In the present study, steel slag powder (SSP) was utilized as the raw material to prepare iron-calcium phosphate cement (ICPC) by reacting with ammonium dihydrogen phosphate (ADP). The influences of the raw materials (SSP/ADP) mass ratios ranging from 2.0 to 7.0 on the properties and microstructures of ICPC pastes were investigated. The compressive strengths of ICPC pastes at all ages firstly increased and then decreased with the increase of SSP/ADP, and the SSP/ADP of 6.0 gave the highest strength. Crystalline mundrabillaite and amorphous phases [i.e. Fe(OH)3, Al(OH)3 and H4SiO4] were formed as the dominant binding phases through the reactions of the calcium-containing compounds (brownmillerite, monticellite and srebrodolskite) in the steel slag and ADP. Further, ADP could also react with the free FeO contained in the steel slag to yield amorphous iron phosphate phase. BSE analysis indicated that the hydration products formed and growed on the surface of steel slag particles and connect them to form the continuous, dense microstructure of ICPC paste. The utilization of high-volume steel slag as the base component will potentially bring great economic and environmental benefits for the manufacture of phosphate cement

Integrated Sensing, Computation, and Communication: System Framework and Performance Optimization

Integrated sensing, computation, and communication (ISCC) has been recently considered as a promising technique for beyond 5G systems. In ISCC systems, the competition for communication and computation resources between sensing tasks for ambient intelligence and computation tasks from mobile devices becomes an increasingly challenging issue. To address it, we first propose an efficient sensing framework with a novel action detection module. It can reduce the overhead of computation resource by detecting whether the sensing target is static. Subsequently, we analyze the sensing performance of the proposed framework and theoretically prove its effectiveness with the help of the sampling theorem. Then, we formulate a sensing accuracy maximization problem while guaranteeing the quality-of-service (QoS) requirements of tasks. To solve it, we propose an optimal resource allocation strategy, in which the minimal resource is allocated to computation tasks, and the rest is devoted to sensing tasks. Besides, a threshold selection policy is derived. Compared with the conventional schemes, the results further demonstrate the necessity of the proposed sensing framework. Finally, a real-world test of action recognition tasks based on USRP B210 is conducted to verify the sensing performance analysis, and extensive experiments demonstrate the performance improvement of our proposal by comparing it with some benchmark schemes

Online Robot Introspection via Wrench-based Action Grammars

Robotic failure is all too common in unstructured robot tasks. Despite well-designed controllers, robots often fail due to unexpected events. How do robots measure unexpected events? Many do not. Most robots are driven by the sense-plan act paradigm, however more recently robots are undergoing a sense-plan-act-verify paradigm. In this work, we present a principled methodology to bootstrap online robot introspection for contact tasks. In effect, we are trying to enable the robot to answer the question: what did I do? Is my behavior as expected or not? To this end, we analyze noisy wrench data and postulate that the latter inherently contains patterns that can be effectively represented by a vocabulary. The vocabulary is generated by segmenting and encoding the data. When the wrench information represents a sequence of sub-tasks, we can think of the vocabulary forming a sentence (set of words with grammar rules) for a given sub-task; allowing the latter to be uniquely represented. The grammar, which can also include unexpected events, was classified in offline and online scenarios as well as for simulated and real robot experiments. Multiclass Support Vector Machines (SVMs) were used offline, while online probabilistic SVMs were are used to give temporal confidence to the introspection result. The contribution of our work is the presentation of a generalizable online semantic scheme that enables a robot to understand its high-level state whether nominal or abnormal. It is shown to work in offline and online scenarios for a particularly challenging contact task: snap assemblies. We perform the snap assembly in one-arm simulated and real one-arm experiments and a simulated two-arm experiment. This verification mechanism can be used by high-level planners or reasoning systems to enable intelligent failure recovery or determine the next most optima manipulation skill to be used.Comment: arXiv admin note: substantial text overlap with arXiv:1609.0494

A Novel Iron Phosphate Cement Derived from Copper Smelting Slag and its Early Age Hydration Mechanism

Copper slag (CS), a by-product of copper smelting, is normally stockpiled, leading to wastes of resource and space as well as environment pollution. It has not been massively reutilized as a supplementary cementitious material in Portland cement due to its low reactivity. In the present study, CS is for the first time utilized as the base component to prepare an iron phosphate cement (IPC) by reacting with ammonium dihydrogen phosphate (ADP) at room temperature. The influence of the raw materials mass ratio (CS/ADP) on the microstructure and performance of IPC pastes are investigated. It is found that the compressive strength of IPC pastes at all ages is not a monotonic function of CS/ADP, and the paste with CS/ADP of 2.0 gives the highest strengths, i.e., 26.8, 38.9 and 47.5 MPa at 1, 3 and 28 d, respectively. The crystalline phases including FeH2P3O10·H2O and FePO4 are formed as the main reaction products to bind the unreacted CS particles. The early age hydration of IPC is found to be a multi-stage process, involving the initial dissolution of ADP and iron-containing phases of CS, the formation of FeH2P3O10·H2O, the initial generation of FePO4, and the attainment of the hydration reaction equilibrium. Unlike the magnesium phosphate cement, a redox reaction of Fe(Ⅱ) into Fe(Ⅲ) occurs due to the suitable range of pH and oxidation-reduction potential of the IPC system during the hydration reaction

Huber Kalman Filter for Wi-Fi based Vehicle Driver\u27s Respiration Detection

The use of breath detection in vehicles can reduce the number of vehicular accidents caused by drivers in poor physical condition. Prior studies of contactless respiration detection mainly targeted a static person. However, there are emerging applications to sense a driver, with emphasis on contactless methods. For example, being able to detect a driver\u27s respiration while driving by using a vehicular Wi-Fi system can significantly enhance driving safety. The sensing system can be mounted on the back of the driver\u27s seat, and it can sense the tiny chest displacement of the driver via Wi-Fi signals. The body displacement and car vibrations could introduce significant noise in the sensed signal. The noise then needs to be filtered to obtain the driver\u27s respiration. In this work, the noise in the sensed signal is proposed to be reduced using a Huber Kalman filter to restore the original respiration curve. Through several experiments in terms of different drivers, different car models, multiple passengers, and abnormal breathing, we demonstrate the accuracy and robustness of the Huber Kalman filter in driver\u27s respiration

Fast Ionic Diffusion-Enabled Nanoflake Electrode by Spontaneous Electrochemical Pre-Intercalation for High-Performance Supercapacitor

Layered intercalation compounds Na$_{x}$MnO$_{2}$ (x = 0.7 and 0.91) nanoflakes have been prepared directly through wet electrochemical process with Na$^{+}$ ions intercalated into MnO$_{2}$ interlayers spontaneously. The as-prepared Na$_{x}$MnO$_{2}$ nanoflake based supercapacitors exhibit faster ionic diffusion with enhanced redox peaks, tenfold-higher energy densities up to 110 Wh·kg$^{-1}$ and higher capacitances over 1000 F·g$^{-1}$ in aqueous sodium system compared with traditional MnO$_{2}$ supercapacitors. Due to the free-standing electrode structure and suitable crystal structure, Na$_{x}$MnO$_{2}$ nanoflake electrodes also maintain outstanding electrochemical stability with capacitance retention up to 99.9% after 1000 cycles. Besides, pre-intercalation effect is further studied to explain this enhanced electrochemical performance. This study indicates that the suitable pre-intercalation is effective to improve the diffusion of electrolyte cations and other electrochemical performance for layered oxides, and suggests that the as-obtained nanoflakes are promising materials to achieve the hybridization of both high energy and power density for advanced supercapacitors.Chemistry and Chemical Biolog

Impact of chest pain center quality control indicators on mortality risk in ST-segment elevation myocardial infarction patients: a study based on Killip classification

BackgroundDespite the crucial role of Chest pain centers (CPCs) in acute myocardial infarction (AMI) management, China's mortality rate for ST-segment elevation myocardial infarction (STEMI) has remained stagnant. This study evaluates the influence of CPC quality control indicators on mortality risk in STEMI patients receiving primary percutaneous coronary intervention (PPCI) during the COVID-19 pandemic.MethodsA cohort of 664 consecutive STEMI patients undergoing PPCI from 2020 to 2022 was analyzed using Cox proportional hazards regression models. The cohort was stratified by Killip classification at admission (Class 1: n = 402, Class ≥2: n = 262).ResultsAt a median follow-up of 17 months, 35 deaths were recorded. In Class ≥2, longer door-to-balloon (D-to-B) time, PCI informed consent time, catheterization laboratory activation time, and diagnosis-to-loading dose dual antiplatelet therapy (DAPT) time were associated with increased mortality risk. In Class 1, consultation time (notice to arrival) under 10 min reduced death risk. In Class ≥2, PCI informed consent time under 20 min decreased mortality risk.ConclusionCPC quality control metrics affect STEMI mortality based on Killip class. Key factors include time indicators and standardization of CPC management. The study provides guidance for quality care during COVID-19